Hydroarylation of styrenes with arenes/heteroarenes using KHSO4 (10 mol%) as an efficient heterogeneous catalyst is described. High conversion and selectivity (>99%) were observed for hydroarylation
of styrenes with 2-naphthol at reflux temperature of 1,2-dichloroethane. Yields were quantitative with all styrenes. Moderate
to good conversions and selectivities were achieved with other aromatics and heteroaromatics under the same conditions. Regeneration
and reusability of KHSO4 were demonstrated. Addition of a trace amount of water could help to reactivate the KHSO4 through dispersion and to facilitate the hydroarylation reaction. 相似文献
The recent explosion in multimedia and networking application places a great demand on efficient transmission of images at
low bit rate with high security. Mixing several existing standard encryption techniques with image encoding tends to change
the compression ratio greatly. In this paper, a novel image encryption algorithm is embedded as a part of JPEG image encoding
scheme to meet three major necessities: (1) to provide temporal security against casual observer, (2) to preserve the compression
ratio, (3) remain compliant with the JPEG file format. In the proposed algorithm, the modified DCT blocks are confused by
a fuzzy PN sequence. In addition to that, the DCT coefficients of each modified DCT block are converted to unique uncorrelated
symbols, which are confused by another fuzzy PN sequence. Finally, the variable length encoded bits are encrypted by chaotic
stream cipher. An amalgamation of all the three techniques with random combination of seeds will provide the required security
against the casual listener/observer where the security needed is only in-terms of few hours. 相似文献
Suzuki-Miyaura cross coupling was successfully used for C5-arylation in 4-amino-2-chloroquinoline-3-carbaldehyde using arylbornic acid and tetrakistriphenylphosphine palladium catalyst in water. Friedländer condensation reaction on 4-amino-2-chloro/2-arylquinoline-3-carbaldehyde and aromatic ketones gave novel aryl and diarylbenzo[h] [1, 6]naphthyridines in good yields. Fluorescence quantum yields were increased by introducing C2 and C5 π donor aryl benzo[h][1, 6]naphthyridines derivatives.
Hexamethyldisiloxane (HMDSO) films have been deposited on bell metal using radiofrequency plasma assisted chemical vapor deposition (RF-PACVD) technique. The protective performances of the HMDSO films and their water repellency have been investigated as a function of DC self-bias voltage on the substrates during deposition. Plasma potential measurements during film deposition process are carried out by self-compensated emissive probe. Optical emission spectroscopy (OES) analyses of the plasma during deposition reveal no significant change in the plasma composition within the DC self-bias voltage range of −40 V to −160 V that is used. Raman and X-ray photoelectron spectroscopy (XPS) studies are carried out for film chemistry analysis and indicate that the impinging ion energy on the substrates influences the physio-chemical properties of the HMDSO films. At critical ion energy of 113 qV (corresponding to DC self-bias voltage of −100 V), the deposited HMDSO film exhibits least defective Si-O-Si chemical structure and highest inorganic character and this contributes to its best corrosion resistance behavior. The hardness and elastic modulus of the films are found to be bias dependent and are 1.27 GPa and 5.36 GPa for films deposited at −100 V. The critical load for delamination is also bias dependent and is 11 mN for this film. The water repellency of the HMDSO films is observed to be dependent on the variation in surface roughness. The results of the investigations suggest that HMDSO films deposited by RF-PACVD can be used as protective coatings on bell metal surfaces. 相似文献
Dry ball milling of hexosides with trityl chloride in the presence of DABCO or Na2CO3 has been found to result in their complete conversion to the respective 6‐O‐trityl ethers. Further wet grinding of the reaction mixture with Ac2O in the presence of DMAP led to the respective fully protected hexosides in good to excellent yields after isolation. It has been found to be an effective one‐pot two‐step synthesis under solvent‐free condition. The speed of homogenization has been shown to highly influence the rate and outcome of the reaction, and commercially available planetary ball mill has been proved to be very convenient for carrying out the reaction under standardized and reproducible conditions. 相似文献
Suitable host lattice and morphology for easy intercalation and deintercalation process are crucial requirements for electrochromic
device. In this investigation, the evolution of structural and morphological changes and their effect on electrochromic (EC)
properties of spray-deposited WO3 thin films are studied. Films of different morphologies were deposited from an ammonium tungstate precursor solution using
a novel pulsed spray pyrolysis technique (PSPT) on tin-doped indium oxide (ITO) coated glass substrates by varying quantity
of spraying solution. Interesting morphological transition from beads-to-wires-to-fibers as a function of quantity of sprayed
solution has been demonstrated. The porosity, crystallinity and “open” structures in the films consisting of beads, wires,
and fiber-like morphology enabled us to correlate these aspects to their EC performance. WO3 films comprising wire-like morphology (20 cc spraying quantity) exhibited better EC properties both in terms of coloration
efficiency (42.7 cm2/C) and electrochemical stability (103 colored/bleached cycles) owing to their adequate open structure, porosity, and amorphicity, compared with the films having
bead/fiber-like morphology. 相似文献
In this letter, we analyze the suitability of the double gate MOSFETs (DG MOSFETs) for RF-mixer applications from the point of optimizing the transconductance gain, power consumption, and area. Mixer topologies using the 0.13-/spl mu/m conventional MOSFETs, simultaneously driven DG MOSFETs (SDDG) and the independently driven DG MOSFETs (IDDG) are compared using extensive device simulations. In the frequency range 1-40 GHz, our simulation results show that the mixer circuits realized using the SDDG technologies show an order of magnitude lower power-area product, for a given transconductance gain, compared to the conventional and the IDDG technologies. 相似文献
This paper presents a new nonquasi-static (NQS) model for the MOSFET. The model is derived from physics and only relies on the very basic approximation needed for a charge-based model. To derive the model, a popular variational technique named Galerkin's Method has been used. The model proves to be very accurate even for extremely fast changes in the bias voltages. Simulation results show a very good match even when the rise time of the applied signal is smaller than the transit time of the device. 相似文献