基于微波无线能量传输多径效应的多角度超表面能量收集器

文中深入研究了基于微波无线能量传输技术的多径效应及其对多角度超表面能量收集器的性能的影响。首先,概述了微波无线能量传输技术的基本原理与发展现状,随后详细讨论了超表面结构在多角度能量接收中的应用。通过理论分析与仿真实验,文中提出了一种优化的超表面设计方案,以提高能量收集效率。实验结果显示,该方案能显著提高多角度超表面能量收集器在复杂传播环境下的能量收集性能,不仅为超表面能量收集器的设计提供了新的视角,也为未来无线能量传输技术的发展提供了理论参考。     

高重频激光对多激光制导武器干扰机理研究北大核心CSCD

本文基于仿真计算方法,研究高重频激光对多激光制导武器的干扰机理。发现重复频率与波门宽度是影响总干扰有效概率的主要因素,干扰反应时间与激光制导信号样式对总干扰有效概率的影响较小,重复频率取整数值则会增大干扰有效概率的不确定性。针对性提出了“一对多”干扰、提前干扰、重复频率避免取整数等改进措施,研究结论可为提升高重频激光对多激光制导武器干扰效果提供参考。     

多波束相控阵天线角度测量方法

在雷达、通信、测控等领域中,基于相控阵天线的幅度和差单脉冲测角技术是基本方法,但该方法通过旋转法向方向图去近似表示子波束方向图,并用一阶泰勒公式近似表示子波束接收信号幅度,从而带来非噪声因素误差,最终导致目标角度估计精度不高。为此,通过相控阵天线同时产生两个形状相同但相互独立的子波束,旋转波束指向中心轴方向的方向图函数来确定两个子波束的方向图函数,并用高阶泰勒公式对子波束接收信号幅度进行近似,从而减少误差。仿真和硬件测试结果表明所提方法能够有效提高测角精度。     

基于子阵近场零陷权的联合波达方向估计方法

针对海底长线阵在近场辐射声干扰及空间水平非均匀噪声下的远距离估计目标波达方向(DoA)问题,该文提出一种基于长线阵分子阵近场零陷权的联合目标方位估计方法.该方法将长线阵分解为多个高重叠子阵,对各个子阵利用零陷抑制技术去除近场强干扰对目标探测的影响,再利用各子阵对远距离目标方位估计结果差异性小、非目标所在频率即噪声对应空间谱最大值随机的特点,空间频率方差加权综合各子阵的目标方位估计结果,从而抑制空间非均匀噪声,实现对远距离目标的探测.仿真结果表明,与长线阵常规波束形成、长线阵近场零陷常规波束形成、长线阵近场零陷传统多重信号分类方法相比,该文方法能够有效降低空间谱背景级60 dB以上,输出信噪比提高15 dB以上,具有较强的提高信噪比能力及较高的空间分辨力,因此具有较好的工程应用价值.     

A Sterically Hindered Zirconocene Complex (1,2-Ph2C5H3)2ZrCl2:Synthesis, Structure and Properties as Olefin Polymerization Catalyst

SinceKaminskyeIal.discoveredthehighlyactivezirconocenedich1oride/methyl-aluminoxane(MAO)catalyticsystemforolefinpolymerization',intensiveresearchworkhasbeenfocusedondevelopingnewgroup4metal1ocenecatalystsforimprovingcatalystactivitiesandpolymerproperties"'.Inthedevelopmentofnewmetallocenecatalystsystems,liganddesignandmodificationhaveplayedanimportantrole.lthasbeenknownthatevenminormodificationofagivenligandframeworkcouldresultinsignificantchangesincatalystactivitiesandpolymerproperties'.Int…     

THE COMPARISON OF LANZHOU LOESS PROFILE WITH VOSTOK ICE CORE IN ANTARCTICA OVER THE LAST GLACIATION CYCLE

Loess near Lanzhou in the late Pleistocene is very sensitive to climatic fluctuations. The Beiyuan terrace profile in Linxia City, of which the curve of susceptibility tallies with the trend of isotopic curves of Vostok 2083 m ice core in Antarctica, is 35m thick. There are five layers of paleosols under Malan loess(L_1). Upper three layers (S_(1-a),S(1-b)and S_(1-c) correspond to three warm stages in last interglaciation, Interstadial of Last Glacial (C stage in Antarctic ice core)was clearly recorded in the Beiyuan profile, in which three layers of paleosols and two of loess were formed. The lowest section of the profile belongs to penultimate glaciation, in which fossils of cold-drought-resistant mammal and mollusc have been discovered.     

