Inclusion complexes of alcohols with α-cyclodextrin

Calorimetric studies of the inclusion complexes of straight and branched alcohols and of diols with alpha-cyclodextrin (-CD) have been carried out in water solvent. The data suggest that straight and branched chain alcohols enter the cavity of -CD alkyl end first. The hydroxyl group hydrogen bonds to the outer oxygen ring of the cyclodextrin. For branched chain alcohols the longer alkyl part of the molecule penetrates the -CD cavity up to the hydroxyl group. Diols form two hydrogen bonds to the outer oxygen ring of the cyclodextrin with some penetration into its interior.     

Simultaneous determination of uric acid, xanthine and hypoxanthine with an electrochemically pretreated carbon paste electrode

A simple method is presented for the simultaneous differential pulse voltammetric determination of uric acid, xanthine and hypoxanthine. It is based on the improved current responses of the three analytes at carbon paste electrodes polarized in a dilute alkaline medium (0.002 mol/l NaOH, 0.1 mol/l NaClO₄) at 1.3 V vs. SCE for a short time. Compared with the methods reported in the literature, this procedure has a much wider linear range (2 to 3 orders of magnitude in concentration), lower detection limits (5 to 10 g l^–1) and less interference by ascorbic acid. The electrochemical responses were found to be dependent on the pre-anodization potential and the time imposed on the electrodes as well as on the alkalinity of the supporting electrolyte. The proposed procedure was used to determine uric acid, xanthine and hypoxanthine in human urine without any preliminary treatment.     

An exponent bound on skew Hadamard abelian difference sets

A difference setD in a groupG is called a skew Hadamard difference set (or an antisymmetric difference set) if and only ifG is the disjoint union ofD, D(^–1), and {1}, whereD(^–1)={d^–1|dD}. In this note, we obtain an exponent bound for non-elementary abelian groupG which admits a skew Hadamard difference set. This improves the bound obtained previously by Johnsen, Camion and Mann.     

基于点云空间分布特征的多级索引结构北大核心CSCD

为解决点云数据分布不规则、非均匀产生的查询效率低下的问题,提出了一种基于三维点云数据空间分布特征的多级索引结构。将点云空间信息引入传统八叉树,形成一种新的数据结构——方向八叉树,用于点云空间的全局划分。在每次划分空间之前,先对点云数据进行主成分分析,形成节点的方向包围盒,再进一步将空间划分为八个子空间。为了实现数据的快速调度与查询,在局部,使用KD树对方向八叉树的叶子节点进行二次组织构建。实验结果表明,方向八叉树能有效减少节点总数和冗余节点数量;方向八叉树和KD树的组合嵌套结构可以有效划分海量点云数据,实现点云数据的高效检索,对点云数据进行有效管理。     

碲锌镉晶体VGF法生长温场的梯度区高度设计研究北大核心CSCD

本文对不同梯度区高度的VGF法温场生长碲锌镉(CdZnTe)晶体过程进行了稳态和非稳态仿真模拟分析。研究发现,晶体生长等径初期界面凸度随着梯度区高度的增加而减小;等径末期界面凸度受梯度区高度的影响不大;界面的凸度与固液界面温度梯度变化率正相关。非稳态模拟结果显示,现有变温条件下,晶体生长过程中固液界面凸度存在先增大后减小的趋势,趋势转变点接近梯度区高度中点;界面形状的变化趋势受固液界面上生长速度分布直接影响;对比而言,10 cm高的梯度区更容易实现前中期固液界面凸界面的获得,利于形成高单晶率CdZnTe晶体。     

基于Transformer的实时语义分割网络及应用北大核心CSCD

为提升机器人对电缆隧道场景的环境感知能力,提出了一种适用于电缆隧道场景的实时语义分割网络。使用Transformer结构提取图像全局语义信息,同时使用卷积神经网络捕获图像局部细节信息,将二者结合增强图像分割精度。同时,针对机器人以及隧道特点,将语义分割结果转化为机器人前方目标信息以及机器人偏离情况信息,辅助机器人导航避障。实验结果表明,所提出的网络在公共数据集Cityscapes、CamVid上平均交叉联合度量分别为77.2%、76.8%,相比BiSeNet分别提高了8.8%、8.1%,并能较好地适应于实际电缆隧道环境中,提供有效的场景感知信息,实现自主避障。     

双层伞状开孔的微测辐射热计红外吸收分析

建立了具有伞状吸收层结构的微测辐射热计探测单元的红外吸收模型。基于光学导纳矩阵法和阻抗匹配理论,采用三维电磁仿真软件CST,对伞状结构不同开孔尺寸和形状下模型的红外吸收特性进行了分析。结果表明,双层伞状开孔微测辐射热计光学性能与伞状结构开孔大小有密切的关系。该伞状微测辐射热计中引入开孔后,在保持较高的红外吸收特性的基础上,减少了探测单元热容,从而提升了器件响应速度。最终所得探测单元在8~14μm红外波段内的平均吸收率为85%,满足超大规模小像元非致冷红外焦平面探测器的设计要求。