Copolymerization of styrene and norbornene with β‐diketiminato nickel/methylaluminoxane catalytic system

Styrene–norbornene (S‐N) copolymerizations were carried out using β‐diketiminato nickel complexes CH{C(CF₃)NAr}₂NiBr (Ar = 2,6‐ⁱPr₂C₆H₃, 1 ; Ar = 2,6‐Me₂C₆H₃, 2 ) in the presence of methylaluminoxane. The influence of the comonomer feed content and polymerization temperature on the conversion and composition of the copolymers with the catalytic system was investigated. An increase in the feed ratio of S/N led to an increase in the incorporated styrene content of the resulting copolymer. NMR characterization of the copolymers generated with the catalytic systems showed that the random S‐N copolymers are produced. Differential scanning calorimetric determination of the copolymers shows higher T_g values than polystyrene, and gel permeation chromatographic measurements have shown that the copolymers possess rather narrow molecular weight distributions, suggesting that the copolymerization take place at a single active site. Copyright © 2012 John Wiley & Sons, Ltd.     

可光纤集成的相干态量子身份认证系统

报道了可光纤集成相干态量子身份认证实验系统。该系统采用偏振相干态的斯托克斯矢量作为量子信号载体,采用动态偏振控制器作为信号调制器,利用固有的相干态量子噪声保证系统的安全性。自行设计了脉冲激光驱动电路、微弱窄脉冲激光探测电路、信号同步模块,采用Socket网络通信程序在TCP/IP局域网中实现了量子保密通信所需要的经典通信。该相干态量子身份认证系统采用的运行密钥为12位,每个光脉冲包含40000个光子,传输速率达到8kbit/s,合法用户间误码率(BER)小于10-4。每传输一个比特信息,攻击者所能窃取的信息量I(Alice,Eve)<10-14bit。     

Theoretical Study of Optically Pumped NH3 Far-Infrared Laser in Vibrational Ground State

In this paper, the density matrix equation of three-level system for far-infrared (FIR) Raman transition in vibrational ground state was solved. By means of iteration method and numerical calculation, the spectral characteristics of NH₃ molecules FIR laser with TEA CO₂-10R(14) laser pumping was studied theoretically. The theoretical result would help us to understand the physical mechanism of optically pumped molecular gases FIR laser with ground-state reversal transition.     

Stoichiometry Control for the Tuning of Grain Passivation and Domain Distribution in Green Quasi‐2D Metal Halide Perovskite Films and Light‐Emitting Diodes

Quasi‐2D metal halide perovskite films are promising for efficient light‐emitting diodes (LEDs), because of their efficient radiative recombination and suppressed trap‐assisted quenching compared with pure 3D perovskites. However, because of the multidomain polycrystalline nature of solution‐processed quasi‐2D perovskite films, the composition engineering always impacts the emitting properties with complicated mechanisms. Here, defect passivation and domain distribution of quasi‐2D perovskite films prepared with various precursor compositions are systematically studied. As a result, in perovskite films prepared from stoichiometric quasi‐2D precursor compositions, large organic ammonium cations function well as passivators. In comparison, precursor compositions of simply adding large organic halide salt into a 3D perovskite precursor ensure not only the defect passivation but also the effective formation of quasi‐2D perovskite domains, avoiding unfavorable appearance of low‐order domains. Quasi‐2D perovskite films fabricated with a well‐designed precursor composition achieve a high photoluminescence quantum yield of 95.3% and an external quantum efficiency of 14.7% in LEDs.     

Layered Silicon‐Based Nanosheets as Electrode for 4 V High‐Performance Supercapacitor

Silicon‐based materials have shown great potential and been widely studied in various fields. Unlike its unparalleled theoretical capacity as anodes for batteries, few investigations have been reported on silicon‐based materials for applications in supercapacitors. Here, an electrode composed of layered silicon‐based nanosheets, obtained through oxidation and exfoliation, for a supercapacitor operated up to 4 V is reported. These silicon‐based nanosheets show an areal specific capacitance of 4.43 mF cm^?2 at 10 mV s^?1 while still retaining a specific capacitance of 834 µF cm^?2 even at an ultrahigh scan rate of 50 000 mV s^?1. The volumetric energy and power density of the supercapacitor are 7.65 mWh cm^?3 and 9312 mW cm^?3, respectively, and the electrode can operate for 12000 cycles in a potential window of 4 V at 2 A g^?1, while retaining 90.6% capacitance. These results indicate that the silicon‐based nanosheets can be a competitive candidate as the supercapacitor electrode material.     

面向近眼式应用的快速瞳孔中心定位算法

针对Hough圆变换、最小二乘法椭圆拟合瞳孔中心定位算法中运算量大的问题,提出一种基于椭圆外切矩形的快速瞳孔中心定位算法。该算法从人眼图像中通过阈值分割得到瞳孔区域,对瞳孔区域进行边缘像素点的提取,然后利用椭圆外切矩形模型定位出瞳孔中心。通过Matlab对中国科学院自动化研究所公开的虹膜数据库中756张人眼图像进行遍历实验验证,所提算法定位准确率为98.3%,平均用时0.192 s。在同等条件下,与Hough圆变换、最小二乘法椭圆拟合算法进行对比,在保证定位准确率的同时,所提算法平均用时更少。实验结果表明,所提算法能够快速准确地完成瞳孔的中心定位。     

功率型白光LED可靠性的实验及仿真建模研究

快速推广LED产品到照明市场最主要的障碍在于长期的可靠性测试问题。由于长期的LED可靠性测试不符合快速且低成本的要求,因此本实验对白光LED进行步进式加速寿命老化测试,步进式环境温度从55oC到145oC变化。同时,对LED进行结温测试,并使用COMSOL仿真软件进行温度场分布仿真来模拟器件的发热情况,结果表明荧光胶处的温度高于LED芯片温度。在长期老化之后,对LED的光度进行测量,可以对LED的失效机理进行分析。通过研究温度对LED的光谱功率分布衰减的影响及光通量衰减的影响,发现在经过近3500 h的老化之后,LED的光衰很严重,表明电流及高温对LED的影响是极大的。     

周期准互补序列集构造法

该文基于2元序列支撑集和低相关序列集,提出一种新的周期准互补序列集构造框架。在此框架基础上,分别利用最优4元序列族A、族D和Luke序列集提出了3类渐近最优和渐近几乎最优周期准互补序列集,序列集参数由2元序列和低相关序列集共同决定。与传统的完备互补序列集相比,所构造的准互补序列集具有更多的序列数目,应用到多载波扩频通信系统中可以支持更多的用户。