Thermal hazard assessment and ranking for organic peroxides using quantitative structure–property relationship approaches

Journal of Thermal Analysis and Calorimetry - Chemical reactivity hazards of organic peroxides are major concerns of the chemical industry due to many serious incidents every year. Thermal hazard...     

Esterification of α-olefins catalyzed by homogeneous and polymer supported phosphine - palladium - tin chloride complexes

The polymer phosphine ligand with various crosslinkage and phosphine contents was prepared by copolymerization of diphenylvinyl-phosphine with divinylbenzene using 2,2′ -azobisisobutyronitrile (AIBN) as initiator. Linear methyl heptanoate in high yield was obtained from hexene-l catalyzed by polymer-supported and homogeneous phosphine-palladium-tin chloride complex. Comparison with the homogeneous catalyst, the polymer catalyst had higher activity and almost the same selectivity. The effects of the catalyst composition, the structure of the polymer ligand and other experimental variables on the catalytic activity and selectivity of the polymer catalyst have been examined, and are discussed in relation to the mode of this catalysis.     

SMDP-based sleep policy for base stations in heterogeneous cellular networks

A dense heterogeneous cellular network can effectively increase the system capacity and enhance the network coverage. It is a key technology for the new generation of the mobile communication system. The dense deployment of small base stations not only improves the quality of network service, but also brings about a significant increase in network energy consumption. This paper mainly studies the energy efficiency optimization of the Macro-Femto heterogeneous cellular network. Considering the dynamic random changes of the access users in the network, the sleep process of the Femto Base Stations (FBSs) is modeled as a Semi-Markov Decision Process (SMDP) model in order to save the network energy consumption. And further, this paper gives the dynamic sleep algorithm of the FBS based on the value iteration. The simulation results show that the proposed SMDP-based adaptive sleep strategy of the FBS can effectively reduce the network energy consumption.     

低压供热涂层材料制备及热性能研究

低压供热技术具有安全系数高和节能降耗等优势,因而成为石化稠油长输管线、风力发电叶片冬季防覆冰和室内供暖等领域的研究热点之一。本文制备了一系列低压供热涂层材料,研究不同碳功能填料对涂层发热速率、发热功率及最高发热温度的影响规律,并揭示石墨烯和碳纤维对提升涂层材料热性能的协同作用。其中石墨烯纳米片的还原程度对材料热性能具有重要影响,降低其表面官能团密度对提升涂层供热特性具有促进作用,但是官能团密度过低会导致石墨烯纳米片的团聚现象,引起涂层发热不均匀。加入适量碳纤维可以提高石墨烯的均匀分散性,提升发热速率。优化石墨烯纳米片和碳纤维的比例后,采用24V电压驱动时,涂层材料的发热速率达到7.1℃·s^-1,功率密度为800W·m^-2,最高发热温度为124℃。     

Contrast enhancement in retinal image via multi-scale geometrical analysis

Recently,there has been a growing awareness to theobservation that wavelets may not be the best choiceforrepresenting natural i mages .This observation is due tothe fact that wavelets are blindtothe smoothness alongthe edges commonly found in i mages .In …     

Use of generalized refined composite multiscale fractional dispersion entropy to diagnose the faults of rolling bearing

Nonlinear Dynamics - A typical symptom of vibration signals collected from rolling bearings with local faults is the existence of periodic transients, which makes the intrinsic structure of...     

The recent progress of functionally graded CNT reinforced composites and structures

In the last decade,the functionally graded carbon nanotube reinforced composites(FG-CNTRCs)have attracted considerable interest due to their excellent mechanical properties,and the structures made of FG-CNTRCs have found broad potential applications in aerospace,civil and ocean engineering,automotive industry,and smart structures.Here we review the literature regarding the mechanical analysis of bulk CNTR nanocomposites and FG-CNTRC structures,aiming to provide a clear picture of the mechanical modeling and properties of FG-CNTRCs as well as their composite structures.The review is organized as follows:(1)a brief introduction to the functionally graded materials(FGM),CNTRCs and FG-CNTRCs;(2)a literature review of the mechanical modeling methodologies and properties of bulk CNTRCs;(3)a detailed discussion on the mechanical behaviors of FG-CNTRCs;and(4)conclusions together with a suggestion of future research trends.     

THE DETERMINATION OF THE COMPUTATIONAL DEGREES OF FREEDOM OF BAR SYSTEMS1)

为了简化和统一结构力学教材中杆件体系计算自由度$W$的算法,本文提出了“直接法”。该方法以相邻节点间的杆件和结点为分析对象,对于含$m$根杆件、$g$ 个单刚结点和$h$个单铰结点的平面杆件体系,直接法给出计算自由度公式$W=3m-(3g+2h$)。相比于已有方法,直接法研究对象清晰,数学运算统一,适合于编程计算,便于初学者准确而快速计算复杂体系的$W$;也为结构超静定次数的确定提供了一种简单有效的数值算法。