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281.
282.
微波萃取花生壳天然黄色素及其稳定性研究 总被引:19,自引:0,他引:19
对福建产花生壳进行了微波萃取天然黄色素及其稳定性的研究 .研究表明微波萃取的工艺条件是 :以pH =3,体积分数 70 %的乙醇水溶液作提取剂 ,原料与提取剂配比为 1g∶5mL ,微波辐射功率为 12 0W ,辐射时间2 4 0s.对该色素稳定性研究结果表明 ,该色素为水溶性色素 ,属黄酮类色素 ,适用pH值范围比较宽 ,尤其碱性状态效果最佳 ,对光、热稳定性好 ,大多数食品添加剂对色素稳定性影响不大 ,对氧化剂H2 O2 的耐受能力较差 ,对还原剂Na2 SO3 的耐受能力强 相似文献
283.
采用溶剂热法制备了石墨烯/SnO_2(G/SnO_2)纳米材料,利用扫描电子显微镜(SEM)、X射线衍射(XRD)、拉曼光谱(Raman)等对G/SnO_2进行了表征,研究了石墨烯的量和溶剂热温度对该纳米材料气敏性能的影响。实验结果表明,石墨烯可以调节SnO_2晶体的生长:当石墨烯上清液的量为1 mL、热处理温度为160℃时,制备的G/SnO_2纳米材料在室温下对氨气具有较好的气敏选择性和较高的灵敏度;且当气体体积浓度为1 000μL·L~(-1)时,对NH3的灵敏度为266.4,检出限达到了0.01μL·L~(-1)。 相似文献
284.
Nanosized surface-enhanced Raman scattering (SERS) substrates fabricated by the controlled growth of metal nanostructures on water-dispersed two-dimensional nanomaterials can open a new avenue for SERS analysis of liquid samples in biological fields. In this work, regular and uniform Ag nanostructures were grown on the surface of graphene oxide (GO) through a microwave-assisted hydrothermal method. Polyamidoamine (PAMAM) dendrimers were assembled on the surface of GO to form GO/PAMAM templates for growing Ag nanostructures, which are primarily comprised of Ag dimers and trimers. The prepared Ag/GO nanocomposites are highly dispersed and stable in aqueous solution and may be used as substrates for enhanced Raman detection of rhodamine 6?G (R6G) in aqueous solution. This special substrate provides high-performance SERS and suppresses R6G fluorescence in aqueous solution and is promising as a nanosized material for the enhanced Raman detection of liquid samples in biological diagnostics. 相似文献
285.
Yuliang Li Nan Zhang Shuai Xu Qi Zhu Jing Hu 《Journal of Dispersion Science and Technology》2019,40(6):874-883
In this article, the equilibrium behavior of solutions of 1-ethyl-3-methylimidazolium dimethyl phosphate ([Emim]DMP) and ethyl acetate or acetone in aqueous two-phase system (ATPS) was discussed to understand the liquid–liquid equilibrium (LLE) behavior of these organic solvents. Thus, we determined phase diagrams and LLE data at 303.15, 308.15, 313.15, and 323.15 K for the investigated biphasic systems. Four empirical equations were used to study the tie lines. The results showed that for the [Emim]DMP?+?acetone?+?water biphasic systems within the investigated temperature range, temperature influences the phase behavior, but for the [Emim]DMP?+?ethyl acetate?+?water biphasic systems within the investigated temperature range, there are no notable changes on the phase behavior with rising temperature. The results may have important applications for the separation of antibiotics and for the recovery of ionic liquids (ILs). 相似文献
286.
Bing-Jie Zhang Wen-Na Xiao Jing Chen Mei-Fen Bao Johann Schinnerl Qi Wang Xiang-Hai Cai 《Tetrahedron》2019,75(38):130515
Continued interest in Erythrina alkaloids resulted in the isolation of 38 alkaloids including 7 undescribed ones from the leaves of Erythrina arborescens Roxburgh. Among the new compounds, erythrivarines H-I were two dimeric alkaloids, while others were Erythrina alkaloid glucosides. Dimeric Erythrina alkaloids and monomers, turcomanidine and isoboldine, showed medium xanthine oxidase inhibition. 相似文献
287.
