3,7-二硝基亚氨基-2,4-二氮杂双环[3,3,0]辛烷的放热分解反应动力学

在程序升温条件下 ,用DSC研究了标题化合物的放热分解反应动力学 .用线性最小二乘法、迭代法以及二分法与最小二乘法相结合的方法 ,以积分方程、微分方程和放热速率方程拟合DSC数据 .在逻辑选择建立了微分和积分机理函数的最可几一般表达式后 ,用放热速率方程得到相应的表观活化能 (Ea)、指前因子 (A)和反应级数 (n)的值 .结果表明 :该反应的微分形式的经验动力学模式函数、Ea 和A值分别为 (1-α) 0 .44、2 30 .4kJ/mol和 10 18.16s-1.借助加热速率和所得动力学参数值 ,提出了标题化合物放热分解反应的动力学方程 .该化合物的热爆炸临界温度为 30 2 .6℃ .上述动力学参数对分析、评价标题化合物的稳定性和热变化规律十分有用 .     

Hydrothermal Reaction Mechanism and Pathway for the Formation of K2Ti6O13 Nanowires

Calculations and detailed first principle and thermodynamic analyses have been performed to understand the formation mechanism of K₂Ti₆O₁₃ nanowires (NWs) by a hydrothermal reaction between bulk Na₂Ti₃O₇ crystals and a KOH solution. It is found that direct ion exchange between K⁺ and Na⁺ plus H⁺ interactions with [TiO₆] octahedra in Na₂Ti₃O₇ promote the formation of an intermediate H₂K₂Ti₆O₁₄ phase. The large lattice mismatch between this intermediate phase and the bulk Na₂Ti₃O₇ structure, and the large energy reduction associated with the formation of this intermediate phase, drive the splitting of the bulk crystal into H₂K₂Ti₆O₁₄ NWs. However, these NWs are not stable because of large [TiO₆] octahedra distortion and are subject to a dehydration process, which results in uniform K₂Ti₆O₁₃ NWs with narrowly distributed diameters of around 10 nm.     

Hybrid Electrodes Used in Polymer Electro-Optic Modulator with Ultra-Broadband

Hybrid electrode combined coplanar waveguide (CPW) and microstrip lines in ultra-broadband electro-optic modulators. The characteristics of the modulators with hybrid electrode is like that of the modulator with the microstrip lines, in which the microstrip electrode is loaded above only one arm of Mach-Zehnder (M-Z) optical waveguide, besides the problem of microstrip line to coaxial transition and corona polarization in polymer modulators have been best solved at the same time. By using finite element method (FEM), the characteristic parameters such as half-wave voltage, modulation bandwidth characteristic impedance, effective microwave refractive index of polymer modulators with microstrip line and hybrid electrode are analysed and compared in this paper. The results present that velocity match, impendence match and lower microwave propagating loss is easily realized in modulators with hybrid electrode.     

Investigation of Mechanical and Electrical Characteristics for Cracked Conductive Particle in Anisotropic Conductive Adhesive (ACA) Assembly

In an anisotropic conductive adhesive (ACA) assembly, the electrical conduction is usually achieved with the conductive particles between the bumps of integrated circuit (IC) and corresponding conductive tracks on the glass substrate. Fully understanding of the mechanical and electrical characteristics of ACA particles can help to optimize the assembly process and improve the reliability of ACA interconnection. Most conductive particles used in the ACA assembly are with cracks in the metal coating of the particles after the ACA bonding. This paper introduced the fracture analysis by applying the cohesive elements in the numerical model of the nickel-coated polymer particle and further simulating the cracks initiation and propagation in the nickel coating during the ACA bonding. The simulation results showed that the stress distribution on the nickel-coated particle with cracks was significantly different from that on the nickel-coated particle without crack, indicating that the stress analysis by taking the crack into consideration is very important for the reliability assessment of the ACA interconnection. The stress analysis of cohesive elements indicated that the cracks initiated at the central area of the nickel coating and propagated to the polar area. Furthermore, by the introduction of a new parameter of the virtual resistance, a mathematical model was established to describe the electrical characteristics of the nickel-coated particle with cracks. The particle resistance of the nickel-coated particle with cracks was found to be much higher than that of the particle without crack in the optimized bonding pressure range, indicating that it is necessary to take the crack into consideration for the particle conduction analysis as well. Therefore, the fracture analysis on the conductive particle by taking the crack into consideration could accurately evaluate the reliability of ACA interconnection and avoid serious reliability issues.     

