Thermal study of accumulation of conformational disorders in the self-assembled monolayers of C8 and C18 alkanethiols on the Au111 surface

The thermal stability of short alkanethiol CH(3)(CH(2))(7)SH (C(8)) and long C(18) self-assembled monolayers (SAMs) is investigated using grazing angle reflection-absorption infrared spectroscopy, cyclic voltammetry, and molecular dynamics simulation. We track the disordering of SAM by untilting and gauche defect accumulation with increasing temperature in the 300-440 K range, a range of interest to tribology. Molecular dynamics simulation with both fully covered and partially covered C(6), C(8), and C(18) monolayers brings out the morphological changes in the SAM, which may be associated with the observed thermal stability characteristics. The molecular dynamics simulations reveal that short-chain C(6) and C(8) alkanethiols are more defective at lower temperature than the long-chain C(18) alkanethiol. With increasing temperature disorder in the SAM, as reflected in both untilting and gauche defect accumulation, tends to saturate at temperatures below 360 K for short-chain SAMs such that any further increase in temperature, until desorption, does not lead to any significant change in conformational order. In contrast the disorder in the long-chain C(18) SAM increases monotonically with temperature beyond 360 K. Thus, in a practical range of temperature, the ability of a SAM to retain order with increasing thermal perturbations is governed by the state of disorder prior to heat treatment. This deduction derived from molecular dynamics simulation helps to rationalize the significant difference we have observed experimentally between the thermal response of short- and long-chain thiol molecules.     

Performance comparison of battery power consumption in wireless multiple access protocols

Energy efficiency is an important issue in mobile wireless networks since the battery life of mobile terminals is limited. Conservation of battery power has been addressed using many techniques such as variable speed CPUs, flash memory, disk spindowns, and so on. We believe that energy conservation should be an important factor in the design of networking protocols for mobile wireless networks. In particular, this paper addresses energy efficiency in medium access control (MAC) protocols for wireless networks. The paper develops a framework to study the energy consumption of a MAC protocol from the transceiver usage perspective. This framework is then applied to compare the performance of a set of protocols that includes IEEE 802.11, ECMAC, PRMA, MDRTDMA, and DQRUMA*. The performance metrics considered are transmitter and receiver usage times for packet transmission and reception. The time estimates are then combined with power ratings for a Proxim RangeLAN2 radio card to obtain an estimate of the energy consumed for MAC related activities. The analysis here shows that protocols that aim to reduce the number of contentions perform better from an energy consumption perspective. The receiver usage time, however, tends to be higher for protocols that require the mobile to sense the medium before attempting transmission. The paper also provides a set of principles that could be applied when designing access protocols for wireless networks.*ECMAC: energyconserving MAC. PRMA: packet reservation multiple access. MDRTDMA: multiservices dynamic reservation TDMA. DQRUMA: distributedqueuing request update multiple access.     

Weak edge-degree domination in hypergraphs

In this paper we extend the notion of weak degree domination in graphs to hypergraphs and find relationships among the domination number, the weak edge-degree domination number, the independent domination number and the independence number of a given hypergraph.     

Molecular Cloning,Characterization, and Expression Analysis of Lignin Genes from Sugarcane Genotypes Varying in Lignin Content

Sugarcane (Saccharum spp.) is one of the highest biomass-producing plant and the best lignocellulosic feedstock for ethanol production. To achieve more efficient conversion of biomass to ethanol, a better understanding of the main factors affecting biomass recalcitrance is needed. Therefore, with this objective, here, we report a systematic study on lignin content, deposition, identification, and cloning of genes involved in lignin biosynthesis and their differential expression in five sugarcane clones, EC11003, EC11010, IK 76-91, IK 76-99, and Co 86032. Lignin content among the clones varied from 26.87 to 23.19 % with the highest in the clone EC11010 and the lowest in high sugar Co86032. Lignin deposition studied through phloroglucinol staining of the cell walls implied that the sclerenchyma cells of the energy canes (EC11010 and EC11003) have more lignin deposition followed by the Erianthus (IK 76-91 and IK 76-99) clones whereas Co86032 has the minimum amount of lignin deposition. We cloned partial coding regions of important genes of lignification COMT (650 bp), CCR (332 bp), and PAL (650 bp) from Erianthus, wild relative of sugarcane followed by the expression analysis through real-time PCR. Differential expression analysis showed high level of expression for the three genes in the energy cane EC11010.     

Speeding up Exponentiation using an Untrusted Computational Resource

We present protocols for speeding up fixed-base variable-exponent exponentiation and variable-base fixed-exponent exponentiation using an untrusted computational resource. In the fixed-base protocols, the exponent may be blinded. In the variable-base protocols, the base may be blinded. The protocols are described for exponentiation in a cyclic group. We describe how to extend them to exponentiation modulo an integer where the modulus is the product of primes with single multiplicity. The protocols provide a speedup of over the square-and-multiply algorithm, where k is the bitlength of the exponent. One application of the protocols is to speed up exponentiation-based verification in discrete log-based signature and credential schemes. The protocols also allow signature verifiers to dynamically choose, for each message, the amount of work it would like to perform to verify the signature. This results in a work-security tradeoff. We introduce a fifth protocol to perform variable-base variable- exponent exponentiation, which also has this feature. Our model allows the trusted resource to perform computations in its idle time. The protocols facilitate the offloading of work to the offline stage, such that the work the trusted resource performs when it has to do an exponentiation is smaller. Our protocols are unconditionally secure.     

Fast Intra-Network and Cross-Layer Handover (FINCH) for WiMAX and Mobile Internet

To support fast and efficient handovers in mobile WiMAX, we propose Fast Intra-Network and Cross-layer Handover (FINCH) for intradomain (intra-CSN) mobility management. FINCH is a complementary protocol to Mobile IP (MIP), which deals with interdomain (inter-CSN) mobility management in mobile WiMAX. FINCH can reduce not only the handover latency but also the end-to-end latency for MIP. Paging extension for FINCH is also proposed to enhance the energy efficiency. The proposed FINCH is especially suitable for real-time services in frequent handover environment, which is important for future mobile WiMAX networks. In addition, FINCH is a generic protocol for other IEEE 802-series standards. This is especially beneficial for the integration of heterogeneous networks, for instance, the integration of WiMAX and WiFi networks. Both mathematical analysis and simulation are developed to analyze and compare the performance of FINCH with other protocols. The results show that FINCH can support fast and efficient link layer and intradomain handovers. The numerical results can also be used to select proper network configurations.     

Modeling and Analysis of On-Chip Single and H-tree Distributed RLC Interconnects

This paper presents novel methods for modeling and analysis of on-chip Single and H-tree distributed resistance inductance capacitance interconnects. The matrix pade-type approximation and scaling and squaring methods are employed for the numerical estimation of delay in single interconnect, and H-tree interconnects. The proposed models, which are based on these methods, provide rational function approximation for obtaining a passive interconnect model. Multiple single input single output model approximated transfer functions are developed for H-tree interconnects structure. With the equivalent reduced order lossy interconnect transfer functions, finite ramp responses are obtained, and line delay is estimated for various line lengths, input ramp rise times, source resistances, parasitic capacitances and load capacitances. In order to demonstrate the accuracy of proposed models, the estimated 50 % delay values are compared with the standard HSPICE W-element model and are found to be in good agreement. The proposed models worst case 50 % delay errors of single interconnect are 0.27 and 0.24 % respectively, while the worst case 50 % delay errors of H-tree structure are 5.73 and 3.94 % respectively.