Synthesis of Two Novel Rhenium（I） Bipyridyl Photosensitive Dyes

Two novel rhenium(I) 2, 2′-bipyridyl complexes, [(4,4′-di-COOEt-bipy) Re(CO)3 (NCCH3)PF6] and [(4,4′-di-COOEt-bipy) Re (CO)3 (NCS)], a model complex [(4,4′-di-COOEt-bipy) Re (CO)3 (pyridine)PF6], were synthesized. Their ground state electronic spectra and emission spectra were measured in acetonitrile. The MLCT absorption maximum of the complex exhibited a considerable red shift as the ligand changed from pyridine to CNCH3, or SCN.     

在酸性条件下合成氧化亚铜纳米立方体(英)

在微酸性(pH：4～6)的水热体系中130 ℃反应18 h合成了氧化亚铜纳米粒子，粒径约为100 nm，呈立方体外形。乙二胺和十六烷基胺在反应体系中充当缓冲试剂，调节反应液的pH值并控制体系中游离Cu²⁺的浓度，使得Cu²⁺不会被迅速还原成单质铜。所合成的纳米立方体的能带宽度约为2.51 eV，比氧化亚铜体材料和氧化亚铜纳米线蓝移了0.51 eV和0.17 eV，它有利于把太阳光谱中能量高的可见光转化成其他形式的能量。     

Catalytic Synthesis of Isopropyl Benzene over SO4^2-/ZrO2 -MCM-41

Introduction Owingtotheirlargeporediametersandlargesur faceareas,silicon basedmolecularsieves(M41S)have receivedmuchattention[1—5]inthefieldsofcatalytic reactions,adsorptiveseparations,andnonmetallicma terialsscience.MCM41isthemosttypicalmaterialof thisk…     

Synthesis of Molecularly Imprinted Polymer Particles by Suspension Polymerization in Silicon Oil

Molecular imprinting is a method to prepare polymers with recognition site of desired and predetermined selectivity1. Molecularly imprinted polymers (MIP) are prepared by copolymerizing functional and cross-linking monomers in the presence of a molecular …     

CdS和CdSe新型纳米结构的高效溶剂热合成

采用快速高效的溶剂热法合成了海星形CdS纳米结构和一维CdSe纳米结构。用XRD、SEM和UV-Vis等表征手段对产物进行了表征，结果表明产物为单一的CdS和CdSe纳米结构，且CdS纳米结构具有良好的分散性，其形成极大地受到pH值影响，而CdSe先形成层状的二维结构、再形成一维纳米结构。     

Novel Water Soluble Fluorescent Trimethine Indocyanines Containing N-ρ-Carboxybenzyl Group

Indocyanine dyes as fluorescent labeling reagents have been used in bioanalysis1,2. Arylsulfonate indocyanine dyes 1d and 1e developed by Waggoner A. S. et al.3,4 have excellent fluorescent properties combined with good aqueous solubility, are a new generation of fluorescent label compounds for proteins, oligonucleotides and other compounds containing hydroxyl, mercaptol or primary amine groups5. However, photostability of these dyes has been a problem. Z. G. YAO et al.6 reported that p…     

一种具有O信息复杂度的高速crossbar调度算法

本文提出一种可扩展性强的高速crossbar调度算法——iRGRR(iterative request-grant-based round-robin),它通过简化处理流程和减小调度开销,克服了传统算法(例如iSLIP^[1]、PIM^[2])可扩展性差的缺陷.iRGRR将控制信息复杂度从O(N)级大大减小到O(logN)级,具有良好的可扩展性,可应用于太比特交换机/路由器中.仿真结果表明,在各种不同的均匀和非均匀业务流下,iRGRR能够获得与iSLIP几乎相同的性能.另外,iRGRR比iSLIP具有更好的公平性以及更加易于用硬件实现.     

我国掺稀土光纤的现状分析

掺稀土光纤作为激光增益介质在光纤通信、光纤激光器和传感器等领域有着广泛的应用,国内掺铒光纤、掺镱光纤的市场曾长期被Corning、Lucent等国外光纤制造厂商所垄断,近年来我国掺铒光纤、掺镱光纤的研究取得了很大进展,已部分替代国外进口.文章主要介绍国内掺铒光纤、掺镱光纤的研究现状和发展趋势.     

图像通信业务的现状与发展方向

阐述了图像通信的业务涵盖范围及其技术发展现状，简要介绍了图像通信的发展方向，指出了图像通信产业发展面临的研究课题。     

可键控的高频信号发生器的设计

介绍了一种键控式的采用单片机对高频函数发生电路进行程序控制的高频信号发生器的设计方案。此方案能产生方波、正弦波和三角波等信号;采用数字频率合成器,使输出信号频稳度和晶体振荡器的相当;并用键盘设置波形和频率,由LED显示。输出信号的频率分成1 MHz~16 MHz和8 kHz~999 kHz两挡。