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941.
Hong-Shuo Li J. M. Cadogan Jian-Min Xu S. X. Dou H. K. Liu 《Hyperfine Interactions》1994,94(1):1929-1935
A study of the Nd-Fe-Ti phases at the Fe-rich end of the phase diagram has been carried out using57Fe Mössbauer spectroscopy, scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDAX). In particular,57Fe Mössbauer spectroscopy has been used to characterize the phases present in these samples. In addition to the two well-known 217 and 112 phases, twonovel phases have been identified, with compositions denoted by3–29 and9–94, which are closely linked to the orthorhombic ScFe6Ga6-type and the hexagonal TbCu7-type structures, respectively. The possible crystal structures of these new phases will be discussed in terms of the dumbbell substitution sequence in the CaCu5 structure. 相似文献
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945.
可见光主动成像系统被广泛应用于成像侦察领域,激光压制干扰是一种可以利用的反制手段。合理地对激光干扰效果进行评估,对于干扰一方具有重要意义。为了更客观地评价激光干扰对成像侦察的影响,从可见光成像侦察的特点出发,对激光干扰可见光成像效果进行划分,确定了干扰效果评估需求。建立了可见光图像的激光干扰效果评估模型,结合基于YOLOv4的目标检测置信度及WFSIM算法的三个图像特征表征指标,形成了对应的评估体系。构建了一套参数可调的激光干扰图像采集及评估分析实验系统,对人体目标进行图像采集,验证了提出的评估体系及方法。 相似文献
946.
调频连续波(FMCW)雷达常用于测量多个目标的距离和速度,被广泛用于自动驾驶场景中。FMCW雷达产生的线性调频波称为啁啾(Chirp),通常由锁相环(PLL)电路产生。由于带宽有限,传统锯齿啁啾下降时间过长,降低了雷达性能。文章提出了一种基于分段电流电荷泵的快速啁啾发生器设计方案。调频阶段采用最佳电荷泵电流,即最优环路带宽,可保证啁啾的线性度。啁啾下降阶段使用更大的电流,可缩短下降时间。仿真结果表明,啁啾发生器频率输出范围为19.25~20.25 GHz, 1.2 V电压下整体功耗为31.8 mW。PLL带宽为1.5 MHz时,锯齿形啁啾下降的最大调制速率为454 MHz/μs。与恒定电荷泵电流方式相比,下降时间缩短了80%。 相似文献
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948.
Ting Wu Tianqun Lang Chao Zheng Wenlu Yan Yu Li Runqi Zhu Xin Huang Huae Xu Yaping Li Qi Yin 《Advanced functional materials》2023,33(7):2212109
The red blood cell membrane (RBCm) provides tight protection, lowers the immunogenicity, and prolongs the circulation time of drugs in vivo when acting as the coating of drug delivery systems. However, the cellular uptake and release of drugs are hindered by RBCm. Docetaxel (DTX) is the first-line medicine for treating triple-negative breast cancer (TNBC), but it induces tumor metastasis. To solve these dilemmas, in this study, the photosensitizer 1,1-dioctadecyl-3,3,3,3-tetramethylindotricarbocyanine iodide (DiR)-modified RBCm (DM) is prepared, which is coated onto a hybrid micelle consisting of the prodrugs of DTX and the anti-metastasis agent calcitriol (CTL), obtaining a nanoparticle, named HDC-DM. In a 4T1 tumor-bearing mouse model, after injecting HDC-DM, the intratumoral DTX and CTL concentrations are increased by 1.7 and 2.5 times compared with the free drug groups. After irradiating tumors with near-infrared laser, DiR elicits the photothermal effect, triggering the rupture of RBCm and drug release, promoting drug penetration in tumors, and inducing immunogenic cell death. The tumor growth inhibition rate is 77%, and the formation of lung metastases is reduced by 82%, with good biocompatibility. It is suggested that the combination of phototherapy, chemotherapy, and anti-metastatic therapy using HDC-DM is expected to be a powerful strategy for treating TNBC. 相似文献
949.
Jiacheng Yin Na Li Ming Liu Zhigang Li Xuemin Wang Mingren Cheng Ming Zhong Wei Li Yunhua Xu Xian-He Bu 《Advanced functional materials》2023,33(21):2211950
Organic redox-active materials are promising electrode candidates for lithium-ion batteries by virtue of their designable structure and cost-effectiveness. However, their poor electrical conductivity and high solubility in organic electrolytes limit the device's performance and practical applications. Herein, the π-conjugated nitrogen-containing heteroaromatic molecule hexaazatriphenylene (HATN) is strategically embedded with redox-active centers in the skeleton of a Cu-based 2D conductive metal–organic framework (2D c-MOF) to optimize the lithium (Li) storage performance of organic electrodes, which delivers improved specific capacity (763 mAh g−1 at 300 mA g−1), long-term cycling stability (≈90% capacity retention after 600 cycles at 300 mA g−1), and excellent rate performance. The correlation of experimental and computational results confirms that this high Li storage performance derives from the maximum number of active sites (CN sites in the HATN unit and CO sites in the CuO4 unit), favorable electrical conductivity, and efficient mass transfer channels. This strategy of integrating multiple redox-active moieties into the 2D c-MOF opens up a new avenue for the design of high-performance electrode materials. 相似文献
950.
Yi Lu Hao Zhang Yida Wang Xiaorong Zhu Weiping Xiao Haolan Xu Gaoran Li Yafei Li Deqi Fan Haibo Zeng Zupeng Chen Xiaofei Yang 《Advanced functional materials》2023,33(21):2215061
The rational design of economic and high-performance electrocatalytic water-splitting systems is of great significance for energy and environmental sustainability. Developing a sustainable energy conversion-assisted electrocatalytic process provides a promising novel approach to effectively boost its performance. Herein, a self-sustained water-splitting system originated from the heterostructure of perovskite oxide with 2D Ti3C2Tx MXene on Ni foam (La1-xSrxCoO3/Ti3C2Tx MXene/Ni) that shows high activity for solar-powered water evaporation and simultaneous electrocatalytic water splitting is presented. The all-in-one interfacial electrocatalyst exhibits highly improved oxygen evolution reaction (OER) performance with a low overpotential of 279 mV at 10 mA cm−2 and a small Tafel slope of 74.3 mV dec−1, superior to previously reported perovskite oxide-based electrocatalysts. Density functional theory calculations reveal that the integration of La0.9Sr0.1CoO3 with Ti3C2Tx MXene can lower the energy barrier for the electron transfer and decrease the OER overpotential, while COMSOL simulations unveil that interfacial solar evaporation could induce OH− enrichment near the catalyst surfaces and enhance the convection flow above the catalysts to remove the generated gas, remarkably accelerating the kinetics of electrocatalytic water splitting. 相似文献