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361.
J.S Yadav B.V.Subba Reddy M Srinivas A Prabhakar B Jagadeesh 《Tetrahedron letters》2004,45(31):6033-6036
2,3-Dihydro-4H-pyran-4-ones derived from d-glucal undergo rapid condensation with aryl hydrazines in the presence of montmorillonite KSF clay under mild conditions to afford a novel class of chiral 5-substituted pyrazoles in good yields with high selectivity. The stereochemical assignments of the products were achieved by NMR studies. 相似文献
362.
N. Suryakiran P. Prabhakar K. Rajesh V. Suresh Y. Venkateswarlu 《Journal of molecular catalysis. A, Chemical》2007,270(1-2):201-204
Facile and an efficient synthesis of β-keto-sulfones is described by the reaction of α-haloketone with sodium alkyl/aryl sulphinates in ionic liquid [TPA][Pro] as an efficient and reusable reaction medium to afford the corresponding β-keto-sulfones in excellent yields. 相似文献
363.
David L. Vander Meulen Prabhakar Misra Jason Michael Kenneth G. Spears Mustafa Khoka 《Photochemistry and photobiology》1992,56(3):325-332
Liposomes made from phospholipids and containing sulforhodamine dye (1-50 mM) have been irradiated with nanosecond and picosecond laser pulses. Individual liposomes were locally heated by laser absorption of dye dimers during a single laser pulse, and heating was sufficient to release the liposome contents. The extent of dye release produced by a single laser pulse was shown to be quantitatively dependent on several interdependent variables, including dye concentration, liposome size, laser excitation parameters and initial temperature of the dye-liposome system. Fluorescence lifetime data having three components have been obtained and analyzed in terms of three dye environments. Quantitative estimates support a photo-induced thermal mechanism for liposome lysis and release of its contents. These results may be useful for laser induced delivery of therapeutic agents or other applications of lasers in biological systems. 相似文献
364.
A one-pot, multicomponent-type, solvent-free Pd(II)-catalyzed direct β-C-H activation/arylation of carboxamides involving anhydrides as substrates via in situ installation of directing group (DG) is reported. Typically, the DG-assisted β-C-H activation/arylation of carboxamides is a two-step process comprising the installation of DG and Pd(II)-catalyzed CH arylation. We attempted a multicomponent-type reaction comprising an anhydride, a DG (e.g. 8-aminoquinoline), an aryl iodide in the presence of the Pd(II) catalyst and an appropriate additive. Different anhydrides, DGs, aryl iodides, catalysts and additives were screened to reveal the scope of this multicomponent-type CH arylation reaction process and various β-C-H arylated carboxamides were obtained in satisfactory to good yields. 相似文献
365.
In the present quantum chemical study, the biogenesis of the cofactor topaquinone (TPQ) has been studied using hybrid density functional theory (B3LYP). The suggested mechanism is divided into six steps and incorporates the observation of four crystallized intermediates. The experimental suggestion that the formation of the Cu(II)-peroxy species is the rate-limiting step is consistent with the results of the present study. Before the formation of the Cu(II)-peroxy species, dioxygen is suggested to first bind at the equatorial position on the copper metal center. A mechanism for the critical O-O bond cleavage is suggested, and this step is found to be driven by an unusually large exothermicity. A complex, spin-forbidden formation of H(2)O(2) with and without the involvement of the copper metal center is discussed. The results are discussed in detail, and comparisons are made to experimental findings and suggestions. 相似文献
366.
Bhaskar G Chary MA Kumar MK Syamasundar K Vairamani M Prabhakar S 《Rapid communications in mass spectrometry : RCM》2005,19(11):1536-1544
The complexes of transition-metal ions (M2+, where M = Fe, Co, Ni, Cu, Zn, Cd, and Hg) with 2-acetylbenzimidazolethiosemicarbazone (L) are studied under electrospray ionization (ESI) conditions. The ESI mass spectra of Fe and Co complexes showed the complex ions corresponding to [M+2L-2H]+, and those of Ni and Zn complexes showed [M+2L-H]+ ions, wherein the metal/ligand ratio is 1:2 and the oxidation state of the central metal ion is +3 in the case of Fe and Co and +2 in the case of Ni and Zn. The Cd and Cu complexes showed preferentially 1:1 complex ions, i.e., [M+L-H]+ or [M+L+Cl]+, whereas Hg formed both 1:1 and 1:2 complex ions. During formation of the above complex ions one or two ligands are deprotonated after keto-enol tautomerism, depending on the nature and oxidation state of central metal ion. The structures and coordination numbers of the metal ions in the complex ions were studied by their collision-induced dissociation spectra and ion-molecule reactions with acetonitrile or propylamine in the collision cell. Based on these results it is concluded that Fe, Co, Ni and Zn form stable octahedral complexes, whereas tetrahedral or square planar complexes are formed preferentially for other metals. In addition, the Cu complex showed a [2L+2Cu-3H]+ ion with a Cu-Cu bond. 相似文献
367.
Goud TV Srinivasulu M Reddy VL Reddy AV Rao TP Kumar DS Murty US Venkateswarlu Y 《Chemical & pharmaceutical bulletin》2003,51(8):990-993
Two new bromotyrosine-derived metabolites (1, 2) have been isolated along with the known compounds 3,5-dibromo-4-methoxyphenylacetonitrile, 3-bromo-4-methoxyphenylacetonitrile, 3-bromo-4-hydroxyphenylacetonitrile, 1-hydroxyuracil, 1-methoxyhemibastadin 2, purpuramine H and a steroid 5alpha,8alpha-epidioxycholest-6-en-3beta-ol from the sponge Psammaplysilla purpurea. Compounds 1 and 2 were characterized by interpretation of their spectral data. The antibacterial activity of these compounds is summarized. 相似文献
368.
A series of complexes of Co(II) and Ni(II) with 2-(R)-3-(X)-substituted quinazoline-(3H)-4-ones, where R = methyl/phenyl and
X = furalamino, uramino and thiouramino have been synthesised and characterised by analytical, conductivity, thermal and magnetic,
infrared and electronic spectral data. Based on analytical and conductivity studies the stoichiometries of the complexes have
been established. Conductivity data also show that all these complexes are non-electrolytes. Infrared spectral data indicate
that all the ligands manifest neutral bidentate with both the metal ions. Geometries for the complexes have been proposed
based on electronic spectral data. Various electronic spectral parameters have been calculated for all the complexes and relevant
conclusions have been drawn with respect to the nature of bonds present in them. 相似文献
369.
The palladium(II)-promoted reaction of a variety of olefins and bromamine-T provided N-tosyl-2-substituted aziridines under mild conditions. Olefins bearing chiral appendages gave only a poor to modest diastereoselectivity. Appropriate deuterated olefins were selected to study the stereochemistry of the reaction. A Pd(IV) intermediate is proposed as the aziridinating species. 相似文献
370.
Aswathanarayana Srinivasa Putta Prabhakar Varma Vijaykumar Hulikal Kittappa M. Mahadevan 《Monatshefte für Chemie / Chemical Monthly》2008,139(2):111-115
Summary. Antimony sulfate was found to be on effective catalyst for the condensation reaction of indoles with carbonyl compounds at
room temperature. This catalyst is inexpensive, easily available and it was also found that this catalyst could be recovered
quantitatively and reused without much loss of catalytic activity. 相似文献