全文获取类型
收费全文 | 309篇 |
免费 | 19篇 |
国内免费 | 5篇 |
专业分类
化学 | 198篇 |
晶体学 | 1篇 |
力学 | 4篇 |
数学 | 27篇 |
物理学 | 54篇 |
无线电 | 49篇 |
出版年
2024年 | 2篇 |
2023年 | 3篇 |
2022年 | 21篇 |
2021年 | 33篇 |
2020年 | 19篇 |
2019年 | 24篇 |
2018年 | 21篇 |
2017年 | 14篇 |
2016年 | 16篇 |
2015年 | 23篇 |
2014年 | 15篇 |
2013年 | 23篇 |
2012年 | 20篇 |
2011年 | 22篇 |
2010年 | 10篇 |
2009年 | 13篇 |
2008年 | 14篇 |
2007年 | 8篇 |
2006年 | 4篇 |
2005年 | 4篇 |
2003年 | 2篇 |
2002年 | 3篇 |
2000年 | 4篇 |
1999年 | 3篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1987年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1975年 | 2篇 |
排序方式: 共有333条查询结果,搜索用时 62 毫秒
51.
Issa Yavari S. Zahra Sayyed-Alangi Maryam Sabbaghan Rahimeh Hajinasiri Nasir Iravani 《Monatshefte für Chemie / Chemical Monthly》2008,139(9):1025-1028
An efficient one-pot synthesis of functionalized thioureas is described via three-component reaction of benzoyl isothiocyanates, secondary amines, and alkyl propiolates in the presence of triphenylphosphine
(20 mol%).
Correspondence: Issa Yavari, Chemistry Department, Tarbiat Modares University, PO Box 14115-175, Tehran, Iran 相似文献
52.
Qassim Nasir 《International Journal of Electronics》2016,103(4):736-746
The objective of this work is to analyse the performance of the newly proposed two-tap FIR digital filter-based first-order zero-crossing digital phase-locked loop (ZCDPLL) in the absence or presence of additive white Gaussian noise (AWGN). The introduction of the two-tap FIR digital filter widens the lock range of a ZCDPLL and improves the loop’s operation in the presence of AWGN. The FIR digital filter tap coefficients affect the loop convergence behaviour and appropriate selection of those gains should be taken into consideration. The new proposed loop has wider locking range and faster acquisition time and reduces the phase error variations in the presence of noise. 相似文献
53.
Akhtar Hayat Amina Rhouati Rupesh K. Mishra Gustavo A. Alonso Muhammad Nasir Georges Istamboulie 《International journal of environmental analytical chemistry》2016,96(3):237-246
Herein, we reported a titanium oxide (TiO2) modified activated carbon nanocomposite that showed advantageous characteristics in terms of electro-conductivity, catalytic activity and surface area. The designed nanocomposite was employed to modify the screen printed carbon electrode transducer surface in the construction of an electrochemical sensor. The electrode surface modification was characterised by cyclic voltammetry and impedimetric studies. The modified transducer surface was subsequently used for the detection of four phenolic endocrine disruptors, p-nitrophenol, hydroquinone, catechol and 1-naphtol. Under optimal conditions, TiO2 modified activated carbon sensor was evaluated by differential pulse voltammetry showing a good linearity with correlation coefficients higher than 0.99. It showed, in parallel, a high sensitivity where the detection limits were 348 ng/L, 110.1 ng/L, 3.3 ng/L and 7.2 µg/L for the respective studied compounds (S/N = 3). Finally, we validated the method with river water samples, and good recovery values were obtained showing the potential application of the reported biosensor. 相似文献
54.
Open‐Pore Two‐Dimensional MFI Zeolite Nanosheets for the Fabrication of Hydrocarbon‐Isomer‐Selective Membranes on Porous Polymer Supports
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Han Zhang Prof. Qiang Xiao Prof. Xianghai Guo Prof. Najun Li Prashant Kumar Neel Rangnekar Mi Young Jeon Prof. Shaeel Al‐Thabaiti Prof. Katabathini Narasimharao Prof. Sulaiman Nasir Basahel Prof. Berna Topuz Frank J. Onorato Prof. Christopher W. Macosko Prof. K. Andre Mkhoyan Prof. Michael Tsapatsis 《Angewandte Chemie (International ed. in English)》2016,55(25):7184-7187
Two‐dimensional zeolite nanosheets that do not contain any organic structure‐directing agents were prepared from a multilamellar MFI (ML‐MFI) zeolite. ML‐MFI was first exfoliated by melt compounding and then detemplated by treatment with a mixture of H2SO4 and H2O2 (piranha solution). The obtained OSDA‐free MFI nanosheets disperse well in water and can be used for coating applications. Deposits made on porous polybenzimidazole (PBI) supports by simple filtration of these suspensions exhibit an n‐butane/isobutane selectivity of 5.4, with an n‐butane permeance of 3.5×10?7 mol m?2 s?1 Pa?1 (ca. 1000 GPU). 相似文献
55.
