全文获取类型
收费全文 | 570篇 |
免费 | 11篇 |
国内免费 | 6篇 |
专业分类
化学 | 310篇 |
晶体学 | 7篇 |
力学 | 19篇 |
数学 | 97篇 |
物理学 | 103篇 |
无线电 | 51篇 |
出版年
2022年 | 2篇 |
2021年 | 6篇 |
2020年 | 2篇 |
2019年 | 1篇 |
2018年 | 8篇 |
2017年 | 4篇 |
2016年 | 10篇 |
2015年 | 10篇 |
2014年 | 15篇 |
2013年 | 25篇 |
2012年 | 23篇 |
2011年 | 28篇 |
2010年 | 28篇 |
2009年 | 19篇 |
2008年 | 41篇 |
2007年 | 32篇 |
2006年 | 29篇 |
2005年 | 23篇 |
2004年 | 19篇 |
2003年 | 33篇 |
2002年 | 23篇 |
2001年 | 11篇 |
2000年 | 22篇 |
1999年 | 8篇 |
1998年 | 16篇 |
1997年 | 11篇 |
1996年 | 11篇 |
1995年 | 13篇 |
1994年 | 10篇 |
1993年 | 11篇 |
1992年 | 3篇 |
1991年 | 15篇 |
1990年 | 6篇 |
1989年 | 8篇 |
1988年 | 7篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1985年 | 5篇 |
1984年 | 8篇 |
1983年 | 3篇 |
1982年 | 6篇 |
1981年 | 8篇 |
1980年 | 3篇 |
1979年 | 4篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1976年 | 4篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1933年 | 1篇 |
排序方式: 共有587条查询结果,搜索用时 15 毫秒
41.
K. C. Nicolaou Dionisios Vourloumis Tianhu Li Joaquin Pastor Nicolas Winssinger Yun He Sacha Ninkovic Francisco Sarabia Hans Vallberg Frank Roschangar N. Paul King M. Ray V. Finlay Pareskevi Giannakakou Pascal Verdier-Pinard Ernest Hamel 《Angewandte Chemie (International ed. in English)》1997,36(19):2097-2103
42.
Far infrared (18–337 μm) magnetotransmission of thin samples of Hg1?kMnkTe (0?k?0.02) at liquid helium temperature was measured. The strong influence of the exchange interaction on the positions of magnetotransmission minima was observed. The results were explained within the framework of Luttinger model (D0 + D1) with additional Heisenberg type Hamiltonian for free carriers-Mn ions exchange interaction. 相似文献
43.
A security analysis of a recently proposed secure communication scheme based on the phase synchronization of chaotic systems is presented. It is shown that the system parameters directly determine the cipher text waveform, hence it can be readily broken by system parameter estimation from the cipher text signal. 相似文献
44.
Versatile chelating behavior of benzil bis(thiosemicarbazone) in zinc, cadmium, and nickel complexes
Reactions of benzil bis(thiosemicarbazone), LH(6), with M(NO(3))(2).nH(2)O (M = Zn, Cd, and Ni), in the presence of LiOH.H(2)O, show the versatile behavior of this molecule. The structure of the ligand, with the thiosemicarbazone moieties on opposite sides of the carbon backbone, changes to form complexes by acting as a chelating molecule. Complexes of these metal ions with empirical formula [MLH(4)] were obtained, although they show different molecular structures depending on their coordinating preferences. The zinc complex is the first example of a crystalline coordination polymer in which a bis(thiosemicarbazone) acts as bridging ligand, through a nitrogen atom, giving a 1D polymeric structure. The coordination sphere is formed by the imine nitrogen and sulfur atoms, and the remaining position, in a square-based pyramid, is occupied by an amine group of another ligand. The cadmium derivative shows the same geometry around the metal ion but consists of a dinuclear structure with sulfur atoms acting as a bridge between the metal ions. However, in the nickel complex LH(6) acts as a N(2)S(2) ligand yielding a planar structure for the nickel atom. The ligand and its complexes have been characterized by X-ray crystallography, microanalysis, mass spectrometry, IR, (1)H, and (13)C NMR spectroscopies and for the cadmium complex by (113)Cd NMR in solution and in the solid state. 相似文献
45.
The emergence of glassy behavior of electrons is investigated for systems close to disorder-driven and interaction-driven metal-insulator transitions. Our results indicate that Anderson localization effects strongly stabilize such glassy behavior, while Mott localization tends to suppress it. We predict the emergence of an intermediate metallic glassy phase separating the insulator from the normal metal. This effect is expected to be most pronounced for sufficiently disordered systems, in agreement with recent experimental observations. 相似文献
46.
