The control of lightning using lasers: properties of streamers and leaders in the presence of laser-produced ionization

This paper summarizes the research this team has performed over the past few years investigating laboratory electrical breakdown discharges in the presence of a plasma cylinder created by a single ultrashort laser pulse. This work is part of a feasibility study about the control of lightning using laser systems. Our experimental investigations have included discharges (i) in modest (30 cm) air gaps mediated by streamers, and (ii) in large (several meters) ambient air gaps for which the discharge took place through the formation of a leader, the mechanism relevant to large scale natural discharges such as lightning. In order to understand the observations, various physical models have been used, the main results of which are discussed in this paper. To cite this article: F. Vidal et al., C. R. Physique 3 (2002) 1361–1374.     

Metabolic studies on toxic compounds

Summary Two new aromatic acids, 3,4- and 3,5-dimethylhippuric acids, have been prepared by reacting acid chlorides of corresponding benzoic acids with sodium glycinate. Their physico-chemical properties and spectroscopic patterns (ultraviolet and infrared) have been described in this report as well as a method of identification by thin-layer chromatography.

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Zusammenfassung 3,4- und 3,5-Dimethylhippursäure, zwei neue aromatische Säuren, wurden durch Einwirkung der entsprechenden Benzoesäurechloride auf Natriumglycinat hergestellt. Ihre physikalisch-chemischen Eigenschaften, ihre UV- und IR-Spektren angegeben und ihr Nachweis durch Dünnschichtchromatographie beschrieben.

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Résumé Deux nouveaux acides aromatiques, les acides diméthyl-3, 4- et diméthyl-3, 5-hippuriques ont été synthétisés en faisant réagir les chlorides des acides benzoïques correspondants sur le glycinate de sodium. Leurs propriétés physico-chimiques et leurs caractéristiques spectroscopiques (dans l'ultraviolet et l'infrarouge) ont été décrites dans ce rapport ainsi qu'une méthode d'identification par Chromatographie sur couche mince.

     

Parallel synthesis and rapid photochemical screening of organosoluble Ru(II) photosensitizers

Ru(II) complexes of heteroaromatic ligands are photosensitizers of interest in such applications as photovoltaic cells. Their bulk preparation is tedious, time-consuming, and expensive. Their assessments, by measurement of the individual excited-state lifetimes, is incomplete and requires specialized equipment and expertise, as well as time. The identification of new, promising photosensitizers would, therefore, greatly benefit from any time- and cost-saving protocol, if absolute purity is not required for assessment. This paper details a protocol for the fairly rapid preparation, in parallel and on a small scale, of organosoluble Ru(II) complexes in a state ready for screening for photosensitization ability. The protocol was tested with a small set of bidentate ligands, generating 20 possible complexes, many of which are known. The protocol was found to produce predominantly the desired species in all cases except those with three different ligands. The batch screening results for the remaining 16 complexes were entirely consistent with those obtained with pure samples of the most promising materials prepared in bulk and were consistent with known photophysical properties.     

Quantitative analysis of positional isomers of triacylglycerols via electrospray ionization tandem mass spectrometry of sodiated adducts

Herein we report a reversed‐phase high‐performance liquid chromatography tandem mass spectrometry (RP‐HPLC/MS/MS) method for the analysis of positional isomers of triacylglycerols (TAGs) in vegetable oils. The fragmentation behavior of [M + X]⁺ ions (X = NH₄, Li, Na or Ag) was studied on a quadrupole‐time‐of‐flight (Q‐TOF) mass spectrometer under low‐energy collision‐induced dissociation (CID) conditions. Mass spectra that were dependent on the X⁺ ion and the nature and position of the acyl substituents were observed for four pairs of 'AAB/ABA'‐type TAGs, namely PPO/POP, OOP/OPO, LLO/LOL and OOL/OLO (where P is 16:0, palmitic acid; O is 18:1, oleic acid; and L is 18:2, linoleic acid). For the majority of [M + X]⁺ adducts, the loss of the fatty acid in the outer positions (sn‐1 or sn‐3) was favored over the loss in the central position (sn‐2), which enabled the determination of the fractional abundance of the isomers. Ratios of the intensity of fragment ions at various AAB/ABA compositions produced linear calibration curves with positive slopes, comparable to those obtained traditionally by ESI‐MS/MS of [M + NH₄]⁺ adducts. The only exceptions were the [M + Ag]⁺ adducts of the PPO/POP system, which produced calibration curves with negative slopes. Sodium adducts provided the most consistent level of isomeric discrimination for the TAGs studied and also offered the most convenience in that they required no additive to the mobile phase. Therefore, calibration curve data derived from [M + Na]⁺ adducts were applied to the quantification of TAG regioisomers in sunflower and olive oils. The regiospecific analysis showed that palmitic acid was typically located at positions sn‐1 or sn‐3, whereas unsaturated fatty acids, oleic and linoleic acids were mostly found at the sn‐2 position. Copyright © 2010 Crown in the right of Canada. Published by John Wiley & Sons, Ltd.     

A Tabu Search Heuristic for Resource Management in Naval Warfare

Effective utilization of scarce resources, in particular weapon resources, is a prominent issue in naval anti-air warfare. In this paper, defence plans are constructed to guide the allocation and scheduling of different types of defence weapons against anti-ship missiles, subject to various physical and operational constraints. To reduce the frequency of replanning, decision trees are considered to explicitly account, in a probabilistic manner, for all possible outcomes of a particular action. A construction heuristic is first developed to generate an initial tree. A tabu search heuristic then improves this tree through the removal or addition of defence actions, followed by update operations aimed at maintaining the consistency. Numerical results obtained on scenarios with an increasing number of threats show that substantial improvements, in terms of survivability of the ship, can be obtained in reasonable computation times using tabu search.