全文获取类型
收费全文 | 270篇 |
免费 | 9篇 |
国内免费 | 5篇 |
专业分类
化学 | 185篇 |
力学 | 12篇 |
数学 | 33篇 |
物理学 | 33篇 |
无线电 | 21篇 |
出版年
2023年 | 2篇 |
2022年 | 1篇 |
2021年 | 4篇 |
2020年 | 10篇 |
2019年 | 10篇 |
2018年 | 13篇 |
2017年 | 7篇 |
2016年 | 13篇 |
2015年 | 12篇 |
2014年 | 10篇 |
2013年 | 28篇 |
2012年 | 18篇 |
2011年 | 24篇 |
2010年 | 18篇 |
2009年 | 23篇 |
2008年 | 19篇 |
2007年 | 18篇 |
2006年 | 9篇 |
2005年 | 11篇 |
2004年 | 8篇 |
2003年 | 6篇 |
2002年 | 1篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1996年 | 2篇 |
1994年 | 1篇 |
1992年 | 2篇 |
1991年 | 3篇 |
1990年 | 2篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有284条查询结果,搜索用时 562 毫秒
21.
Hosseini M Ganjali MR Tavakoli M Norouzi P Faridbod F Goldooz H Badiei A 《Journal of fluorescence》2011,21(4):1509-1513
A novel and simple fluorescence enhancement method for selective pyrophosphate(PPi) sensing was proposed based on a 1:1 metal
complex formation between bis(8-hydroxy quinoline-5-solphonat) chloride aluminum(III) (Al(QS)2Cl), (L) and PPi in aqueous solution. The linear response range covers a concentration range of 1.6 × 10−7 to 1.0 × 10−5 mol/L of PPi and the detection limit of 2.3 × 10−8 mol/L. The association constant of L-PPi complex was calculated 2.6 × 105 L/mol. L was found to show selectively and sensitively fluorescence enhancement toward PPi over than I3-, NO3-, CN−, CO32−, Br−, Cl−, F−, H2PO4− and SO42−, which was attributed to higher stability of inorganic complex between pyrophosphate and L. 相似文献
22.
Adaptive allocation of resources and call admission control forwireless ATM using genetic algorithms
Sherif M.R. Habib I.W. Nagshineh M. Kermani P. 《Selected Areas in Communications, IEEE Journal on》2000,18(2):268-282
In wireless ATM-based networks, admission control is required to reserve resources in advance for calls requiring guaranteed services. In the case of a multimedia call, each of its substreams (i.e., video, audio, and data) has its own distinct quality of service (QoS) requirements (e.g., cell loss rate, delay, jitter, etc.). The network attempts to deliver the required QoS by allocating an appropriate amount of resources (e.g., bandwidth, buffers). The negotiated QoS requirements constitute a certain QoS level that remains fixed during the call (static allocation approach). Accordingly, the corresponding allocated resources also remain unchanged. We present and analyze an adaptive allocation of resources algorithm based on genetic algorithms. In contrast to the static approach, each substream declares a preset range of acceptable QoS levels (e.g., high, medium, low) instead of just a single one. As the availability of resources in the wireless network varies, the algorithm selects the best possible QoS level that each substream can obtain. In case of congestion, the algorithm attempts to free up some resources by degrading the QoS levels of the existing calls to lesser ones. This is done, however, under the constraint of achieving maximum utilization of the resources while simultaneously distributing them fairly among the calls. The degradation is limited to a minimum value predefined in a user-defined profile (UDP). Genetic algorithms have been used to solve the optimization problem. From the user perspective, the perception of the QoS degradation is very graceful and happens only during overload periods. The network services, on the other hand, are greatly enhanced due to the fact that the call blocking probability is significantly decreased. Simulation results demonstrate that the proposed algorithm performs well in terms of increasing the number of admitted calls while utilizing the available bandwidth fairly and effectively 相似文献
23.
24.
Dispersive liquid-liquid microextraction (DLLME) combined with spectrofluorimetry was applied to the extraction, pre-concentration and analysis of thiamine (vitamin B1). The procedure is based on (a) the oxidation of thiamine with ferricyanide to form fluorescent thiochrome (TC), (b) the trapping of TC into a microextraction solvent, and (c) spectrofluorometric determination. Microextraction solvent and disperser solvent are directly injected into an aqueous solution containing TC. After centrifuging, phase separation is performed by sedimenting the fine droplets of the microextraction solvent on the bottom of a test tube. The settled phase is transferred into a fluorometer for the determination of thiamine at excitation/emission wavelengths of 375/438 nm. Under the optimized experimental conditions, the method provides a linear dynamic range of 0.2–100 ng mL?1, a detection limit of 0.06 ng mL?1, and a relative standard deviation of 3.0%. The method was successfully applied to pharmaceutical formulations and human urine. The results were validated by recovery test and by comparison with other methods, and were found to be highly satisfactory. 相似文献
25.
