Synthesis of SE- and TE-Containing Amino Acids: Useful Probes for Structural Studies of Proteins

ABSTRACT

The synthesis of (l)-Se-cystine, (l)-[⁷⁷Se]-cystine and (l)-Te-cystine in 4 steps from commercially available 2(S)-[(tert-butoxycarbonyl)amino]-3-hydroxy-propionate has been accomplished. [4-¹³C]Te-Met has been synthesized in a one pot reaction.     

Redundancy for localized frames

Redundancy is the qualitative property which makes Hilbert space frames so useful in practice. However, developing a meaningful quantitative notion of redundancy for infinite frames has proven elusive. Though quantitative candidates for redundancy exist, the main open problem is whether a frame with redundancy greater than one contains a subframe with redundancy arbitrarily close to one. We will answer this question in the affirmative for ℓ ¹-localized frames. We then specialize our results to Gabor multi-frames with generators in M ¹(R ^d ), and Gabor molecules with envelopes in W(C, l ¹). As a main tool in this work, we show there is a universal function g(x) so that, for every ε =s> 0, every Parseval frame {f _i } _i=1 ^M for an N-dimensional Hilbert space H _N has a subset of fewer than (1+ε)N elements which is a frame for H _N with lower frame bound g(ε/(2M/N − 1)). This work provides the first meaningful quantative notion of redundancy for a large class of infinite frames. In addition, the results give compelling new evidence in support of a general definition of redundancy given in [5].     

USB3.0电路保护

USB3.0接口设备集合了通信速度为5Gbps的四个额外的数据通道,而且电源总线也有着高达900mA的最大输出电流。这些新的USB3.0规格加上集成芯片几何尺寸的不断缩小,使得预防电气瞬变和过流故障也变得更重要复杂。即使是很小的静电放电(ESD)和短路事故带来的危害也相比更大。寄生电容,低钳位电压和低电阻成为电路保护元件选择中的关键指标。本文网络版地址:http://www.eepw.com.cn/article/145483.htm     

Determining the solution state orientation of a Ti enolate via stable isotope labeling, NMR spectroscopy, and modeling studies

Our group has used Ti-promoted aldol additions with an oxazolidineselone as the chiral auxiliary with much success. In these reactions, the Se atom in the auxiliary both promotes stereospecific addition as well as reports on, through the use of 77Se NMR spectroscopy, the ratio of diastereomers produced and the geometry of intermediates as the reaction proceeds. Through stable isotope labeling and NMR spectroscopy, we are able to experimentally observe a Ti enolate in solution and gain insight into its structure and reactivity. Results from molecular modeling calculations are also presented for comparison with NMR data.     

Single quark transition analysis of baryon resonance photocouplings

Resonance photocouplings of Barbour and Crawford are analysed within the context of the Melosh transformation. These photocouplings are the first set that favour a particular relative sign of the P-wave and F-wave pionic decays of the $\text{[}\text{56}\text{, L = 2]}$ multiplet. This conclusion rests primarily on the photocouplings of the P13⁺(1790) resonance. The favoured sign disagrees with that found in an analysis of πN → πΔ which relies on the contribution of the F15(1680) resonance.