全文获取类型
收费全文 | 3087篇 |
免费 | 356篇 |
国内免费 | 347篇 |
专业分类
化学 | 1698篇 |
晶体学 | 21篇 |
力学 | 110篇 |
综合类 | 4篇 |
数学 | 380篇 |
物理学 | 771篇 |
无线电 | 806篇 |
出版年
2024年 | 5篇 |
2023年 | 81篇 |
2022年 | 83篇 |
2021年 | 115篇 |
2020年 | 150篇 |
2019年 | 127篇 |
2018年 | 97篇 |
2017年 | 99篇 |
2016年 | 128篇 |
2015年 | 143篇 |
2014年 | 139篇 |
2013年 | 217篇 |
2012年 | 225篇 |
2011年 | 256篇 |
2010年 | 160篇 |
2009年 | 165篇 |
2008年 | 205篇 |
2007年 | 172篇 |
2006年 | 145篇 |
2005年 | 162篇 |
2004年 | 81篇 |
2003年 | 71篇 |
2002年 | 65篇 |
2001年 | 69篇 |
2000年 | 67篇 |
1999年 | 59篇 |
1998年 | 49篇 |
1997年 | 45篇 |
1996年 | 54篇 |
1995年 | 51篇 |
1994年 | 48篇 |
1993年 | 36篇 |
1992年 | 30篇 |
1991年 | 39篇 |
1990年 | 27篇 |
1989年 | 17篇 |
1988年 | 17篇 |
1987年 | 14篇 |
1986年 | 16篇 |
1985年 | 12篇 |
1984年 | 12篇 |
1983年 | 5篇 |
1982年 | 8篇 |
1981年 | 7篇 |
1980年 | 4篇 |
1979年 | 5篇 |
1977年 | 2篇 |
1975年 | 3篇 |
1968年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有3790条查询结果,搜索用时 250 毫秒
101.
Yushu Liu Chun Gao Qing Li Prof. Dr. Huan Pang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(9):2141-2160
Nickel oxide (NiO) has emerged as one of the most promising transition-metal oxides (TMOs) for electrochemical capacitors, batteries, catalysis, and electrochromic films, owing to its cost-effectiveness, abundance, and well-defined electrochemical properties. Recent studies have identified that mixing NiO with graphene or graphene derivatives results in novel composites with synergistic effects and superior electrochemical performance. This review summarizes the latest advances in composites of NiO with graphene or graphene derivatives. The synthetic strategies, morphologies, and electrochemical performance of these composites are introduced, as well as their electrochemical applications in supercapacitors, batteries, sensors, catalysis, and so forth. Finally, tentative conclusions and assessments regarding the opportunities and challenges for the future development of these composites and other TMOs/graphene or graphene-derived composites are presented. 相似文献
102.
Dr. You Xu Xingjie Chai Tianlun Ren Hongjie Yu Shuli Yin Dr. Ziqiang Wang Prof. Dr. Xiaonian Li Prof. Dr. Liang Wang Dr. Hongjing Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(70):16074-16080
The realization of water electrolysis on the basis of highly active, cost-effective electrocatalysts is significant yet challenging for achieving sustainable hydrogen production from water. Herein, N-doped Ni3S2/N-doped MoS2 1D hetero-nanowires supported by Ni foam (N-Ni3S2/N-MoS2/NF) are readily synthesized through a chemical transformation strategy by using NiMoO4 nanowire array growth on Ni foam (NiMoO4/NF) as the starting material. With the in situ generation of Ni3S2/MoS2 heterointerfaces within nanowires and the incorporation of N− anions, an extraordinary hydrophilic nature with abundant, well-exposed active sites and optimal reaction dynamics for both oxidation and reduction of water are obtained. Attributed to these properties, as-converted N-Ni3S2/N-MoS2/NF exhibits highly efficient electrocatalytic activities for both hydrogen and oxygen evolution reactions under alkaline conditions. The superior bifunctional properties of N-Ni3S2/N-MoS2/NF enable it to effectively catalyze the overall water-splitting reaction. 相似文献
103.
In this paper, we study the normality of the family of meromorphic functions from the viewpoint of hyperbolic metric. Then, a new sufficient and necessary condition is obtained, which can determine a given family of meromorphic functions is normal or not. 相似文献
104.
