Enhanced Catalytic Hydrogen Evolution Reaction in Phosphorene Nanosheet via Cobalt Intercalation

Searching alternatives to Pt-based catalyst for producing hydrogen via water splitting has gathered enormous attention to develop renewable energy. Phosphorene has been investigated widely for its large surface area, low cost, and high carrier mobility, however, the poor activity in hydrogen evolution reaction (HER) and low conductivity limit its practical application. Herein, on the basis of first-principles calculations, we demonstrate that the catalytic HER in phosphorene can be enhanced significantly with cobalt intercalations. The Co-intercalated phosphorene is metallic with charge transfer from Co atoms to phosphorene, which could enhance the catalytic activity of phosphorene. In addition, the calculated Gibbs free energy of hydrogen adsorption on Co-intercalated phosphorene bilayer is comparable to that on Pt(111) surface, independent of the degree of hydrogen coverage. Our study implies that the Co intercalation provides an effective approach to enhance the catalytic HER inphosphorene.     

北京谱仪III上利用神经网络方法进行粒子鉴别的研究

本文描述了一种多层感知器的神经网络系统在BESIII粒子鉴别技术中的应用。网络按照子探测器分别进行训练, 输出结果可以作为后续网络的输入或者可以为似然函数方法构建概率密度函数。蒙特卡罗模拟样本的检验结果表明, 利用神经网络方法可以在BESIII上获得较好的粒子鉴别效果。     

Space-Selective Precipitation of Ba2TiSi2O8 Crystals in Sm3^＋-Doped BaO-TiO2-SiO2 Glass by Femtosecond Laser Irradiation

The ferroelectric crystal Ba2TiSi2O8 with high second-order optical nonlinearity is precipitated in Sm^3＋-doped BaO-TiO2-SiO2 glass by a focused 800hm, 250 kHz and 150fs femtosecond laser irradiation. No apparent blue and red emissions are observed at the beginning, while strong blue emission due to second harmonic generation and red emission due to the f-f transitions of Sm^3＋ are observed near the focal point of the laser beam after irradiation for 25s. Micro-Raman spectra confirm that Ba2 TiSi2O8 crystalline dots and lines are formed after laser irradiation. The mechanism of the phenomenon is discussed.     

Stationary Fluid Dynamic Behaviour of V-Shaped Diffuser/Nozzle Elements for Valveless Micropump

A novel type of V-shaped （isosceles triangle cross-section） diffuser/nozzle element is proposed for use for valveless micropump. Stationary fluid dynamic behaviour of V-shaped diffuser/nozzle elements in a valveless micropump is investigated by experiment and simulation. Both the results agree well with each other when the Reynolds number is higher than 100 and the pressure loss coefficient ratio of micropump nearly always keeps a constant. For a single V-shaped diffuser, the general trends of variation of pressure loss coefficient with opening angle and Reynolds number are opposite in small and large angles. Compared with conical and flat-wall diffusers, V-shaped diffuser shows the smallest pressure loss when the Reynolds number is 200.     

Blue-to-Orange Tunable Luminescence from Europium Doped Yttrium--Silicon--Oxide--Nitride Phosphors

Europium-doped yttrium-silicon-oxide-nitride phosphors are synthesized by carbothermal reduction and nitridation method. The crystal structure of the phosphors changed gradually from oxide Y2Si2O7 to nitride YSi3N5 state with increasing dosage of Si3N4 and carbon powder. The Y2Si2O7：Eu phosphor shows a blue emission at 465 nm with 300 nm excitation and a characteristic red emission of Eu^3＋ at 612 nm with 230 nm excitation. The YSi3N5：EU phosphor shows a broad emission band centred at 595nm with some sharp peaks of Eu^3＋ with 325nm excitation. The absorption of the studied phosphors increases from 450 to 700hm with an increment in nitrogen content. Blue-to-orange tunable luminescence is observed with 390 nm excitation.     

Tunable Photonic Crystal Mach--Zehnder Interferometer Based on Self-collimation Effect

A theoretical model for tunable Mach--Zehnder interferometers (TMZIs) constructed in a two-dimensional photonic crystal (2D PhC) is proposed. The 2D PhC consists of a square lattice of cylindric air holes in silicon. The TMZI includes two mirrors and two splitters. Light propagates between them employing a self-collimation effect. The two interferometer branches have different path lengths. Parts of the longer branch are infiltrated with a kind of liquid crystal (LC) with ordinary and extraordinary refractive indices 1.522 and 1.706, respectively. The transmission spectra at two TMZI output ports are in the shape of sinusoidal curves and have a uniform peak spacing 0.0017c/a in the frequency range from 0.26c/a to 0.27c/a. When the effective refractive index n_eff of the liquid crystal is increased from 1.522 to 1.706, the peaks shift to the lower frequencies over 0.0017c/a while the peak spacing is almost kept unchanged. Thus this TMZI can work as a tunable power splitter or an optical switch. For the central operating wavelength around 1550nm, its dimensions are only about tens of micron. Thus this device may be applied to photonic integrated circuits.     

1 MV紧凑型重频Marx发生器绝缘设计和数值分析

通过分析六氟化硫气体在静态高电压和脉冲高电压作用下的绝缘特性对Marx模块式开关结构和外筒尺寸进行了优化设计,着重优化设计了Marx发生器中的两个关键绝缘部位——开关腔体结构和外金属筒与顶部电容绝缘距离,并通过数值模拟计算,分析了该区域的局部3维电场强度分布。结果表明:最大场强均小于六氟化硫的沿面闪络和电击穿场强阈值。对模块式开关腔和外筒尺寸进行优化得到的绝缘结构满足0.3 MPa下六氟化硫的绝缘要求。     

微光像增强器荧光屏测试系统的研究

为了评价微光像增强器在封装前各组成部分的性能,设计并研制了微光像增强器荧光屏测试系统。阐明测试系统的构成以及设计的关键技术,采用数学建模的方法确定热电子发射源的形状。研究了亮度均匀性校正,给出荧光屏发光均匀性、亮度、发光效率和余辉的测试方法。该仪器可以广泛应用到各种型号的荧光屏的研究和生产领域。     

一种激光平行分束器的设计

为满足波面剪切干涉和双细光束干涉曲反射表面非接触精密测量、台阶高度测量以及其他平行分光需要,利用双折射晶体特性,研究并设计了一种单一平板激光平行分束器。当一束激光入射到双折射晶体时,它的2个相互正交的的偏振分量将有不同的折射特性,因此特定晶轴方向和厚度的晶体平行平板可以实现入射光束的平行分束。描述了双折射晶体平行平板的分束原理,推导了分束距离与光轴方向、晶体厚度、入射角的关系,分析了分束距离随主要设计参数的变化规律。采用设计的晶体激光分束器进行了实验测试,验证了分析与实测结果的一致性。     

一种批量化T/R组件盒体成型工艺研究

通过一种批量化T/R组件盒体的成型工艺试验和分析,采用压铸工艺,选用合适的压铸铝合金材料、合理的工艺措施,同时解决电磁兼容、散热、三防等关键技术,满足总体设计要求。