The biosurfactant production potential of a new microbial consortium of Enterobacter cloacae and Pseudomonas sp. (ERCPPI-2) which was isolated from heavy crude oil-contaminated soil in the south of Iran, has been investigated under extreme environmental conditions. The isolated consortium produces a biosurfactant mixture with excessive oil spreading and emulsification properties. This consortium was able to grow and produce biosurfactant at temperatures up to 70 °C, pressures up to 6000 psia, salinities up to 15% (w/v), and in the pH range 4-10. Besides, the optimum biosurfactant production conditions were found to be 40 °C and 7.0 for the temperature and pH value, respectively. These conditions gave the best biosurfactant production of 1.74 g/1 when the cells were grown on a minimal salt medium containing 1.0% (w/v) olive oil, 1.0% (w/v) sodium nitrate supplemented with 1.39% (w/v) K(2)HPO(4) at 40 °C and 150 rpm after 48 h of incubation. The ERCPPI-2 could reduce surface and interfacial tensions to 31.7 and 0.65 mN/m from the original values of 58.3 and 16.9 mN/m, respectively. The isolated consortium produced biosurfactant using heavy crude oil as the sole source of carbon and emulsified the available heavy crude oil up to E(24)=83.4%. The results of the core holder flooding tests at simulated reservoir conditions demonstrated that the oil recovery efficiency due to the injection of the cell-free biosurfactant solution was 27.2%, and the bacterium injection reduced the final residual oil saturations to below 3% at optimum conditions. 相似文献
26.
Strategies for electrochemical sensing of DNA can be classified into label-free and label-based approaches, categories of which include enzyme-, nanomaterial- and redox labels that are attached to DNA either by covalent or non-covalent means. Metallointercalators represent one group of small molecule redox labels that non-covalently enter the groove of a DNA. The metallointercalator plays a dual-role in acting as a structure indicator (for hybridization) and a signal generator. Labeling is not needed, and electrochemical measurements can be carried out in a label-free solution of an electrolyte. However, such metallointercalators lack the option of catalytic signal generation as in the case of enzyme- and nanomaterial-based labels. Therefore, signal amplification becomes crucial. We first survey here recent progress in this area. A signal-amplifying system is presented that relies on the electroatalytic oxidation of a metallointercalator ruthenium(II)bipyridine/phenoxazine complex in the presence of electron donor species such as oxalate, DNA bases, or tripropylamine. Recent work on such DNA sensors is discussed. Results suggest that such metallointercalator-based DNA sensors represent a viable platform for developing high-throughput and automated PCR/lab-on-a-chip devices as well as visualized multifunctional DNA sensors.
DNA biosensors based on metallo-intercalator probes and electrocatalytic amplification 相似文献
27.
Azadbakht R Parviz M Tamari E Keypour H Golbedaghi R 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,82(1):200-204
A new macrocyclic chemosensor containing two naphthalene fluorophores has been synthesized. The fluorescent properties of this receptor has been studied in the presence of various metal ions such as Na+, Ag+, Cr3+, Mn2+, Fe3+, Co2+, Ni2+, Cu2+, Zn2+, Cd2+ and Pb2+. When increasing concentrations of Zn2+ ions were introduced, the emission of L was drastically increased (EFE = 4.34). This special change was not observed when other metal ions were used; such highly selective fluorescent response indicates that this receptor can easily discriminate Zn2+ ions from other similar species. Model calculations at DFT level further suggest the possible interaction mode, and relatively steric position between the host and guest also influence the optical response. 相似文献
28.
Foroutan-Nejad C Shahbazian S Rashidi-Ranjbar P 《Physical chemistry chemical physics : PCCP》2011,13(10):4576-4582
The nature of bonding and aromaticity of Ti(3)(CO)(3), a mill-shaped metal-carbonyl complex, is studied carefully. A unique bonding mechanism between metal and carbonyl groups is found in this species. Ti(3)(CO)(3) is an example of a metal-carbonyl complex with prominent metal to carbonyl donation. Moreover, it is proven that not only is Ti(3)(CO)(3) not an antiaromatic complex but also it is the first synthesized example of d-block, σ+π aromatic species. A quick survey among the first row of transition metals in the periodic table shows that other local minima with similar structures and aromaticity are present and Ti(3)(CO)(3) is the first synthesized species of an unknown family. 相似文献
29.
Non-uniform grid in finite-difference time-domain methods, which is typically used to resolve fine structures, can reduce the computational domain and therefore lead to a reduction of the computational cost. However, for high-accuracy problems, such as partially-filled parallel plate waveguide and resonators, using different grid size increases the truncation error at the boundary of domains having different grid size. To address this problem, in this work, we introduce the complementary derivatives method (CDM). Theoretical discussion and numerical results will be presented to show that the CDM can maintain second-order accuracy throughout the computational domain. 相似文献
30.
In this paper, an improved recovery method for target ssDNA using amino-modified silica-coated magnetic nanoparticles (ASMNPs) is reported. This method takes advantages of the amino-modified silica-coated magnetic nanoparticles prepared using water-in-oil microemulsion technique, which employs amino-modified silica as the shell and iron oxide as the core of the magnetic nanoparticles. The nanoparticles have a silica surface with amino groups and can be conjugated with any desired bio-molecules through many existing amino group chemistry. In this research, a linear DNA probe was immobilized onto nanoparticles through streptavidin conjugation using covalent bonds. A target ssDNA(I) (5′-TMR-CGCATAGGGCCTCGTGATAC-3′) has been successfully recovered from a crude sample under a magnet field through their special recognition and hybridization. A designed ssDNA fragment of severe acute respiratory syndrome (SARS) virus at a much lower concentration than the target ssDNA(I) was also recovered with high efficiency and good selectivity. 相似文献