新型手性氨基醇的合成及其用于不对称催化醛类烷基化反应

制备了一种由糖类化合物衍生的新型手性氨基醇（Ⅰ），并将其作为手性源用于醛类的不对称烷基化反应．考察了在手性氨基醇的存在下，各种醛和二乙基锌作用生成相应的手性仲醇的光学收率及化学收率．结果表明，该催化剂对于芳香醛的烷基化更为有效．并考察了几种反应条件对于苯甲醛的不对称催化烷基化反应的影响，其中最佳结果为１－苯基－１－丙醇的光学收率达８２．７％，而化学收率达５８．８％．     

APPLICATION OF THE MOMENT METHODS TO ANALYSIS OF X-RAY DIFFRACTION LINE PROFILE FOR PA1010-BMI SYSTEM

Pure X-ray diffraction profiles have been analysed for polyamide 1010 and PA1010--BMI system by means of multipeak fitting resolution of X-ray diffraction.The methods ofvariance and fourth moment have been applied to determine the particle size and strainvalues for theparacrystalline materials.The results indicated that both variance and fourthmoment of X-ray diffraction line profile yielded approximately the same values of theparticle size and the strain.The particle sizes of(100)reflection have been found todecrease with increasing BMI content,whereas the strain values increased.     

纳米核壳式铜-锡双金属粉的制备及性能研究

A kind of novel core-shell Cu-Sn bimetallic nanoparticles has been prepared by a new method (displacement method), in which Sn was made to cover on the surface of Cu nano-core. The preparation method and reaction mechanism have been discussed. This reaction happened under the existence of coordinate agent-(NH₂)₂CS and protective agent PVP. The nanoparticles prepared were with a core-shell structure, granule diameter between 50～100 nm and good dispersing capability. The Cu-Sn nanoparticles proposed has better oxidation-resistant ability than Cu nanoparticles with corresponding granule diameter and can be applied as lubricant additives as well as antibacterial agent. When the additive amount is very low (0.1wt‰～0.5wt‰), it can improve the P_B of the lubricant by 92%～106%, and also enhance its antiwear characteristics and friction-reducing properties. At the concentration of 1 000 ppm, it can reach an antibacterial ratio of 99.99%.     

Synthesis, Characterization and Crystal Structure of （Z）-1-[2-（Triarylstannyl）vinyl]-1-indanols and Their Arylhalostannyl Derivatives

(Z)-1-[2-(Tri-o-tolylstannyl)vinyl]-1-indanol (1) and (Z)-1-[2-(tri-p-tolylstannyl)vinyl]-l-indanol (2) were synthesized by the addition reaction of 1-ethynylindanol with tri-o-tolyltin and tri-p-tolyltin hydride. The aryl groups in compound 1 and 2 were substituted by Br2 or I2 to yield monohalide derivatives (3-6). The compounds 1-6 were characterized by elemental analysis, ^1H NMR and FT-IR spectroscopy. The crystal structures of 1, 2 and 4 have been determined by single crystal X-ray diffraction analysis. The Sn atom in 1 and 2 exhibits a tetrahedral geometry distorted towards trigonal bipyramid due to a weak intramolecular interaction between Sn and the hydroxyl O atoms [0.2839(4) nm and 0.2744(5) nm], while the Sn atom in 4 adopts a trigonal bipyramidal geometry with a significant O→Sn(1) interaction [0.2552(5) nm].