全文获取类型
收费全文 | 135492篇 |
免费 | 20288篇 |
国内免费 | 15341篇 |
专业分类
化学 | 72456篇 |
晶体学 | 1139篇 |
力学 | 5876篇 |
综合类 | 666篇 |
数学 | 12627篇 |
物理学 | 39571篇 |
无线电 | 38786篇 |
出版年
2024年 | 550篇 |
2023年 | 3155篇 |
2022年 | 4191篇 |
2021年 | 5151篇 |
2020年 | 5204篇 |
2019年 | 4703篇 |
2018年 | 4429篇 |
2017年 | 4155篇 |
2016年 | 5881篇 |
2015年 | 6247篇 |
2014年 | 7658篇 |
2013年 | 9746篇 |
2012年 | 11404篇 |
2011年 | 11602篇 |
2010年 | 8587篇 |
2009年 | 8512篇 |
2008年 | 8773篇 |
2007年 | 7952篇 |
2006年 | 7546篇 |
2005年 | 6619篇 |
2004年 | 4825篇 |
2003年 | 4027篇 |
2002年 | 3630篇 |
2001年 | 3102篇 |
2000年 | 2812篇 |
1999年 | 2936篇 |
1998年 | 2502篇 |
1997年 | 2169篇 |
1996年 | 2142篇 |
1995年 | 1900篇 |
1994年 | 1616篇 |
1993年 | 1340篇 |
1992年 | 1175篇 |
1991年 | 994篇 |
1990年 | 827篇 |
1989年 | 590篇 |
1988年 | 461篇 |
1987年 | 377篇 |
1986年 | 383篇 |
1985年 | 293篇 |
1984年 | 221篇 |
1983年 | 191篇 |
1982年 | 141篇 |
1981年 | 84篇 |
1980年 | 65篇 |
1979年 | 27篇 |
1978年 | 28篇 |
1976年 | 24篇 |
1975年 | 23篇 |
1957年 | 27篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
11.
Wang Rong Li Xu Zhou Youshi Cao Shuxuan Xu Honghao Han Wenjuan Zhang Yuxia Liu Junhai 《Journal of Russian Laser Research》2022,43(4):476-481
Journal of Russian Laser Research - We demonstrate a passively-mode-locked Pr3+: LuLiF4 laser operated at the 604 nm orange wave-length, using monolayer graphene as a saturable absorber. The... 相似文献
12.
13.
Jia Dai Xiang Cheng Xiaofeng Li Zhisheng Wang Yufeng Wang Jing Zheng Jun Liu Jiawei Chen Changjin Wu Jinyao Tang 《Advanced functional materials》2021,31(48):2106204
Synthetic active matters are perfect model systems for non-equilibrium thermodynamics and of great potential for novel biomedical and environmental applications. However, most applications are limited by the complicated and low-yield preparation, while a scalable synthesis for highly functional microswimmers is highly desired. In this paper, an all-solution synthesis method is developed where the gold-loaded titania-silica nanotree can be produced as a multi-functional self-propulsion microswimmer. By applying light, heat, and electric field, the Janus nanotree demonstrated multi-mode self-propulsion, including photochemical self-electrophoresis by UV and visible light radiation, thermophoresis by near-infrared light radiation, and induced-charge electrophoresis under AC electric field. Due to the scalable synthesis, the Janus nanotree is further demonstrated as a high-efficiency, low-cost, active adsorbent for water decontamination, where the toxic mercury ions can be reclaimed with enhanced efficiency. 相似文献
14.
Applied Mathematics and Mechanics - Spiral springs have a wide range of applications in various fields. As a result of the complexity of friction, few theoretical analyses of spring belts under... 相似文献
15.
