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81.
Gefeson Mendes Pacheco Eugenio Scalise Jr. Nori Beraldo 《Journal of Infrared, Millimeter and Terahertz Waves》1993,14(8):1619-1625
The two main constrains on the characteristics of the acousto-optic deflector are the acoustic sound attenuation and velocity. These two parameters will determine the resolution and the radio frequency bandwidth. Due to a double degenerated phase matching condition on a specific acousto-optic deflector configuration, the possibility of an improvement on the resolution of the acousto optic deflector becomes evident. This degenerescence is the result of the action of a D.C. electric field by the electro-optic effect. This configuration presents several advantages upon the early related works based on optical activity of selected materials and enables a wideband interaction in such a way that the number of resolvable channels is kept high. This has implications on the acousto-optic spectrometers for wideband radio astronomy research. 相似文献
82.
D.J. Morrissey G.J. Wozniak L.G. Sobotka R.J. McDonald A.J. Pacheco L.G. Moretto 《Nuclear Physics A》1985,442(3):578-604
The angular distributions of sequential fission fragments have been measured for the reactions of 40Ar with 197Au and 238U as a function of reaction Q-value and charge transfer. These angular, distributions are used to study the angular momentum and alignment of the deep-inelastic products which undergo fission. All of the fission fragment angular distributions are strongly focused into the plane defined by the beam and the projectile-like fragment velocity vectors. The in-plane angular distributions from reactions with uranium are isotropic for small energy losses and become anisotropic as the energy loss increases. For large negative Q-values, the in-plane anisotropy increases as the deep-inelastic products become more symmetric. The variation of the in-plane anisotropy with mass asymmetry for the two systems in this work was compared to a compilation of previous work and a consistent pattern was found. These alignment data are compared to equilibrium statistical calculations. 相似文献
83.
W-D Schöne W. Ekardt J. M. Pacheco 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1996,36(1):65-67
The effect of the ionic positions on the optical spectra of magic metal clusters is studied via pseudopotential perturbation theory. Electronic many-body effects are considered within perturbed time-dependent local-density-approximation. Quantitative agreement with recent experiments by Reiners et al. is obtained. In this way a natural explanation is obtained for the temperature dependence of the optical absorption of magic metal clusters. 相似文献
84.
A technique for efficient Raman conversion of an excimer pumped dye laser is described, based on the use of a Raman oscillator/amplifier combination. A photon conversion efficiency of 90% to first Stokes is demonstrated, with diffraction-limited beam quality. 相似文献
85.
Suzuki TM Llosa Tanco MA Pacheco Tanaka DA Hayashi H Takahashi Y 《The Analyst》2005,130(11):1537-1542
A Pb(2+) selective membrane filter was fabricated from the fibrous CeO(H(2)PO(4))(2).2H(2)O (CeP) crystals by blending with cellulose fiber. Enrichment of ppb level of Pb(2+) was achieved simply by filtration of aqueous sample solution through the membrane filter. Pb(2+) was strongly retained on the membrane filter by accommodation into the interlayer gallery of a CeP crystal. Visual detection of the enriched Pb(2+) was achieved by subsequent color signaling as PbS deposit upon treatment of the membrane filter with 3% Na(2)S solution. The analytical procedure and sample treatment conditions were optimized with respect to pH of the sample solution, filtration rate and masking of interfering ions. Detection of 20 ppb of Pb(2+) was not interfered by the presence of 1000-fold of Ca(2+), Mg(2+), and up to 100-fold of Fe(3+)and Cu(2+) by masking with 1 x 10(-3) mol dm(-3) of iminodiacetic acid (IDA). Most anions including phosphate (20 000 times) did not interfere with the determination of Pb(2+). The present simple method was applied to the determination of Pb(2+) in real samples like mine valley water. 相似文献
86.
Ana Maria Rocco Daniel Perrone Moreira Robson Pacheco Pereira 《European Polymer Journal》2003,39(9):1925-1934
Blends of poly(ethylene oxide) (PEO) of high molecular weight with poly(bisphenol A-co-epichlorohydrin) (PBE) with high epoxy equivalent were studied spectroscopically, thermally and morphologically. As similar systems of low molecular weight, a single Tg was observed for all blends, indicating miscibility. A progressive decrease in the degree of crystallinity and in the size of the PEO spherulites as the PBE is added is also observed. Quantitative analysis from FTIR spectra provided determination of specific interactions between the constituents and their variation with PEO content. Simulations were performed utilising the spectra of the pure polymers to confirm that the observed changes in the experimental spectra of the blends were due to interaction between the polymers. 相似文献
87.
