季铵盐改性蒙脱石的制备与表征

采用十六烷基三甲基氯化铵(CTAC)对钠基蒙脱石(MMT)进行季铵化改性,制备有机蒙脱石(CMMT),对改性后的蒙脱石进行X射线衍射(XRD)、电位分析法(PA)、红外光谱(FT-IR)和热分析(TGA)等分析表征,并用改性后的蒙脱石吸附五氟尿嘧啶(5-FU)后测定并比较其载药量.结果表明,改性剂已成功插入到蒙脱石的层间;相比于钠基蒙脱石,有机蒙脱石的层间距和热稳定性均有所增大;当制备季铵盐有机改性蒙脱石时,反应温度为80℃,且CTAC的用量是MMT的2.5倍阳离子交换容量时,形成的有机蒙脱石的阳离子化程度和对5-FU的载药量最高.此外,考察并比较了有机蒙脱石和钠基蒙脱石的体外细胞毒性,结果显示有机蒙脱石具有更好的生物相容性和更低的细胞毒性.     

THE REFORM OF AERODYNAMICS CURRICULUM IN VIEW OF INNOVATION AND ENGINEERING PRACTICE

目前国内针对高等院校的创新创业教育改革正在稳固推进,与此相关的空气动力学课程体系教学改革也在积极落实。但由于我校在改革初期机械地照搬名校的成功经验,只注重课程体系本身的教学改革,对课程体系之外的外部因素关注度并不高,导致改革的成效不明显。本文从学生和教师两个层面对影响我校空气动力学课程体系教学改革的外部因素进行归纳和研究,并有针对性地提出因地制宜的解决办法。     

La1-x CaxAl0.8Cr0.2O3/CaZrO3(0≤x≤0.2)复相陶瓷材料发射率的研究

以La2O3、Al2O3、ZrO2、Cr2O3、CaCO3为原料,通过高温固相反应法制备La1-xCaxAl0.8 Cr0.2O3/CaZrO3(0≤x≤0.2)复相陶瓷材料,分别通过XRD、SEM和EDS等仪器对试样的物相组成和显微结构进行分析,利用紫外可见近红外分光光度计测量其红外吸收曲线.结果 表明:当CaZrO3理论生成量和La1-xCaxAl0.8Cr0.2O3的摩尔比小于0.20时复相陶瓷材料在0.76～2.5 μm的发射率较La0.8 Ca0.2Al0.8Cr0.2O3得到进一步提高,当CaZrO3理论生成量和La1-xCaxAl0.8Cr0.2O3的摩尔比为0.04时发射率最佳.     

茚三酮光度法测定加巴喷丁

加巴喷丁是一种抗癫痫新药,为1-（氨基甲基）-环己烷乙酸。其测定方法从结构上分析可以用非水滴定法,文献[2]报道用高效液相色谱法（衍生化后）,加巴喷丁可见光区无吸收,紫外光区吸收太小,文献[3]中未见茚三酮显色法测定加巴喷丁的报道,此法适用于痕量加巴喷丁的测定。     

New conversion of Friendlnder reaction of 3-amino-1H-benzo[f]chromene-2-carbonitriles with cyclohexanone

Two different skeletons of heterocyclic compounds,quinoline and quinazolinone analogs could be obtained by a novel one-pot synthesis from substituted 3-amino-1 H-benzo[f]chromene-2-carbonitrile derivatives and cyclohexanone in DMF in the catalyst of anhydrous zinc chloride under reflux.A plausible mechanism was proposed.     

Vapor-phase synthesis of V-butylaniline from aniline and 1-butanol over Cu/SiO2 catalyst

The Cu/SiO2 catalyst prepared by incipient wetness method exhibited very high activity and selectivity for the vapor-phase synthesis of JV-butylaniline from aniline and 1-butanol. When Cu loading was 0.70 mmol/g-SiO2 and the catalyst precursor was calcined at 500 ℃, 1-butanol conversion reached 99%, and the selectivity of JV-butylaniline exceeded 97%.     

Synthesis of polypyridyl ruthenium complexes with 2-(1-aryl)-1H-imidazo[4,5-f]-1,10-phenanthroline ligand and its application for luminescent oxygen sensing

Polypyridyl ruthenium (Ru) complexes 1–3 were prepared. Their photophysical properties were investigated by UV-Vis absorption and luminescence emission spectra. The luminescent lifetimes of these Ruthenium complex were prolonged by more than 5 folds (τ = 2.50 μs for complex 3) when compared with the parent Ru complex 1 (τ = 0.45 μs). We propose that the extended luminescent lifetime of complex 3 is due to the equilibrium between ³MLCT state and the pyrene localized ³π-π* triplet state (³IL). The luminescent O₂-sensing property of the complexes in solution and the IMPEK-C polymer film were studied, and the O₂ sensing was quantified with the two-site model. The oxygen-sensing property of the Ru complexes can be improved by 104-fold with extension of the luminescent lifetimes. For example, the quenching constant K _SV was improved from 0.0023 Torr⁻¹ of 1 to 0.2393 Torr⁻¹ for 3. Our results demonstrated a versatile approach for the preparation of Ru (II) polypyridine complexes with extended luminescent lifetimes as functional materials, for example, for luminescent oxygen-sensing applications.     

一种合成N-苯基苯并咪唑的新方法

成功开发出一种直接合成N-苯基苯并咪唑的新方法.在不使用金属催化剂与强碱的条件下,通过苯并咪唑与二苯基碘三氟甲磺酸盐的反应合成了目标化合物,采用1H NMR与13C NMR技术对目标化合物进行了表征,并确定了最佳反应条件.在苯并咪唑与二苯基碘三氟甲磺酸盐的物质的量比为1∶1.2、溶剂乙醇/二甲苯的体积比为1∶4、反应温度为120℃、反应时间为24h的最佳反应条件下,使目标化合物的产率达到了52.0％,并回收了等量的碘苯.此外,通过高效液相色谱技术进行跟踪监测,对该反应的机理进行了探讨.     

岩石爆破破碎时间及微差起爆延时优化

利用分形理论分析岩石爆破的破碎时间，提出了岩石爆破破碎时间的计算方法和微差起爆延时优化的一种途径。     

GCr15钢-CVDCr_7C_3镀层摩擦副摩擦振动的研究

本文系统地研究了GCr15钢球-CVDCr_7C_3镀层钢盘摩擦副滑动干摩擦引起的摩擦力(切向力)振动特性及其对材料摩擦磨损性能的影响。试件系统在垂直和水平方向上均处于低刚度、小阻尼状态。试验信号由微机采集、处理并进行频谱分析。结果表明,摩擦力振动的类型与正压力有关,而与拖动速度无关;摩擦力呈周期性自持振动时具有与相对滑动速度典型的非线性关系,振动频率接近(略低)于系统在切向的固有频率,而与拖动速度无关;摩擦力呈非平稳随机振动时,振动频率与系统在法向的振动频率有关,而与系统在切向的固有频率及拖动速度都无关;摩擦偶件运动的平稳性与摩擦力振动的类型有关,而与平均摩擦系数无关;摩擦力所耗费的能量与正压力呈比例关系。