Peng Li Haibin Jiang Ariel Barr Zhichu Ren Rui Gao Hua Wang Weiwei Fan Meifang Zhu Guiyin Xu Ju Li 《Advanced functional materials》2021,31(51):2105845
Mercury, lead, and cadmium are among the most toxic and carcinogenic heavy metal ions (HMIs), posing serious threats to the sustainability of aquatic ecosystems and public health. There is an urgent need to remove these ions from water by a cheap but green process. Traditional methods have insufficient removal efficiency and reusability. Structurally robust, large surface-area adsorbents functionalized with high-selectivity affinity to HMIs are attractive filter materials. Here, an adsorbent prepared by vulcanization of polyacrylonitrile (PAN), a nitrogen-rich polymer, is reported, giving rise to PAN-S nanoparticles with cyclic π-conjugated backbone and electronic conductivity. PAN-S can be coated on ultra-robust melamine (ML) foam by simple dipping and drying. In agreement with hard/soft acid/base theory, N- and S-containing soft Lewis bases have strong binding to Hg2+, Pb2+, Cu2+, and Cd2+, with extraordinary capture efficiency and performance stability. Furthermore, the used filters, when collected and electrochemically biased in a recycling bath, can release the HMIs into the bath and electrodeposit on the counter-electrode as metallic Hg0, Pb0, Cu0, and Cd0, and the PAN-S@ML filter can then be reused at least 6 times as new. The electronically conductive PAN-S@ML filter can be fabricated cheaply and holds promise for scale-up applications. 相似文献
16.
Xiaozhen Li Chao Yin Si Si Liew Chun-Sing Lee Kanyi Pu 《Advanced functional materials》2021,31(46):2106154
Optical imaging has played a pivotal role in deciphering in vivo bioinformatics but is limited by shallow penetration depth and poor imaging performance owing to interfering tissue autofluorescence induced by concurrent photoexcitation. The emergence of near-infrared (NIR) self-luminescence imaging independent of real-time irradiation has timely addressed these problems. There are two main kinds of self-luminescent agents, namely inorganic and organic luminophores. Inorganic luminophores usually suffer from long-term biotoxicity concerns resulting from potential heavy-metal ions leakage and nonbiodegradability, which hinders their further translational application. In contrast, organic luminophores, especially organic semiconducting luminophores (OSLs) with good biodegradable potential, tunable design, and outstanding optical properties, are preferred in biological applications. This review summarizes the recent progress of OSLs used in NIR afterglow, chemiluminescence, and bioluminescence imaging. Molecular manipulation and nanoengineering approaches of OSLs are discussed, with emphasis on strategies that can extend the emission wavelength from visible to NIR range and amplify luminescence signals. This review concludes with a discussion of current challenges and possible solutions of OSLs in the self-luminescence field. 相似文献
17.
18.
This study is to numerically test the interfacial instability of ferrofluid flow under the presence of a vacuum magnetic field. The ferrofluid parabolized stability equations(PSEs) are derived from the ferrofluid stability equations and the Rosensweig equations, and the characteristic values of the ferrofluid PSEs are given to describe the ellipticity of ferrofluid flow. Three numerical models representing specific cases considering with/without a vacuum magnetic field or viscosity are created to mathematically examine the interfacial instability by the computation of characteristic values. Numerical investigation shows strong dependence of the basic characteristic of ferrofluid Rayleigh-Taylor instability(RTI) on viscosity of ferrofluid and independence of the vacuum magnetic field.For the shock wave striking helium bubble, the magnetic field is not able to trigger the symmetry breaking of bubble but change the speed of the bubble movement. In the process of droplet formation from a submerged orifice, the collision between the droplet and the liquid surface causes symmetry breaking. Both the viscosity and the magnetic field exacerbate symmetry breaking. The computational results agree with the published experimental results. 相似文献
19.
20.
Reza Kordnezhadian Bing-Yu Li Armir Zogu Dr. Joachim Demaerel Prof. Dr. Wim M. De Borggraeve Dr. Ermal Ismalaj 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(60):e202201491
Pentafluorosulfanyl (SF5)-containing compounds and corresponding analogs are a highly valuable class of fluorine-containing building blocks owing to their unique properties. The reason for that is the set of peculiar and tremendously beneficial characteristics they can impart on molecules once introduced onto them. Despite this, their application in distinct scientific fields remains modest, given the extremely harsh reaction conditions needed to access such compounds. The recent synthetic approaches via S−F, and C−SF5 bond formation as well as the use of SF5-containing building blocks embody a “stairway-to-heaven” loophole in the synthesis of otherwise-inaccessible chemical scaffolds only a few years ago. Herein, we report and evaluate the properties of the SF5 group and analogs, by summarizing synthetic methodologies available to access them as well as following applications in material science and medicinal chemistry since 2015. 相似文献