Merlin Rosales Jesús A. Durn ngel Gonzlez Ins Pacheco Roberto A. Snchez-Delgado 《Journal of molecular catalysis. A, Chemical》2007,270(1-2):250-256
Cationic rhodium and iridium complexes of the type [M(COD)(PPh3)2]PF6 (M = Rh, 1a; Ir, 1b) are efficient precatalysts for the hydroformylation of 1-hexene to its corresponding aldehydes (heptanal and 2-methylhexanal), under mild pressures (2–5 bar) and temperatures (60 °C for Rh and 100 °C for Ir) in toluene solution; the linear to branched ratio (l/b) of the aldehydes in the hydroformylation reaction varies slightly (between 3.0 and 3.7 for Rh and close to 2 for Ir). Kinetic and mechanistic studies have been carried out using these cationic complexes as catalyst precursors. For both complexes, the reaction proceeds according to the rate law ri = K1K2K3k4[M][olef][H2][CO]/([CO]2 + K1[H2][CO] + K1K2K3[olef][H2]). Both complexes react rapidly with CO to produce the corresponding tricarbonyl species [M(CO)3(PPh3)2]PF6, M = Rh, 2a; Ir, 2b, and with syn-gas to yield [MH2(CO)2(PPh3)2]PF6, M = Rh, 3a; Ir, 3b, which originate by CO dissociation the species [MH2(CO)(PPh3)2]PF6 entering the corresponding catalytic cycle. All the experimental data are consistent with a general mechanism in which the transfer of the hydride to a coordinated olefin promoted by an entering CO molecule is the rate-determining step of the catalytic cycle. 相似文献
88.
Voltammetric determination of copper and lead in gasoline using sample preparation as microemulsions. 总被引:1,自引:0,他引:1
Carlos E Cardoso Wagner F Pacheco Rangel Sarubi Márcio L N Ribeiro Pércio A M Farias Ricardo Q Aucélio 《Analytical sciences》2007,23(9):1065-1069
A voltammetric method for the determination of Cu(II) and Pb(II) in gasoline using sample preparation as three-component solutions (gasoline:propan-1-ol:water, 25:60:15 v/v/v) is proposed. HNO(3) was employed as a supporting electrolyte and to allow the use of aqueous inorganic standards for calibration, even if the analyte species originally in gasoline is present as a metallo-organic form. A square-wave anodic sequential determination was used by measuring the stripping current of Cu(II) (at +104 mV) using a glassy carbon electrode (GCE) and, in a second run, measuring the Pb(II) stripping current (at -470 mV) using a bismuth-film deposited on the surface of the GCE. The method allowed the quantification of 1.7 x 10(-9) mol L(-1) of Cu and 1.4 x 10(-10) mol L(-1) of Pb employing a 1500-s accumulation time. Recovery tests using analyte spiked three-component solutions prepared with commercial gasoline samples enabled recoveries of Cu and Pb from 97 +/- 8 to 102 +/- 5%. 相似文献
89.
90.
Merlín Rosales Gustavo Chacón Angel González Inés Pacheco Pablo J. Baricelli 《Reaction Kinetics and Catalysis Letters》2007,92(1):105-110
The effect of the addition of triphenylphosphine sulfide, thiophene, benzo[b]thiophene and dibenzo[b,d]thiophene on the hydroformylation of 1-hexene catalyzed by rhodium complexes RhH(CO)4, RhH(CO)2(PPh3)2 and RhH(CO)2(diphos) was studied. The addition of these sulfur compounds did not affect the activity of non modified rhodium precatalysts,
decreased the activity of the PPh3-modified one and increased the activity of the diphos-modified ones, which is indicative of the sulfur tolerance of these
precatalysts. The linear to branched ratio (l/b) varied from 0.5 to 3.4 for the non-modified precatalyst, and from 1.7 to
3.3 for the phosphine-modified ones. 相似文献