增强型GaN绝缘栅HEMT线性电荷控制解析模型

基于MIS理论和含极化的泊松方程,应用费米能级与二维电子气密度线性近似,并考虑计入了绝缘体/AlGaN界面的陷阱或离子电荷,导出建立了适用于增强型且兼容耗尽型AlGaN/GaN绝缘栅HEMT的线性电荷控制解析模型。研究表明,Insulator/AlGaN界面陷阱密度在1013cm-2数量级;基于该模型的器件转移特性的理论结果与器件的实测转移特性数据比较符合。该模型可望用于器件性能评估和设计优化。     

Synthesis,Crystal Structure,Spectroscopic Property and Redox Behavior of Zinc(Ⅱ) Complexes Containing Oligoaniline-functionalized Terpyridine Ligands

Two novel mono-nuclear zinc(Ⅱ) complexes with oligoaniline-functionalized terpyridine ligands have been synthesized and verified by 1H-NMR,13C-NMR,Elemental Analysis (EA) and X-ray Diffraction (XRD). The UV-vis spectra show the ligand-centered (LC) π-π* transitions and intra-ligand charge transfer (1ILCT) transitions,and the 1ILCT band red-shifts with the increasing number of aromatic amine groups in the ligands. Complex [Zn(L1)2](PF6)2 with an aromatic amine group in ligand shows a strong emission peak at 523 nm in the MeCN solution at 293 K and a blue-shifted band at 517 nm in the alcoholic glass at 77 K. However,for complex [Zn(L2)2](PF6)2 containing aniline dimer modified ligand,no apparent emission can be observed in the MeCN solution at room temperature due to a PET non-radiative decay pathway. Both of them show multiplicate redox processes based on oligoaniline and terpyridine units. The shifts of redox potentials also reflect the D-A interactions between the oligoaniline units and [Zn(TPY)2]2+ core.     

Synthesis,Crystal Structure and Characterizations of New 3,4,7,8-Tetrachloro-1,10-Phenanthroline Zn(II) Complex

Abstract  

A novel 3,4,7,8-tetrachloro-1,10-phenanthroline (Cl₄phen) Zn(II) complex has been synthesized. The complex, [Zn(Cl₄phen)₂(H₂O)₂](NO₃)₂·CH₃CH₂OH (1), has been identified and characterized by single crystal X-ray diffraction, elemental analysis, FT-IR, thermogravimetric analysis and photoluminescence studies. Single crystal X-ray diffraction analysis reveals that complex (1) belongs to the monoclinic system, space group P2(1)/c, a = 10.061(2) Å, b = 18.924(4) Å, c = 18.189(4) Å, β = 100.94(3)°, and Z = 4. Complex (1) consists of cationic species [Zn(Cl₄phen)₂(H₂O)₂]²⁺, NO₃ ⁻ and CH₃CH₂OH. The zinc atom displays a distorted cis-N₄O₂ octahedral geometry. Via extended Zn–O–H···O–N–O···H–O–Zn bridge, every mononuclear unit is linked with other ones to form one-dimensional (1D) infinite chain of hydrogen bond system. Three-dimensional (3D) polymeric network arrangement was built via weak C–H···O and π-stacking interactions between Cl₄phen moieties. A solvent-dependency effect of complex (1) was observed in spectroscopic properties.     

活性炭负载硅钼钒杂多酸催化苯羟基化反应

以活性炭为载体,采用回流吸附法制备了负载型硅钼钒杂多酸催化剂,以冰醋酸作溶剂,过氧化氢作氧化剂,研究了由苯直接羟基化制苯酚的催化活性。结果表明,苯为2mL,冰醋酸为15mL,过氧化氢为5mL,当负载型杂多酸的用量为0.2g、反应温度70℃、反应时间60m in时,硅钼钒催化合成苯酚的收率可达7.4%,选择性达97.1%。     

双波长高精度红外测温仪

利用双波长红外测温方法,通过黑体红外辐射曲线中双波长等比吸收的原理消除了由于辐射环境中水蒸气等外界吸收原因造成的单波长红外测温仪中的测量误差,实现更稳定的高精度红外测温.该方法绕开了传统红外测温方法中"辐射率修正困难"的问题.同时利用此红外测温仪器改进了金属钨电子逸出功测量实验.     

