全文获取类型
收费全文 | 1269篇 |
免费 | 60篇 |
国内免费 | 4篇 |
专业分类
化学 | 920篇 |
晶体学 | 10篇 |
力学 | 39篇 |
数学 | 49篇 |
物理学 | 238篇 |
无线电 | 77篇 |
出版年
2023年 | 12篇 |
2022年 | 39篇 |
2021年 | 33篇 |
2020年 | 43篇 |
2019年 | 46篇 |
2018年 | 47篇 |
2017年 | 59篇 |
2016年 | 47篇 |
2015年 | 46篇 |
2014年 | 48篇 |
2013年 | 115篇 |
2012年 | 92篇 |
2011年 | 103篇 |
2010年 | 43篇 |
2009年 | 42篇 |
2008年 | 41篇 |
2007年 | 57篇 |
2006年 | 44篇 |
2005年 | 35篇 |
2004年 | 33篇 |
2003年 | 18篇 |
2002年 | 21篇 |
2001年 | 6篇 |
2000年 | 12篇 |
1999年 | 9篇 |
1998年 | 5篇 |
1997年 | 7篇 |
1996年 | 5篇 |
1995年 | 8篇 |
1994年 | 12篇 |
1993年 | 13篇 |
1992年 | 13篇 |
1991年 | 14篇 |
1990年 | 11篇 |
1989年 | 11篇 |
1988年 | 8篇 |
1987年 | 11篇 |
1986年 | 7篇 |
1985年 | 14篇 |
1984年 | 11篇 |
1983年 | 12篇 |
1982年 | 4篇 |
1981年 | 12篇 |
1980年 | 10篇 |
1979年 | 15篇 |
1978年 | 10篇 |
1977年 | 8篇 |
1976年 | 4篇 |
1974年 | 5篇 |
1973年 | 4篇 |
排序方式: 共有1333条查询结果,搜索用时 390 毫秒
91.
A. R. Joshi Abhay V. Patil U. M. Kasar 《Journal of Radioanalytical and Nuclear Chemistry》2010,286(1):67-69
Precipitation and solvent extraction methods have been investigated for the purification of plutonium from silver from the
solution generated during oxidative dissolution of plutonium oxide using Ag(II) ions. Initial experiments have been carried
out using thorium as representative of plutonium. Selecting the optimum conditions, the experiments were repeated with plutonium.
The results revealed that Pu can be purified from silver ions either by precipitating silver as silver chloride or silver
metal followed by Pu(IV) oxalate precipitation or by selective extraction of Pu(IV) into 20% Aliquat-336 or 30% TBP. 相似文献
92.
A theoretical calculation is performed to investigate the I/V characteristics of GaAs MESFETs. The calculation is based on a simple model that takes into account the dependence of electron mobility on electric field and doping. It is shown that velocity overshoot may be treated by an effective velocity higher than the bulk value.<> 相似文献
93.
U. S. Mote S. L. Bhattar S. R. Patil G. B. Kolekar 《Journal of solution chemistry》2009,38(5):619-628
The interaction between fluorescein and felodipine (FLD) was investigated by the spectrofluorometric method. The fluorescence
of FLD was quenched by fluorescein and quenching is in accordance with the Stern-Volmer relation. The binding constants of
fluorescein with FLD were obtained at different temperatures. The binding constant and number of binding sites at different
temperatures were calculated yielding the corresponding thermodynamic parameters ΔS, ΔH and ΔG. The distance r between the donor (FLD) and acceptor (fluorescein) molecules was obtained according to the fluorescence resonance energy
transfer. The optimum conditions for the fluorometric determination of fluorescein were studied and the quenching method was
successfully applied to estimate the fluorescein concentration of the pharmaceutical sample directly. 相似文献
94.
95.
We study reducing feedback overhead of users' channel state information required for opportunistic scheduling at a base station while minimizing the throughput penalty incurred due to reduced feedback. We first propose a simple contention based scheme known as 'static splitting' for best effort traffic. The idea is to divide users into static groups, with users that belong to a group, and have their currently supported rate above a threshold, contending to send their current feedback to the base station. This is combined with maximum quantile scheduling -scheduling a user whose current rate is high relative to its distribution, to obtain thresholds that are independent of users' rate distributions even when they are heterogeneous, allowing off-line optimization of thresholds. Next we develop the insight that for a traffic mixture of best effort and real-time traffic one has to combine contention and polling to reduce feedback while providing quality of service. We propose a scheme based on this insight. Under this scheme we prove a lower bound on the service seen by a real-time when users' channel capacities are fast fading. Furthermore, we propose a heuristic modification that is able to exploit a larger fraction of opportunism. Simulation results illustrate the performance advantage of the proposed schemes. 相似文献
96.
Vikrant Patil Enrique Barragan Shivaputra A. Patil Siddappa A. Patil Alejandro Bugarin 《Tetrahedron letters》2017,58(35):3474-3477
A series of new chlorinated thiabendazoles (6a–m) have been synthesized from readily available anilines and 4-cyanothiazole in moderate to good yields. All synthesized compounds were fully characterized using 1H NMR, 13C NMR, IR, and mass spectrometry. Additionally, the structure of the compound (6f) was confirmed by single-crystal X-ray diffraction. In addition, synthesis of 2-substituted benzimidazoles and 2-phenyl benzothiazole was investigated using our optimized conditions and the outcome is presented herein. 相似文献
97.