A novel antimicrobial flavonoid from the stem bark of Commiphora pedunculata (Kotschy & Peyr.) Engl.
Nasir Tajuddeen Muhammad S. Sallau Aliyu M. Musa Sani M. Yahaya James D. Habila Abdullahi Musa Ismail 《Natural product research》2016,30(10):1109-1115
A new flavonoid, 2-(3,5-dihydroxy-4-methoxy-phenyl)-3,5-dihydroxy-8,8-dimethyl-2,3-dihydro-8H-pyrano[3,2]chromen-4-one, together with previously reported epicatechin was isolated from the ethyl acetate soluble fraction of the methanol extract of the stem bark of Commiphora pedunculata. The structures of these compounds were elucidated based on extensive analysis of their spectral data, including 1 and 2D NMR. The compounds were active against 9 out of 12 tested microorganisms including a resistant strain; vancomycin-resistant entrococci (VRE), Escherichia coli, Staphylococcus aureus and Candida albicans. The zones of inhibition ranged between 22 and 34 mm against the microorganisms. The minimum inhibitory concentration was as low as 6.25 μg/mL against Shigella dysentriae, Bacillus cereus and S. aureus while the minimum bactericidal concentration was as low as 50 μg/mL against Pseudomonas aeruginosa, VRE and C. albicans. This is the first report of the isolation of the compound. 相似文献
56.
57.
58.
Priya Malpani Kishore Thapliyal Nasir Alam Anirban Pathak Venkatakrishnan Narayanan Subhashish Banerjee 《Annalen der Physik》2019,531(11)
Quantum phase properties of photon added and subtracted displaced Fock states (and their limiting cases) are investigated from a number of perspectives, and it is shown that the quantum phase properties are dependent on the quantum state engineering operations performed. Specifically, the analytic expressions for quantum phase distributions and angular Q distribution as well as measures of quantum phase fluctuation and phase dispersion are obtained. The uniform phase distribution of the initial Fock states is observed to be transformed by the unitary operation (i.e., displacement operator) into non‐Gaussian shape, except for the initial vacuum state. It is observed that the phase distribution is symmetric with respect to the phase of the displacement parameter and becomes progressively narrower as its amplitude increases. The non‐unitary (photon addition/subtraction) operations make it even narrower in contrast to the Fock parameter, which leads to broadness. The photon subtraction is observed to be a more powerful quantum state engineering tool in comparison to the photon addition. Further, one of the quantum phase fluctuation parameters is found to reveal the existence of antibunching in both the engineered quantum states under consideration. Finally, the relevance of the engineered quantum states in the quantum phase estimation is also discussed. 相似文献
59.
This paper describes the peristaltic motion of a non-Newtonian fluid in a channel having compliant boundaries. Constitutive equations for a Maxwell fluid have been used. Perturbation method has been used for the analytic solution. The influence of pertinent parameters is analyzed. Comparison of the present analysis of Maxwell fluid is made with the existing results of viscous fluid. 相似文献
60.
Haidawati Nasir Vladimir Stanković Stephen Marshall 《Signal Processing: Image Communication》2012,27(2):180-191
In this paper, we address a super-resolution problem of generating a high-resolution image from low-resolution images. The proposed super-resolution method consists of three steps: image registration, singular value decomposition (SVD)-based image fusion and interpolation. The contribution of this work is two-fold. First we customize an image registration approach using Scale Invariant Feature Transform (SIFT), Belief Propagation and Random Sampling Consensus (RANSAC) for super-resolution. Second, we propose SVD-based fusion to integrate the important features from the low-resolution images. The proposed image registration and fusion steps effectively maintain the important features and greatly improve the super-resolution results. Results, for a variety of image examples, show that the proposed method successfully generates high-resolution images from low-resolution images. 相似文献