Bingyan Jiang Lei Zhang Jie Yan Qingquan Huang Bing Liao Hao Pang 《Journal of polymer science. Part A, Polymer chemistry》2014,52(17):2442-2453
A series of well‐defined thermoresponsive graft polymers with different lengths and graft densities, poly(glycidyl methacrylate)‐graft‐poly(N‐isopropylacrylate) (PGMA‐g‐PNIPAM), were successfully prepared by combination of controlled/living free radical polymerization and click chemistry. Effects of grafting length and density on the thermoresponsive behavior, aggregating mean diameter, and self‐assembly morphology are systematically investigated. The thermosensitive characteristics of graft polymers in aqueous solution prove that the length and graft density had positive co‐relationship with the lower critical solution temperature value and mean diameter of micelles as well as the size distribution, while the effect of graft length of polymers is more significant than that of density. Transmission electron microscopy analysis shows that the conformations of PGMA45‐g‐PNIPAM20 and PGMA45‐g‐PNIPAM46 with longer length and bigger grafting density in aqueous solutions are spherical nanoparticles with the increasing trend of the diameters, while that of PGMA45‐g‐PNIPAM(73, 50%) shows a spherical‐like morphology, which indicates that the graft length and density have a significant effect on the mean diameter of micelle but not on the self‐assembly morphology. These results reveal that to obtain desired thermoresponsive behavior and self‐assembly morphology of functional polymers, it is essential to design and fabricate the structure of graft polymers with proper length and graft density. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 2442–2453 相似文献
105.
Inside Back Cover: Ultrathin WS2 Nanoflakes as a High‐Performance Electrocatalyst for the Hydrogen Evolution Reaction (Angew. Chem. Int. Ed. 30/2014)
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
106.
Hua Pang 《Telematics and Informatics》2018,35(8):2147-2156
Although WeChat has recently spawned significant resolutions in technology-mediated social contact and interpersonal communication, the research regarding the social and psychological impacts of the newly emerging technology is relatively few. The primary purpose of the current empirical research is to unearth whether and how WeChat interaction could enhance overseas students’ sense of subjective well-being by concentrating on social integration, bridging relationships, and bonding relationships. Using web-based data of 228 Chinese subjects, the obtained results reveal that the time spent on WeChat significantly and directly impacts users’ subjective well-being. Additionally, the findings demonstrate that social integration, bridging relationships, bonding relationships are all significant predictors to subjective well-being. Furthermore, the perceptions of social integration and social capital could play the crucial mediating roles in the connection between WeChat use and the dependent variable of subjective well-being. Therefore, these outcomes may shed light on a more nuanced comprehending of the influence of the new social media interaction on sojourner’s social adaption and overall life quality in the digital age. 相似文献
107.
Jing He Mohan Yu Maofu Pang Yanqing Fan Zhe Lian Dr. Ying Wang Prof. Wenguang Wang Prof. Yajun Liu Prof. Hua Jiang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(13):e202103832
Structural designs combining cycloparaphenylenes (CPPs) backbone with planar chiral [2.2]paracyclophane ([2.2]PCP) lead to optical-active chiral macrocycles with intriguing properties. X-ray crystal analysis revealed aesthetic necklace-shaped structures and size-dependent packages with long-range channels. The macrocycles exhibit unique photophysical properties with high fluorescence quantum yield of up to 82 %, and the fluorescent color varies with ring size. In addition, size-dependent chiroptical properties with moderately large CPL dissymmetry factor of 10−3 and CPL brightness in the range of 30–40 M−1 cm−1 were observed. 相似文献
108.
Yue Liu Mingxin Lv Lu Li Hailong Yu Qiong Wu Jinhui Pang Yuxiang Liu Congxia Xie Shitao Yu Shiwei Liu 《应用有机金属化学》2019,33(4)
An amino‐functionalized silica‐coated Fe3O4 nanocomposite (Fe3O4@SiO2/APTS) was synthesized. The Fe3O4@SiO2 microspheres possessed a well‐defined core–shell structure, uniform sizes and high magnetization. An immobilized ruthenium nanoparticle catalyst (Fe3O4@SiO2/APTS/Ru) was obtained after coordination and reduction of Ru3+ on the Fe3O4@SiO2/APTS nanocomposite. The Ru nanoparticles were not only ultra‐small with nearly monodisperse sizes but also had strong affinity with the surface of Fe3O4@SiO2/APTS. The obtained catalyst exhibited excellent catalytic performance for the hydrogenation of a variety of aromatic nitro compounds, even at room temperature. Moreover, Fe3O4@SiO2/APTS/Ru was easily recovered using a magnetic field and directly reused for at least five cycles without significant loss of its activity. 相似文献
109.
Acta Mathematicae Applicatae Sinica, English Series - For the variational inequality with symmetric cone constraints problem, we consider using the inexact modified Newton method to efficiently... 相似文献
110.
Zhang Ning Zhang Bin Pang Yong Yang Hong-Sheng Zong Lu Duan Yong-Xin Zhang Jian-Ming 《高分子科学》2022,40(4):373-383
Chinese Journal of Polymer Science - Macromolecule nanocrystal network and strong interfacial interaction are always beneficial to enhance the mechanical property of polymer-based nanocomposites.... 相似文献