Enantioselective Total Synthesis of (+)‐Steenkrotin A and Determination of Its Absolute Configuration

The first enantioselective total synthesis of (+)‐steenkrotin A has been achieved in 18 steps and 4.2 % overall yield. The key features of the strategy entail a Rh‐catalyzed O?H bond insertion followed by an intramolecular carbonyl‐ene reaction, two sequential SmI₂‐mediated Ueno–Stork and ketyl–olefin cyclizations, and a cascade intramolecular aldol condensation/vinylogous retro‐aldol/aldol process with inversion of the relative configuration at the C7 position. The absolute configuration of (+)‐steenkrotin A was determined based on the stepwise construction of the stereocenters during the total synthesis.     

Synthesis,Characterization, and Electronic Structures of Porphyrins Fused with Polycyclic Aromatic Ring Systems

A series of porphyrins fused with acenaphthylene, phenanthroline, and benzofluoranthene polycyclic aromatic rings were prepared by means of a 3+1 porphyrin synthesis approach and subsequent retro‐Diels–Alder reaction of bicyclo[2.2.2]octadiene‐fused precursors. Analysis of the magnetic circular dichroism spectra and the results of time‐dependent DFT calculations are used to identify the reasons for the trends observed in the wavelengths and relative intensities of the Q bands of the products. Michl's perimeter model is used as a conceptual framework to explain the changes in the relative energies of the frontier π‐molecular orbitals.     

基于空间统计模型的热带气旋路径模拟及其风险评估

该研究致力于建立台风路径模拟模型,目的在于提高风险评估的稳健性和实用性。首先,采用中国台风网提供的CMA-STI热带气旋最佳路径数据集,以广东省为研究区域,通过引入空间统计模型,结合马尔可夫—蒙特卡罗方法模拟了西北太平洋的热带气旋路径。进一步,参数和非参数假设检验结果表明模拟结果是合理的,可以作为风险评估的数据来源。在此基础上,本研究模拟出620年的台风路径,给出了以地级市为基础的重现期估计和风险图绘制方法。研究发现,模拟数据克服了历史数据的时空局限性,与历史数据相比较,基于模拟数据估计的重现水平更具准确性和稳定性;其次,采用模拟方法还可以绘制出历史数据无法实现的大比例风险图,很大程度上提高了风险评估的实用性.研究结果可以作为保险行业开展巨灾保险业务,政府部门制定防灾减灾规划的科学依据.     

考虑运动受限的履带式移动机器人轨迹跟踪控制

针对履带式移动机器人的轨迹跟踪控制问题进行研究,首先,建立了履带式移动机器人的运动学模型和跟踪误差模型；其次,设计了转速有限时间控制和线速度滑模控制的轨迹跟踪控制律,并给出了考虑运动受限作用下的控制律修正表达式；最后,基于MATLAB对所提控制律进行仿真,对比分析了不考虑运动受限情况下跟踪控制效果;结果表明,设计的跟踪控制律能够实现履带式移动机器人对圆轨迹的有效跟踪,且考虑运动受限作用的控制律更加符合实际;文章研究分析了运动受限作用对于移动机器人轨迹跟踪控制的影响,分析结果对其他移动机器人的运动控制研究具有参考价值。     

Design of Millimeter-wave Rectangular Waveguide to HMSIW Transition Based on Trapezoidal-shaped Probe

In this letter, a compact rectangular waveguide-to-half mode substrate integrated waveguide (HMSIW) transition is presented. It uses a trapezoidal-shaped probe to couple the energy from rectangular waveguide to HMSIW. A back-to-back test module at Ka-band is fabricated and measured. It provides a return loss better than 15 dB and an insertion loss of 0.85 to 1.3 dB within a frequency range from 25 to 40 GHz. The circuit size of the proposed transition is reduced by approximately 81.8% as compared with the waveguide-to-HMSIW transition using antipodal fin-line. Additionally, no intermediate transition is needed for this transition, which simplify the design of transition circuit. The measurement results agree well with simulation results, which validate the feasibility of the transition. Also, a tolerance analysis is performed via the simulation to verify the reliability of this transition design.     

A New Synthesis for Methyl 2-Benzyloxylphenylacetate

A new synthetic method for methyl 2-benzyloxylphenylacetate, a key intermediate of a new type of fungicides, had been found, which has only 3 steps. The 80% yield of the new method is a major improvement over the 30% 6-step-process reported by the literature.