非平衡态/不可逆过程的热力学理论(Ⅱ)

<正> 7 解的唯一性 如果不考虑非平衡态和不可逆性,则等能密度理论中的基本命题与经典弹性理论中的在形式上完全相同。无论整个系统的动能是大还是小,图6中(sumform)_o上的面力T_i和在(sumform)_c和在的位移u_i将始终在空间坐标系x_i和时刻i下给出。与一般力学中相同,必须知道有关位移u_i及其时间导数的初始条件。它们的影响则可通过(38)和(39)向等能面转化,从而得到     

Dithienylethene-Based Single Molecular Photothermal Linear Actuator

By employing a mechanically controllable break junction technique, we have realized an ideal single molecular linear actuator based on dithienylethene (DTE) based molecular architecture, which undergoes reversible photothermal isomerization when subjected to UV irradiation under ambient conditions. As a result, open form (compressed, UV OFF) and closed form (elongated, UV ON) of dithienylethene-based molecular junctions are achieved. Interestingly, the mechanical actuation is achieved without changing the conductance of the molecular junction around the Fermi level over several cycles, which is an essential property required for an ideal single molecular actuator. Our study demonstrates a unique example of achieving a perfect balance between tunneling width and barrier height change upon photothermal isomerization, resulting in no change in conductance but a change in the molecular length, which results in mechanical actuation at the single molecular level.     

Optical gain and refractive index of a laser amplifier in the presence of pump light for cross-gain and cross-phase modulation

The wavelength dependent changes in optical gain and refractive index in a Fabry-Perot semiconductor optical amplifier are measured for various detunings of the pump wavelength from the quasi-Fermi level separation. The refractive index change is nearly constant over a very large wavelength range. We also present data for the linewidth enhancement factor due to optical injection. Estimates of the carrier densities and stimulated recombination rates are made using our optical gain model based on realistic band structure calculations for a strained quantum-well laser. Our results are very useful for ultra-broad-band wavelength conversion by cross-gain and cross-phase modulation (XGM, XPM).     

Room-temperature continuous-wave operation of long wavelength (l ?9.5 lm) MOVPE-grown quantum cascade lasers

High-power continuous-wave operation of long wavelength quantum cascade lasers grown by metal organic vapour phase epitaxy is reported. The lasers have been processed as buried heterostructures with thick gold-plated contacts. The devices emit at a wavelength of 9.5 mum with output powers of several hundreds of milliwatts at room temperature.     

Relative intensity noise reduction in InGaAs/InP multiple quantum well lasers with low nonlinear damping

The authors demonstrate theoretically and experimentally that the relative intensity noise (RIN) of laser diodes can be dramatically reduced by decreasing nonlinear damping in the laser. Four types of InGaAs/InP multiple quantum well (MQW) lasers with different well widths, barrier widths, and numbers of wells were fabricated. By comparing these four types of devices, it is shown that MQW lasers with wider wells, narrower barriers, and larger numbers of wells have smaller nonlinear damping and lower RIN.<>