Connecting mem-models with classical theories

A family of mem-models, including the mem-dashpots, mem-springs, and most recently, mem-inerters, is emerging as a new and powerful way of capturing complex nonlinear behaviors of materials and systems under various types of dynamic loads involving different frequency, amplitude, and loading histories (e.g., hysteresis). Under the framework of nonlinear state-space representation and hybrid dynamical systems, mem-springs may be formulated to effectively represent an inherent degradation of material state. It is shown in this study, for the first time, how the absement (time integral of strain/displacement), a signature state variable for a mem-spring, can be connected with the damage variable, a key quantity in continuum damage mechanics. The generalized momentum (time integral of stress), on the other hand, is shown to be efficient in modeling strain ratcheting via the concept of mem-dashpot. It is also shown in this study, for the first time, how two formulations of the memcapacitive system models (for mem-springs) are special cases of the Preisach model.

     

Electrochemical adsorption properties and inhibition of copper corrosion in chloride solutions by ascorbic acid: experimental and theoretical investigation

In this study, the effect of ascorbic acid in the electrochemical behavior of copper has been investigated in 3.5 % NaCl solution using potentiodynamic polarization and electrochemical impedance spectroscopy. Current-potential curve and Nyquist diagrams were obtained in different concentrations of ascorbic acid. The surface morphology of copper after its exposure to 3.5 % NaCl solution with and without of ascorbic acid was examined by scanning electron microscopy. The obtained results show that ascorbic acid inhibits corrosion of copper in 3.5 % NaCl solution. The inhibition activity of ascorbic acid increases with a decrease in the concentration of ascorbic acid.     

Blaus?ure

Ohne Zusammenfassung     

Critical stresses in mechanochemical reactions

The rates of mechanochemical reactions are generally found to increase exponentially with applied stress. However, a buckling theory analysis of the effect of a normal stress on an adsorbate that is oriented perpendicularly to the surface that reacts by tilting suggests that a critical value of the stress should be required to initiate a mechanochemical reaction. This concept is verified by using density functional theory calculations to simulate the effect of compressing a homologous series of alkyl thiolate species on copper by a hydrogen-terminated copper counter-face. This predicts that a critical stress is indeed needed to initiate methyl thiolate decomposition, which has a perpendicular C–CH₃ bond. In contrast, no critical stress is found for ethyl thiolate with an almost horizontal C–CH₃ bond, while a critical stress is required to isomerize propyl thiolate from a trans to a cis configuration. These predictions are tested by measuring the mechanochemical reaction rates of these alkyl thiolates on a Cu(100) substrate by sliding an atomic force microscope tip over the surface and finding a critical stress of ∼0.43 GPa for methyl thiolate, ∼0.33 GPa for propyl thiolate, but no evidence of a critical stress for ethyl thiolate, in accord with the predictions. These results provide insights not only into mechanochemical reaction mechanisms on surfaces, but also on the origin of critical phenomena in stress-induced processes in general. It also suggests novel approaches to designing robust surface films that can resist wear and damage.

The rates of mechanochemical reactions are generally found to increase exponentially with applied stress.     

Untersuchung von Seifen

Ohne Zusammenfassung     

Standard ultraviolet daylight for nonextreme exposure conditions

The skin is exposed to ultraviolet radiation (UVR) from natural or artificial sources on a daily basis. The effects of chronic low dose exposure merit investigation, even when these effects are neither conspicuous nor clinically assessable. The purpose of the present study was to define a relative spectral UV irradiance that is representative of frequent nonextreme sun exposure conditions and therefore more appropriate for studies of the long-term and daily effects of solar UV on the skin. Solar spectral UV irradiance values were calculated for different dates and locations by using a radiative transfer model. The spectral irradiance values obtained when the solar elevation is lower than 45 degrees were averaged. An important feature is the dUVA (320-400 nm) to dUVB (290-320 nm) irradiance values ratio, which was found to be 27.3 for the overall average. When the months corresponding to extreme irradiance values (low or high) were excluded from the calculations, the dUVA to dUVB ratio ranged from 27.2 to 27.5. The mean spectral irradiance of the model presented here represents environmental UV exposure conditions and can be used both as a standard to investigate the biological effects of a nonextreme UVR and to assess the effectiveness of products for daily skin protection.