Nan Zhang Ming‐Yu Qi Lan Yuan Xianzhi Fu Zi‐Rong Tang Jinlong Gong Yi‐Jun Xu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(29):10108-10112
The efficiency of solar hydrogen evolution closely depends on the multiple electrons accumulation on the catalytic center for two‐electron‐involved water reduction. Herein, we report an effective approach to enable broadband light absorption and unidirectional electron flow for efficiently accumulating electrons at active sites for hydrogen evolution by rationally engineering the nanostructure of Pt nanoparticles (NPs), TiO2, and SiO2 support. In addition to Schottky‐junction‐driven electron transfer from TiO2 to Pt, Pt NPs also produce hot electrons by recycling the scattered visible and near‐infrared (vis‐NIR) light of the support. Unidirectional electron flow to active sites is realized by tuning the components spatial distribution. These features collectively accumulate multiple electrons at catalytic Pt sites, thereby affording enhanced activity toward hydrogen evolution under simulated sunlight. 相似文献
288.
Qi Xiao Jingjing Tian Qifan Xue Jing Wang Bijin Xiong Mengmeng Han Zhen Li Zonglong Zhu Hin‐Lap Yip Zhong'an Li 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(49):17888-17894
Development of high‐performance dopant‐free hole‐transporting materials (HTMs) with comprehensive passivation effects is highly desirable for all‐inorganic perovskite solar cells (PVSCs). Squaraines (SQs) could be a candidate for dopant‐free HTMs as they are natural passivators for perovskites. One major limitation of SQs is their relatively low hole mobility. Herein we demonstrate that polymerizing SQs into pseudo two dimensional (2D) p–π conjugated polymers could overcome this problem. By rationally using N,N‐diarylanilinosquaraines as the comonomers, the resulting polysquaraine HTMs not only exhibit suitable energy levels and efficient passivation effects, but also achieve very high hole mobility close to 0.01 cm?2 V?1 s?1. Thus as dopant‐free HTMs for α‐CsPbI2Br‐based all‐inorganic PVSCs, the best PCE reached is 15.5 %, outperforming those of the doped‐Spiro‐OMeTAD (14.4 %) based control devices and among the best for all‐inorganic PVSCs. 相似文献
289.
Mykola Telychko Jie Su Aurelio Gallardo Yanwei Gu Jesús I. Mendieta‐Moreno Dongchen Qi Anton Tadich Shaotang Song Pin Lyu Zhizhan Qiu Hanyan Fang Ming Joo Koh Jishan Wu Pavel Jelínek Jiong Lu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(51):18764-18770
The ability to use mechanical strain to steer chemical reactions creates completely new opportunities for solution‐ and solid‐phase synthesis of functional molecules and materials. However, this strategy is not readily applied in the bottom‐up on‐surface synthesis of well‐defined nanostructures. We report an internal strain‐induced skeletal rearrangement of one‐dimensional (1D) metal–organic chains (MOCs) via a concurrent atom shift and bond cleavage on Cu(111) at room temperature. The process involves Cu‐catalyzed debromination of organic monomers to generate 1,5‐dimethylnaphthalene diradicals that coordinate to Cu adatoms, forming MOCs with both homochiral and heterochiral naphthalene backbone arrangements. Bond‐resolved non‐contact atomic force microscopy imaging combined with density functional theory calculations showed that the relief of substrate‐induced internal strain drives the skeletal rearrangement of MOCs via 1,3‐H shifts and shift of Cu adatoms that enable migration of the monomer backbone toward an energetically favorable registry with the Cu(111) substrate. Our findings on this strain‐induced structural rearrangement in 1D systems will enrich the toolbox for on‐surface synthesis of novel functional materials and quantum nanostructures. 相似文献
290.
Three multinuclear Cu (II), Zn (II) and Cd (II) complexes, [Cu2(L)(μ‐OAc)]·CHCl2 ( 1 ), [Zn2(L)(μ‐OAc)(H2O)]·3CHCl3 ( 2 ) and [{Cd2(L)(OAc)(CH3CH2OH)}2]·2CH3CH2OH ( 3 ) with a single‐armed salamo‐like dioxime ligand H3L have been synthesized, and characterized by FT‐IR, UV–vis, X‐ray crystallography and Hirshfeld surfaces analyses. The ligand H3L has a linear structure and C‐H···π interactions between the two molecules. The complex 1 is a dinuclear Cu (II) complex, Cu1 and Cu2 are all five‐coordinate possessing distorted square pyramidal geometries. The complex 2 also forms a dinuclear Zn (II) structure, and Zn1 and Zn2 are all five‐coordinate bearing distorted trigonal bipyramidal geometries. The complex 3 is a symmetrical tetranuclear Cd (II) complex, and Cd1 is a hexa‐coordinate having octahedral configuration and Cd2 is hepta‐coordinate with a pentagonal bipyramidal geometry, and it has π···π interactions inside the molecule. In addition, fluorescence properties of the ligand and its complexes 1 – 3 have also been discussed. 相似文献