Rahul A. Patil Mohsen Talebi Leonard M. Sidisky Daniel W. Armstrong 《Chromatographia》2017,80(10):1563-1574
Dicationic ionic liquids (ILs) are widely used as gas chromatography (GC) stationary phases as they show higher thermal stabilities, variety of polarities, and unique selectivities towards certain compounds. An important aspect contributing to them is that they show multiple solvation interactions compared to the traditional GC stationary phases. Dicationic ILs are considered as combination of three structural moieties: (1) cationic head groups; (2) a linkage chain; and (3) the counter anions. Modifications in these structural moieties can alter the chromatographic properties of IL stationary phases. In this study, a series of nine thermally stable IL stationary phases were synthesized by the combination of five different cations, two different linkage chains, and two different anions. Different test mixtures composed of a variety of compounds having different functional groups and polarities were analyzed on these columns. A comparison of the separation patterns of these different compounds on nine different IL columns provided some insights about the effects of structural modifications on the selectivities and polarities of dicationic ILs. 相似文献
98.
Manisha S. Patil Amey V. Palav Chetan K. Khatri Ganesh U. Chaturbhuj 《Tetrahedron letters》2017,58(29):2859-2864
The present study describes a rapid, simple and straightforward approach to the synthesis of 1,8-dioxo-octahydroxanthenes, 14-phenyl-14H-dibenzo[a,j]xanthene and tetrahydrobenzoxanthene-11-ones under solvent-free conditions using sulfated polyborate as a highly efficient catalyst. The procedure offers several advantages including cleaner reaction profile, mild reaction condition, economic, recyclable and environmentally benign catalyst, high yields, simple experimental and workup procedures. While non-extractive work up/purification, along with reusability of catalyst make this method economically affordable for large scale. 相似文献
99.
An array of 2-substituted-4,5-diphenyloxazoles were found to be cleaved to triacylamines and diacylamines (imides) using a reagent system composed of m-chloroperbenzoic acid (MCPBA) and 2,2′-bipyridinium chlorochromate (BPCC). The 2-alkyl-4,5-diphenyloxazoles give imides (38–60%) as the predominant cleavage product while the 2-aryl-4,5-diphenyloxazoles give triacylamines (44–71%). Two mechanisms involving intermediates such as cyclic endoperoxides or oxachromacycles were proposed. An application of the oxidative cleavage to the multi-step synthesis of (±)-phoracantholide I seco acid is detailed. 相似文献
100.
Siddappa Patil Karolin Dietrich Anthony Deally Brendan Gleeson Helge Müller‐Bunz Francesca Paradisi Matthias Tacke 《Helvetica chimica acta》2010,93(12):2347-2364
From the reaction of 1H‐imidazole ( 1a ), 4,5‐dichloro‐1H‐imidazole ( 1b ), 1H‐benzimidazole ( 1c ), 1‐methyl‐1H‐imidazole ( 1d ), and 1‐methyl‐1H‐benzimidazole ( 1f ) with methyl 4‐(bromomethyl)benzoate ( 2 ), symmetrically and nonsymmetrically 4‐(methoxycarbonyl)benzyl‐substituted N‐heterocyclic carbene (NHC) precursors, 3a – 3f , were synthesized. These NHC precursors were then reacted with silver(I) acetate (AgOAc) to yield the NHC–silver acetate complexes (acetato‐κO){1,3‐bis[4‐(methoxycarbonyl)benzyl]imidazol‐2‐ylidene}silver ( 4a ), (acetato‐κO){4,5‐dichloro‐1,3‐bis[4‐(methoxycarbonyl)benzyl]‐2,3‐dihydro‐1H‐imidazol‐2‐yl}silver ( 4b ), (acetato‐κO){1,3‐bis[4‐(methoxycarbonyl)benzyl]‐2,3‐dihydro‐1H‐benzimidazol‐2‐yl}silver ( 4c ), (acetato‐κO){1‐[4‐(methoxycarbonyl)benzyl]‐3‐methyl‐2,3‐dihydro‐1H‐imidazol‐2‐yl}silver ( 4d ), (acetato‐κO){4,5‐dichloro‐1‐[4‐(methoxycarbonyl)benzyl]‐3‐methyl‐2,3‐dihydro‐1H‐imidazol‐2‐yl}silver ( 4e ), and (acetato‐κO){1‐[4‐(methoxycarbonyl)benzyl]‐3‐methyl‐2,3‐dihydro‐1H‐benzimidazol‐2‐yl}silver ( 4f ), respectively. The three NHC–AgOAc complexes 4a, 4c , and 4d were characterized by single‐crystal X‐ray diffraction. All compounds studied in this work were preliminarily screened for their antimicrobial activities in vitro against Gram‐positive bacteria Staphylococcus aureus, and Gram‐negative bacteria Escherichia coli using the qualitative disk‐diffusion method. All NHC–AgOAc complexes exhibited weak‐to‐medium antibacterial activity with areas of clearance ranging from 4 to 7 mm at the highest amount used, while the NHC precursors showed significantly lower activity. In addition, NHC–AgOAc complexes 4a and 4b , and 4d – 4f exhibited in preliminary cytotoxicity tests on the human renal‐cancer cell line Caki‐1 medium‐to‐high cytotoxicities with IC50 values ranging from 3.3±0.4 to 68.3±1 μM . 相似文献