Pressurized Hot Water Extraction of anthocyanins from red onion: A study on extraction and degradation rates

Pressurized Hot Water Extraction (PHWE) is a quick, efficient and environmentally friendly technique for extractions. However, when using PHWE to extract thermally unstable analytes, extraction and degradation effects occur at the same time, and thereby compete. At first, the extraction effect dominates, but degradation effects soon take over. In this paper, extraction and degradation rates of anthocyanins from red onion were studied with experiments in a static batch reactor at 110 °C. A total extraction curve was calculated with data from the actual extraction and degradation curves, showing that more anthocyanins, 21-36% depending on the species, could be extracted if no degradation occurred, but then longer extraction times would be required than those needed to reach the peak level in the apparent extraction curves. The results give information about the different kinetic processes competing during an extraction procedure.     

A component tracking algorithm for accelerated and improved liquid chromatography-mass spectrometry method development

A method for tracking of sample components during liquid chromatography-mass spectrometry (LC-MS) method development has been proposed. The method manages to, fully automatically and without user intervention, find the chromatographic peaks in the data sets, discriminate them to sample components and track them when the separation conditions have been changed. The algorithm utilises the resolution obtained from all considered data sets and has the ability to discriminate the non informative parts. The technique has a great sensitivity even in cases where a majority of the tracked components cannot easily be spotted by means of traditional total ion chromatogram (TIC) or base peak chromatogram (BPC) representations. The method was tested on an experimental sample using six different columns and an average of 79% of the suggested sample components could be successfully tracked at a minimum area of 0.05% of the main component in the sample. 66 components with 79-92% of the total suggested component area were able to be tracked between all data sets. The method could be used to rapidly investigate selectivity during different types of separation conditions.     

Hypercyclic sequences of PDE-preserving operators

A sequence of continuous linear operators is said to be hypercyclic if there exists a vector , called hypercyclic for , such that {T_nx:n0} is dense. A continuous linear operator, acting on some suitable function space, is PDE-preserving for a given set of convolution operators, when it map every kernel set for these operators invariantly. We establish hypercyclic sequences of PDE-preserving operators on , and study closed infinite-dimensional subspaces of, except for zero, hypercyclic vectors for these sequences.     

Photoionization assessment of C3-C5 alkadienes and alkenes in urban air.

Hydrocarbons from samples of traffic-polluted urban air were separated by gas chromatography on an aluminium oxide column and assessed simultaneously by photoionization detection (PID) and flame ionization detection (FID) after effluent splitting. The 10.2 eV photoionization detector selectively detects alkadienes and alkenes but not alkanes and alkynes in the C3-C5 region. The maximum PID/FID response ratio for alkadienes and alkenes is also obtained in this region. The analytical system as a whole is particularly favourable for the C3-C5 alkenes. Analytical data are given for propadiene, 1,3-butadiene, propene, butenes and pentenes.     

Chromatographic classification and comparison of commercially available reversed-phase liquid chromatographic columns using principal component analysis

A total of 135 commercially available alkyl, cyano, phenyl, perfluorinated, polar embedded, enhanced polar selectivity (i.e., polar/hydrophilic endcapped), "Aqua type" and a variety of novel phases including some non-silica based stationary phases have been characterised in terms of their surface coverage, hydrophobic selectivity, shape selectivity, hydrogen bonding capacity and ion-exchange capacity at pH 2.7 and 7.6. Principal component analysis has been used to provide a simple graphical comparison of the differences/similarities between columns in the entire database and differing subsets such as "Aqua type"/enhanced polar selectivity phases. The PCA has been correlated to the phase's ability to analyse a range of hydrophilic bases.     

A McLafferty-type rearrangement of a trimethylsilyl group in silylated hydroxy carbonyl compounds

A McLafferty-type rearrangement of a trimethylsilyl group is demonstrated. Abundant rearrangement ions are formed for trimethylsilyl derivatives of α,β-dihydroxy carbonyl compounds. Data are given for a large number of hydroxy acids and hydroxy ketones including aldonic acids, aldaric acids, acyclic ketoses and hydroxy keto acids. A few branched lactones are also shown to rearrange. The positive charge and the unpaired electron are extensively delocalized in the odd-electron rearrangement ions. Those substituents at the α-carbon atom which offer a favourable delocalization promote the rearrangement. Spectra of specifically methylated species reveal that migration over larger than six-membered rings occurs to some extent. An observed dependence of abundance on configuration is associated with steric strains in the transition state. The rearrangement ions are of great diagnostic value in structural analysis. They are relatively more abundant at low electron energies and give rise to the base peak at 20 eV for many compounds. Ions produced by the competing conventional McLafferty rearrangement are less abundant.     

Chiral phase transition in lattice QCD with dynamical quarks

The effect of virtual light quark loops on the chiral phase transition in lattice QCD with staggered fermions is investigated by employing the pseudo-fermion Monte Carlo method on a 6³ × 2 lattice. The variation in the order parameter $\text{〈}\text{ψ}\text{ψ〉}$ is found to become less sharp than the quenched case, indicating a second order chiral phase transitioon in the full theory.     

The Number of Nonisomorphic Two-dimensional Algebras over a Finite Field

In this paper, we derive explicit formulas for the number of nonisomorphic two-dimensional nonassociative algebras, possibly without a unit, over a finite field. The proof combines the first author’s general classification theory of two-dimensional nonassociative algebras over arbitrary base fields with elementary counting arguments which are primarily addressed to the problem of determining the number of orbits of a finite set acted upon by the group of integers mod 2. The number of nonisomorphic two-dimensional division algebras will also be determined.