LaSrBO4型复合氧化物的合成及其CO氧化活性研究

LaSrBO4(B=Cu、Ni、 Co、 Fe、 Mn、 Cr ) was studied with respect to their preparation, characteristics and catalytic oxidation activity by means of XRD, XPS, electric conductivity and activity evaluation. Results showed that the calcination temperature has great influence on the formation of the phases of such samples, and was associated with the radius of B ion. The greater the B ion radius, the higher the calcination temperature required for the formation of the phases. It was also found that the activity and the relative content of adsorptive oxygen and lattice oxygen on the sample surf are, the activation energy of electron conduction and the CO oxidation activity may vary with different B ions, and demonstrate a dual-peak pattern with the increase in the number of 3d electrons of the B ion.     

Numerical blow-up analysis of the explicit L1-scheme for fractional ordinary differential equations

Numerical Algorithms - This paper deals with the blow-up behavior of numerical solutions to nonlinear fractional ordinary differential equations with a dissipative term. Based on the positivity...     

A Review of Results on Axially Symmetric Navier-Stokes Equations,with Addendum by X. Pan and Q. Zhang

In this paper, we give a brief survey of recent results on axially symmetric Navier-Stokes equations (ASNS) in the following categories: regularity criterion, Liouville property for ancient solutions, decay and vanishing of stationary solutions. Some discussions also touch on the full 3 dimensional equations. Two results, closing of the scaling gap for ASNS and vanishing of homogeneous D solutions in 3 dimensional slabs will be described in more detail.In the addendum, two new results in the 3rd category will also be presented, which are generalizations of recently published results by the author and coauthors.     

一种扇区投影和滑窗连线的特征提取方法

针对点云特征线提取中不均匀点、不明显特征点和特征线断裂的问题,提出了一种扇区投影和滑窗连线的特征提取方法。该方法首先对点云进行全局密度分析,计算平均点间距,然后采用扇区投影法统计扇区内邻近点的分布情况,由分布情况确定点云模型边界点,进而计算局部三角形法线,根据法线突变情况判断尖锐折边点,在扇区投影的基础上延伸局部探线,根据不同的探线类型制定判断非尖锐折边点的相关策略,最后基于滑窗连线的方法,将无序特征点有序连接,得到光滑特征线。实验证明,该方法可以较完整地提取模型的特征线,同时具有一定的抗噪能力。对比其他两种方法,本文方法对模型中的弱特征更敏感,提取效果相对较好。     

基于显著性检测的星载嵌入式跟踪系统

随着航天科技的不断发展,计算机视觉算法在卫星上的应用方兴未艾,为了实现更多的功能需求和应对可能的威胁,视觉目标跟踪作为其中基础但具有挑战性的任务更是至关重要。然而,目前已有的目标跟踪算法大多数算法只限于对图像序列进行跟踪。另一方面,受到硬件条件制约,很多优秀的算法因为复杂度较高很少被应用到星载嵌入式系统中。这些目标跟踪算法运行时,通常需要人为地给出目标的边界框。为了自动得到边界框,需要目标检测算法对输入图像进行运动目标检测。本文提出了一种基于显著性检测和相关滤波的单目标检测与跟踪一体化算法,并与嵌入式系统相结合,在搭载的TMS320C6678芯片上达到了2 048 pixel×2 048 pixel分辨率下24 fps的帧率。具体地,检测算法负责对图像进行预处理并获得边界框,然后目标跟踪算法给出目标在后续帧中的位置。为了验证算法在实际跟踪中的有效性,本研究搭建了一个由相机、DSP和云台组成的光学平台并进行了实验验证。在该系统中,DSP自动完成检测、跟踪、驱动云台和再检测任务,达到了很好的检测跟踪效果。     

Promote Intratumoral Drug Release and Penetration to Counteract Docetaxel-Induced Metastasis by Photosensitizer-Modified Red Blood Cell Membrane-Coated Nanoparticle