A generalized quasi-sum relations for oscillator strengths in transition arrays: theoretical study of the opacity of Ge plasmas

We present a simplified relativistic configuration interaction method (SRCI), by which all the energy levels and oscillator strengths in each transition array can be calculated. There exist generalized quasi-sum relations for the calculated oscillator strengths in the relevant transition arrays by the SRCI and by an unresolved transition array model (UTA). Based on UTA and the detailed configuration accounting (DCA), with a fully relativistic treatment incorporated with the quantum defect theory, the X-ray absorption spectra for any middle- and high-Z plasmas or composite plasmas can be calculated with much less computational efforts. The gross features of calculated spectra by DCA-UTA are in agreement with the relevant experimental measurements, except some detailed structures in some narrow spectral ranges. Such detailed structures can be calculated by SRCI incorporated with DCA-UTA. As an illustrative example, the absorption spectra of Ge plasmas are calculated by DCA-UTA-SRCI and are in agreement with the experimental opacity data. Therefore, the theoretical method (DCA-UTA-SRCI) verified by experimental measurements will not only be a basic tool to provide “precision” opacity data for the inertial confinement fusion research (ICF) and studies in stellar physics but also can be used to analyze the relevant diagnostic measurements for ICF plasmas.     

Linux系统防火墙技术的实现

防火墙是提供网络安全性的重要手段之一,Linux提供了实现防火墙技术的工具包.分析了Linux系统中常用的包过滤防火墙技术--IPchains和IPtables.这两种防火墙技术作为两种基本的包过滤工具,实际上使用的是内核中的信息表,将来自非信任源的不必要的信息过滤出去.与IPchains相比,IPtables信息包过滤系统是最新的解决方案,也是第一个集成到Linux内核的解决方案.在许多方面,IPtables比IPchains灵活,它允许管理员控制更多的细节,例如记录日志等级.     

MAX+Plus与数字电路教学

MAX PlusⅡ是美国Altera公司为开发其编程逻辑器件而推出的工具软件,可以完成从门级到系统级的逻辑芯片的设计,是典型的逻辑设计与综合工具.将MAX PlusⅡ用于课堂教学中,可以起到事半功倍的效果,作图快捷,修改方便,仿真结果直观具体,提高课堂讲授效率,将抽象的逻辑教学形象化和直观化.简要介绍了电子设计自动化(EDA)的理念和工具MAX Plus及其在普通数字电路教学中的应用,并以设计一个有使能控制端的半加器为例,说明MAX PlusⅡ的设计、仿真过程,以期得到融传统教学方式和现代化设计理念为一体的教学效果.     

MC-CDMA系统迭代检测中的一种信道估计算法

在DS—CDMA系统中，联合译码的迭代多用户检测是克服多址干扰增加系统容量的有效方法。本文将多用户检测和译码相结合的迭代检测技术应用于MC—CDMA系统，其中，多用户检测器由串行干扰消除和其后的MMSE滤波器组成。文中提出一种时域信道估计作为迭代初始值的频域信道估计算法，比单纯的频域信道估计方法节约导频符号数量，并且由于信道估计性能的改善，加快了迭代检测的收敛速度。     

一种低功耗Cache设计技术的研究

低功耗、高性能的cache系统设计是嵌入式DSP芯片设计的关键。本文在多媒体处理DSP芯片MD32的设计实践中，提出一种利用读／写缓冲器作为零级cache，减少对数据、指令cache的读／写次数，由于缓冲器读取功耗远远小于片上cache，从而减小cache相关功耗的方法。通过多种多媒体处理测试程序的验证，该技术可减少对指令cache或者数据cache20％～40％的读取次数，以较小芯片面积的增加换取了较大的功耗降低。     

EPP在便携式数据采集系统中的应用

分析了并口处于EPP(增强型并行端口)模式时和单片机进行数据交换的原理.介绍了有关EPP的基本特性、信号定义、操作模式及其程序设计方法,设计了基于EPP协议的便携式数据采集系统,给出了技术解决方案,讨论了系统的硬件接口电路和软件编程.方案具有可靠性高、速度快、软硬件设计简捷等优点.