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101.
Qin Zhu Lu Lin Rulin Qiu Prof. Dr. Jun Zhu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(24):5381-5387
Aromaticity is one of the most basic concepts in organic chemistry. The planar Möbius aromatic metallapentalynes and metallapentalenes have attracted considerable attention in the past few years. However, the aromaticity of metallapentalenes containing heteroatoms (such as B, N, and O), termed as hetero-metallapentalenes, is rarely studied. Herein, the stability and aromaticity of a series of hetero-metallapentalenes are theoretically investigated. The results reveal lower aromaticity in metallaborapentalene, comparable aromaticity in metallazapentalene, and nonaromaticity in metalloxapentalene relative to that of metallapentalene. Moreover, the effect of Lewis bases on the aromaticity and stability of metallaborapentalene is discussed. These results provide useful information for experimental chemists to realize more hetero-metallapentalenes. 相似文献
102.
Dr. Xiaoming Jie Dr. Qiu Sun Dr. Constantin G. Daniliuc Robert Knitsch Prof. Dr. Michael Ryan Hansen Prof. Dr. Hellmut Eckert Dr. Gerald Kehr Prof. Dr. Gerhard Erker 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(6):1269-1273
The active six-membered cyclo-FLP 6 undergoes a rapid P/B addition reaction to carbon dioxide. At elevated temperature, the resulting heterobicyclo[2.2.2]octane derived product 7 undergoes ring opening and equilibrates with the cyclotetramer (7)4 . In the large macrocyclic structure, four monomeric six-membered cyclo-FLP units are connected by four CO2 molecules to form the supramolecular ring system. The P/B cyclo-FLP 6 undergoes a variety of additional cycloaddition reactions. 相似文献
103.
Andreev Yu. A. Smirnov S. S. Zavyalova K. V. Xie Y. Qiu Y. 《Russian Physics Journal》2020,63(2):250-257
Russian Physics Journal - Comparative experimental investigations of combined and helical ultra-wideband antennas are performed. The antennas are optimized to be excited by the 1 ns bipolar voltage... 相似文献
104.
JingWei Wen XiaoCong Qiu XiangYu Kong XinYu Chen Fan Yang GuiLu Long 《中国科学:物理学 力学 天文学(英文版)》2020,(3):112-115
Quantum computing is an emerging and promising research field in modern quantum physics and is committed to accelerating traditional calculation processes using the principle of quantum mechanics[1,2].Several computation models have been proposed,including the circuit model[3],topologic quantum computation[4],adiabatic quantum computing[5],and duality quantum computing[6-8].Universal quantum computation generally includes a system initialization,evolutionary control,and a final-state readout[9],where the preparation of the initial state is a key step in the entire process. 相似文献
105.
Kun Chen Yong Cheng Yongzhi Chang Enqin Li Qing-Long Xu Can Zhang Xiaoan Wen Hongbin Sun 《Tetrahedron》2018,74(4):483-489
N-Substituted-3(10H)-acridones have been established as visible-light organic photocatalyst. These photosensitizers are efficient for oxidative coupling reaction of N-aryl tetrahydroisoquinolines with various nucleophiles. Notably, N-methyl-3(10H)-acridone (Ia) is stable and can be effectively prepared. It is a water-soluble and atom-economic catalyst, and thus holds promise for green chemical applications. Mechanistic studies confirm a single electron transfer (SET)-induced radical process and a rate-limiting step. Analysis of the photocatalytic reactivity?structure relationship reveals that the acridones are robust and tunable photosensitizers for photoredox catalysis. 相似文献
106.
Chen Chao Ji Kun 《高校应用数学学报(英文版)》2007,22(4):393-404
In this paper,a nonlinear nonautonomous predator-prey dispersion model with continuous distributed delay is studied,where all parameters are time-dependent.In this system consisting of n-patches the prey species can disperse among n-patches,but the predator species is confined to one patch and cannot disperse.It is proved that the system is uniformly persistent under any dispersion rate effect.Furthermore,some sufficient conditions are established for the existence of a unique almost periodic solution of the system.The example shows that the criteria in the paper are new,general and easily verifiable. 相似文献
107.
Existence of the perfect transmission resonances of spin waves in a one-dimensional Thue–Morse magnonic quasicrystal is proposed. We find that occurrence of the perfect transmission just corresponds to the repeated bandedges in the bandedge map. Frequencies at the perfect transmissions for system with arbitrary generation order can be predicted by the bandedge map of the second and third order systems using two iterative schemes. These results show that density of the perfect transmission resonance increases exponentially for increasing the order of the system. However, the perfect transmissions are kept for higher order systems even if the peaks become denser. 相似文献
108.
109.
In this paper, we show the following result: Let K
i
be a knot in a closed orientable 3-manifold M
i
such that (M
i
,K
i
) is not homeomorphic to (S
2 ×S
1, x
0 ×S
1), i = 1, 2. Suppose that the Euler Characteristic of any meridional essential surface in each knot complement E(K
i
) is less than the difference of one and twice of the tunnel number of K
i
. Then the tunnel number of their connected sum will not go down. If in addition that the distance of any minimal Heegaard
splitting of each knot complement is strictly more than 2, then the tunnel number of their connected sum is super additive. 相似文献
110.
Miao-Kun Wang Yu-Ming Chu Song-Liang Qiu Yue-Ping Jiang 《Journal of Approximation Theory》2012,164(7):928-937
In this paper, we present several bounds for the perimeter of an ellipse, which improve some well-known results. 相似文献