Grirrane A Pastor A Galindo A Ienco A Mealli C Rosa P 《Chemical communications (Cambridge, England)》2003,(4):512-513
The compound [Mn(tda)(bipy)] (tda = S(CH2COO)2(2-)) features the first structurally characterized tetra-carboxylate dimanganese antiferromagnetic system with 'copper acetate' core; the binuclear units, completed by bipyridine chelates, are doubly chained by the tda anions that adopt an unprecedented mu,mu'-eta1,eta1,eta1,eta1 coordination mode. 相似文献
47.
Rodríguez JL Souto RM Fernández-Mérida L Pastor E 《Chemistry (Weinheim an der Bergstrasse, Germany)》2002,8(9):2134-2142
Spectroelectrochemical studies on the reactivity of butanol isomers on Pt electrodes in perchloric acid medium led to the observation of structural effects that result from the different arrangements of atoms in the organic molecules. The use of differential electrochemical mass spectrometry (DEMS) to detect volatile products showed that all four isomers react on the electrode, though different product yields were observed for each compound. In spite of the differences in the electrochemical behaviour of the butanol isomers, a series of general processes accounts for the results obtained. The formation of strongly adsorbed residues by a dehydration process leading to the formation of a C=C bond was proposed for all isomers. Electroreduction of the adsorbates produces C(4) and C(3) alkanes, and the latter reveal the existence of a fragmentation process. The C(4) hydrocarbons can be formed by hydrogenation of these residues and by hydrogenolysis of alcohol molecules in the bulk solution which react at the electrode with adsorbed hydrogen. On the other hand, CO(2) is formed during electrooxidation of the adsorbed species. Partial-oxidation products containing a carbonyl group were detected from 0.2 M solutions of 1-butanol, isobutyl alcohol and sec-butyl alcohol. The tertiary alcohol tert-butyl alcohol only reacts in its adsorbed state. 相似文献
48.
Prof. Dr. Mateo Alajarin Dr. Raul‐Angel Orenes Prof. Dr. Judith A. K. Howard Dr. Elinor C. Spencer Prof. Dr. Jonathan W. Steed Dr. Aurelia Pastor 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(8):2389-2397
Tris(2‐ and 3‐ureidobenzyl)amines with Cs symmetry self‐assemble in solution forming mixtures of regioisomeric capsular aggregates, one of which is chiral and the other centrosymmetric. Under certain conditions, a predominance of the centrosymmetric regioisomer is found before equilibrium, that is, a mixture close to the statistical ratio of the two species is reached. In the solid state, there is a preference for the centrosymmetric capsules. Molecular models of both regioisomeric aggregates have been built and analyzed for comparison. Guests inside capsules formed by self‐assembly of desymmetrized tris(3‐ureidobenzyl)amines feel different magnetic environments, depending on whether they are inside a chiral or an achiral regioisomeric container. Of special significance are the experiments with a more flexible triurea endowed with an ureidopropylic arm, which self‐assembles with the same efficiency as the more rigid tris(ureidobenzyl)amines. 相似文献
49.
Patricia Cava-Montesinos Agustin Pastor Miguel de la Guardia 《Analytica chimica acta》2003,481(2):291-300
A sensitive procedure has been developed for selenium and tellurium determination in milk by hydride generation atomic fluorescence spectrometry (HG-AFS) after microwave-assisted sample digestion. The method provides sensitivity values of 1591 and 997 fluorescence units ng−1 ml−1 with detection limits of 0.005 and 0.015 ng ml−1 for Se and Te, respectively. The application of the developed methodology to the analysis of cow milk samples of the Spanish market evidenced the presence of concentration ranges from 11.1 to 26.0 ng ml−1 for Se, and from 1.04 to 9.7 ng ml−1 for Te having found a good comparability with data obtained after dry-ashing of samples. 相似文献
50.
Kleij AW Souto B Pastor CJ Prados P de Mendoza J 《The Journal of organic chemistry》2003,68(22):8711-8714
The selective preparation and complete structural characterization of a small series of 1,2-anti-heterodisubstituted calix[4]arenes has been accomplished. These compounds were obtained in two steps from unsubstituted p-tert-butylcalix[4]arene by tribenzoylation and a subsequent one-pot, two-step sequence involving alkylation with simultaneous partial deacylation, resulting in heterodisubstituted calixarenes carrying an alkyl and an aroyl group. The monoalkyl-tribenzoyl intermediate, prior to in situ deprotection, could also be isolated. 相似文献