SnMe3/Pt/HY分子筛的合成与表征

在高真空系统下研究了SnMe4与Pt修饰的HY沸石分子筛表面的接枝反应,并用元素分析、FT-IR,XRD,DRS,BET,GC等表征了接枝产物的组成和性质。结果表明：Pt／HY沸石的表面羟基可以与SnMe4在常温下反应,将三甲基锡基团接枝在沸石的超笼中。Pt／HY与SnMe4发生接枝反应后晶相结构没有改变,微孔体积和BET表面积都下降。     

Experimental Measurements for the QEC-Value of 183Os-Decay

Activities of ¹⁸³Os were produced by 39MeV α particles bombarding on a natural tungsten target.β⁺ spectrum with coincidence gate set on the strongest 382keV γ-rays of ¹⁸³Os decay was measured.The endpoint energy of the β⁺ spectrum was determined and the Q_EC value of ¹⁸³Os decay was extracted to be 2.24±0.10MeV which is in good agreement with the predicted value 2.30±0.10MeV on the basis of mass systematics.     

A SYSTEMATIC DISTORTED WAVE IMPULSE APPROXIMATION ANALYSIS OF THE CONVENTIONAL MECHANISM FOR PION DOUBLE CHARGE EXCHANGE

In the framework of the distorted wave impulse approximation,a systematic analysis is performed for the contribution from the conventional mechanism to the double charge exchange to the double isobaric analog state.The effects of distortions of pions,nuclear wave functions,short-range correlation functions,parameters of form factors,the spin-dependent term in the πN amblitude etc.are examined.It is shown that all these elements are very important and not negligible for the conventional mechanism.But after including the effects of all these elements,the conventional mechanism is still not able to reproduce the experimental excitation function and agular distribution for the energy region of 0—300MeV,therefore the effects of some other mechanisms should be included.     

甾体植物生长促进剂的研究 VIII: 3α-羟基-7-氧-6-酮-B-高-5α-胆烷酸甲酯的区域选择性合成

油菜甾醇是以油菜花粉分离到的一种促进植物生长甾体, 能促进细胞生长和分裂,与已知植物生长的元素相比, 它具有广谱生物活性, 因此他可能在农业上有实际应用的价值.本文报道了3α-羟基-7-氧-6-酮-B-高-5α-胆烷酸甲酯的区域选择性合成.     

反-1,2-双 二唑基取代环丙烷的合成与环丙烷环的不饱和性

本文合成了一个新的反-1,2-双芳杂环取代的环丙烷类化合物─反-1,2-双-2'-[5'-(对乙基苯基-1',3',4'- 二唑基)]环丙烷(Et-BDCP), 研究了其紫外吸收光谱及其荧光激发与发射光谱, 并通过与Et-BPDS, Et-BPDE和Et-PDDDP光谱性质的比较; 以及用MNDO方法对模型化合物(1-8)所进行了模拟量子化学计算, 证明了环丙烷环可以在某种程度上与不饱和体系共轭。     

Analytic Calculation of Arbitrary Matrix Elements for Boson Exponential Quadratic Operators

By means of the transformation relation between the ordinary form of boson exponential quadratic operators (BEQO) and its anti-normal product form, we present an effective method to conveniently calculate arbitrary matrix elements of BEQO. By this method, many important matrix elements can be calculated analytically. As a direct application, we obtain the exact solutions of the density matrix and partition function for general boson quadratic Hamiltonian without any information about the energy level.     

Synthesis and Spectroscopic Characterization of Transition Metal Complexes of Maleionitriledithiolate and 5-Nitro-Phenanthroline

The dithiolenes and diimines and their metal complexes are an important research field in the organic and coordination chemistry^[1-3]. Transition metal complexes of a dithiolene and a diimine have excellent electronic functions due to the intramolecular charge transfer from a ligand to other ligand (LL'CT)^[3], in which are interested authors^[4,5]. Recently we have been studied in detail the synthesis and properties of the title complexes M(mnt)(5-NO₂-phen), M=Mn^Ⅱ, Fe^Ⅱ, Co^Ⅱ, Ni^Ⅱ, Cu^Ⅱ, Zn^Ⅱ. The structure and properties of the M(mnt)(5-NO₂-phen) were characterized by the elemental analysis, TDA-TG, MASS, IR, UV-Vis, fluorescence and EPR spectra,molar conductivity and magnetic susceptibility. In the present abstract we report only the synthesis and spectroscopic characterization of these complexes.     

NaBH4/BiCl3复合体系还原芳香硝基化合物为氧化偶氮苯及其类似物

NaBH4/BiCl3复合体系在甲醇介质中对硝基化合物进行部分还原,可以获得相应的氧化偶氮苯类化合物。实验中发现此反应与反应底物的Hammett常数有着密切的关系。     

Two Applications of Linear Quantum Transformation Theory in Multi-Mode Fock Space

By the aid of the linear quantum transformation (LQT), we derive all of the explicit expressions of Bogoliu bov-Valatin transformation and the rotation transformation in the case of multi-mode Fock space.