The red blood cell membrane (RBCm) provides tight protection, lowers the immunogenicity, and prolongs the circulation time of drugs in vivo when acting as the coating of drug delivery systems. However, the cellular uptake and release of drugs are hindered by RBCm. Docetaxel (DTX) is the first-line medicine for treating triple-negative breast cancer (TNBC), but it induces tumor metastasis. To solve these dilemmas, in this study, the photosensitizer 1,1-dioctadecyl-3,3,3,3-tetramethylindotricarbocyanine iodide (DiR)-modified RBCm (DM) is prepared, which is coated onto a hybrid micelle consisting of the prodrugs of DTX and the anti-metastasis agent calcitriol (CTL), obtaining a nanoparticle, named HDC-DM. In a 4T1 tumor-bearing mouse model, after injecting HDC-DM, the intratumoral DTX and CTL concentrations are increased by 1.7 and 2.5 times compared with the free drug groups. After irradiating tumors with near-infrared laser, DiR elicits the photothermal effect, triggering the rupture of RBCm and drug release, promoting drug penetration in tumors, and inducing immunogenic cell death. The tumor growth inhibition rate is 77%, and the formation of lung metastases is reduced by 82%, with good biocompatibility. It is suggested that the combination of phototherapy, chemotherapy, and anti-metastatic therapy using HDC-DM is expected to be a powerful strategy for treating TNBC.     

Challenges and Opportunities of Implantable Neural Interfaces: From Material,Electrochemical and Biological Perspectives

The desirable implantable neural interfaces can accurately record bioelectrical signals from neurons and regulate neural activities with high spatial/time resolution, facilitating the understanding of neuronal functions and dynamics. However, the electrochemical performance (impedance, charge storage/injection capacity) is limited with the miniaturization and integration of neural electrodes. The “crosstalk” caused by the uneven distribution of elctric field leads to lower electrical stimulation/recording efficiency. The mismatch between stiff electrodes and soft tissues exacerbates the inflammatory responses, thus weakening the transmission of signals. Though remarkable breakthroughs have been made through the incorporation of optimizing electrode design and functionalized nanomaterials, the chronic stability, and long-term activity in vivo of the neural electrodes still need further development. In this review, the neural interface challenges mainly on electrochemistry and biology are discussed, followed by summarizing typical electrode optimization technologies and exploring recent advances in the application of nanomaterials, based on traditional metallic materials, emerging 2D materials, conducting polymer hydrogels, etc., for enhancing neural interfaces. The strategies for improving the durability including enhanced adhesion and minimized inflammatory response, are also summarized. The promising directions are finally presented to provide enlightenment for high-performance neural interfaces in future, which will promote profound progress in neuroscience research.     

Hydrofluoric Acid-Removable Additive Optimizing Electrode Electrolyte Interphases with Li+ Conductive Moieties for 4.5 V Lithium Metal Batteries

High-voltage lithium metal batteries (LMBs) are capable to achieve the increasing energy density. However, their cycling life is seriously affected by unstable electrolyte/electrode interfaces and capacity instability at high voltage. Herein, a hydrofluoric acid (HF)-removable additive is proposed to optimize electrode electrolyte interphases for addressing the above issues. N, N-dimethyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl) aniline (DMPATMB) is used as the electrolyte additive to induce PF₆⁻ decomposition to form a dense and robust LiF-rich solid electrolyte interphase (SEI) for suppressing Li dendrite growth. Moreover, DMPATMB can help to form highly Li⁺ conductive Li₃N and LiBO₂, which can boost the Li⁺ transport across SEI and cathode electrolyte interphase (CEI). In addition, DMPATMB can scavenge traced HF in the electrolyte to protect both SEI and CEI from the corrosion. As expected, 4.5 V Li|| LiNi_0.6Co_0.2Mn_0.2O₂ batteries with such electrolyte deliver 145 mAh g⁻¹ after 140 cycles at 200 mA g⁻¹. This work provides a novel insight into high-voltage electrolyte additives for LMBs.