Q-switched mode-locking femtosecond all-fiber laser based on Er3+/Yb3+ codoped phosphate fiber

A Q-switched mode-locking femtosecond all-fiber laser based on a 2 cm long homemade Er³⁺/Yb³⁺ codoped phosphate glass fiber has been reported. By using the nonlinear polarization evolution technique, a nearly 100% modulation depth of mode-locking pulse train is achieved. At a pump power of 410 mW, the energy of each Q-switched envelope, whose width is about 220 μs, is 10 μJ, while the duration of mode-locking pulse within the Q-switched envelope is 318-fs.     

一类广义幂零群

This paper considers such a group G which possesses nontrivial proper subgroups H 1 ,H 2 such that any proper subgroup of G not contained in H 1 ∪ H 2 is p-closed and obtains that if G is soluble,then the number of prime divisors contained in ｜G｜ is 2,3 or 4;if not,then it has a form x N where N/Φ（N） is a non-abelian simple group.Then the structure of such a group is determined for p = 2,H 1 = H 2 under some conditions.     

60 GHz Radio over Fiber Technology for Wireless Access by employing Narrow-Angle PSK Modulation

This paper investigates two key techniques used in 60 GHz Radio over Fiber (RoF) technology for wireless access, namely, the generation of 60 GHz signals and the distribution of 60 GHz local oscillator (LO). In the proposed model, a 60 GHz PSK signal is generated by a heterodyne of two subcarriers with narrow-angle PSK (NA-PSK) modulation, whose phase shift is equal to one half that of a normal PSK signal. Then we use a 60 GHz mixer to frequency mix two PSK signals in two different bands, 60 GHz and baseband. By doing this, the modulation information can be fully eliminated, resulting in a 60 GHz LO. In the wireless terminal, coherent demodulation is realized by a self-mixing of the transmitted 60 GHz PSK signal and LO. Thus no millimeter-wave (mm-wave) band oscillator is needed in the wireless terminal.     

Z箍缩等离子体X射线凸晶谱仪

 针对波长为0.3~0.5 nm的喷气箍缩等离子体X射线诊断,研制了一种适用的高空间分辨的晶体谱仪。色散元件采用云母（002）凸面晶体,布拉格角为37°,信号采用X射线胶片进行接收,有效接收面积为30 mm×80 mm。物理实验在“阳”加速器装置上进行,胶片获得了氩喷气K,L壳层光谱信号,其光谱范围较宽,为0.31~0.40 nm。经解谱发现,类氦谱线有明显的基底,用最小二乘法拟合包络曲线去噪处理后,得到类氦谱线光谱分辨力为200~300。实验结果表明,该谱仪获得的X射线测量值与理论值相符,适合喷气箍缩等离子体X射线光谱的诊断。     

图形处理器并行计算用于离子发动机粒子模拟

 为了研究离子发动机羽流对航天器的影响,采用质点网格-蒙特卡罗碰撞方法对离子发动机羽流中的交换电荷离子进行了模拟。利用计算设备统一架构技术,开发出一套基于图形处理器的并行粒子模拟程序。随机数生成采用并行MT19937伪随机数生成器算法,电场方程使用完全近似存储格式的代数多重网格法求解。r-z轴对称坐标系中,在z=0 m处获得的电流密度均值为4.5×10^-5 A/m²,图形处理器所得结果与中央处理器模拟结果吻合。在16核心的NVIDIA GeForce 9400 GT图形显示卡上,取得相对于Intel Core 2 E6300中央处理器4.5~10.0倍的加速比。