全文获取类型
收费全文 | 387篇 |
免费 | 14篇 |
专业分类
化学 | 218篇 |
晶体学 | 9篇 |
力学 | 25篇 |
数学 | 29篇 |
物理学 | 65篇 |
无线电 | 55篇 |
出版年
2023年 | 2篇 |
2022年 | 22篇 |
2021年 | 14篇 |
2020年 | 16篇 |
2019年 | 12篇 |
2018年 | 24篇 |
2017年 | 16篇 |
2016年 | 20篇 |
2015年 | 8篇 |
2014年 | 23篇 |
2013年 | 41篇 |
2012年 | 28篇 |
2011年 | 30篇 |
2010年 | 17篇 |
2009年 | 9篇 |
2008年 | 17篇 |
2007年 | 11篇 |
2006年 | 7篇 |
2005年 | 9篇 |
2004年 | 11篇 |
2003年 | 3篇 |
2002年 | 4篇 |
2001年 | 7篇 |
2000年 | 7篇 |
1999年 | 5篇 |
1998年 | 5篇 |
1997年 | 6篇 |
1996年 | 5篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1992年 | 4篇 |
1991年 | 1篇 |
1990年 | 3篇 |
1989年 | 1篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1980年 | 1篇 |
1968年 | 1篇 |
排序方式: 共有401条查询结果,搜索用时 0 毫秒
51.
Othman Al Musaimi Oscar M. Mercado Valenzo Daryl R. Williams 《Journal of separation science》2023,46(2):2200743
Hydrophobicity is an important physicochemical property of peptides and proteins. It is responsible for their conformational changes, stability, as well as various chemical intramolecular and intermolecular interactions. Enormous efforts have been invested to study the extent of hydrophobicity and how it could influence various biological processes, in addition to its crucial role in the separation and purification endeavor as well. Here, we have reviewed various studies that were carried out to determine the hydrophobicity starting from (i) simple amino acids solubility behavior, (ii) experimental approach that was undertaken in the reversed-phase liquid chromatography mode, and ending with (iii) some examples of more advanced computational and machine learning models. 相似文献
52.
53.
Field-induced phase transitions in chiral smectic liquid crystals studied by the constant current method 下载免费PDF全文
In ferroelectric liquid crystals, phase transitions can be induced by an electric field. The current constant method allows these transition to be quickly localized and thus the(E, T) phase diagram of the studied product can be obtained.In this work, we make a slight modification to the measurement principles based on this method. This modification allows the characteristic parameters of ferroelectric liquid crystal to be quantitatively measured. The use of a current square signal highlights a phenomenon of ferroelectric hysteresis with remnant polarization at null field, which points out an effect of memory in this compound. 相似文献
54.
A. D. Wiheeb M. A. Ahmad M. N. Murat J. Kim M. R. Othman 《Transport in Porous Media》2014,104(1):133-144
Hydrotalcite (HT) materials have been known to be able to adsorb \(\hbox {CO}_{2}\) even at high temperature. However, HT has not been made into a micro-porous membrane because of its meso-porous nature. In order to form a micro-porous HT membrane, silica was selected as a host matrix due to its ability to retain its micro-porosity. In this paper, a micro-porous hydrotalcite–silica membrane was formed on a meso-porous \(\upgamma \) -alumina layer supported by a macro-porous \(\upalpha \) -alumina substrate. Most of the micro-porosity determined from nitrogen adsorption measurement was found to be either closed or open but not interconnected, whereas most of the meso-porosity (at ca. 11.2 nm) in the micro-porous membrane was open and interconnected, thereby promoting gas flow. Viscous flow mechanism was observed to dominate transport of gases in macro-porous membrane. Knudsen diffusion dominated transport of gases in meso-porous membrane. On the other hand, surface affinity influenced the transport of carbon dioxide through the micro-porous membrane rather significantly. While permeability of pure hydrogen and carbon dioxide were independent of pressure, the permeability of the gases in the binary mixtures decreased with increasing pressure. Both experiment and simulation demonstrated consistent results. 相似文献
55.
An aluminum alloy1 was tested at quasi-static to dynamic strain-rates (from 10−1 to 5 103 s−1), using a single measuring device, a modified Split Hopkinson Bar. A wave separation technique [Bussac et al., J Mech Phys
Solids 50:321–350, 2002] based on the maximum likelihood method was applied to process the strain and velocity measurements recorded at various points
on each bar. With this method, it is possible to compute the stress, strain, displacement and velocity at any point on the
bar. Since the measurement time is unlimited, the maximum strain measured in a given specimen no longer decreases with the
strain-rate, as occurs with the classical Split Hopkinson Bar method.
1The authors wish to thank the automobile manufacturer who provided samples of the alloy used in this study. For reasons of
commercial and industrial confidentiality, we were not informed about the composition of this alloy. 相似文献
56.
Samir AL-Sadder Raid A. Othman AL-Rawi 《Archive of Applied Mechanics (Ingenieur Archiv)》2006,75(8-9):459-473
An efficient scheme, called quasi-linearization finite differences, is developed for large-deflection analysis of prismatic
and non-prismatic slender cantilever beams subjected to various types of continuous and discontinuous external variable distributed
and concentrated loads in horizontal and vertical global directions. Simultaneous equations of highly nonlinear and linear
terms are obtained when casting the derived exact highly nonlinear governing differential equation using central finite differences
on the nodes along the beam. A quasi-linearization scheme is used to solve these equations based on successive corrections
of the nonlinear terms in the simultaneous equations. The nonlinear terms in the simultaneous equations are assumed constant
during each correction (iteration). Several representative numerical examples of prismatic and non-prismatic slender cantilever
beams with different loading conditions are analyzed to illustrate the merits of the adopted numerical scheme as well as its
validity, accuracy and efficiency. The results of the present scheme are checked using large-displacement finite element analysis
by the MSC/NASTRAN program. A comparison between the present secheme, MSC/NASTRAN and available results from the literature
reveals excellent agreement. The advantage of the new scheme is that the load can be applied in one step with few iterations
(3–6 iterations). 相似文献
57.
58.
A method is proposed to calculate the response of periodic structures subjected to moving loads. It is based on the Floquet decomposition which allows the restriction of the analysis for the overall system to a generic cell. The main contribution of the approach presented hereafter is that the response is directly deduced from transfer functions in the space-wavenumber domain calculated in an unbounded generic cell. Moreover, the equivalence of this new solution with the response of invariant structures obtained using Fourier transforms is established. To cite this article: H. Chebli et al., C. R. Mecanique 334 (2006). 相似文献
59.
The construction and performance characteristics of a novel chromate ion-selective membrane sensor are described and used for determining chromium(III) and chromium(VI) ions. The sensor is based on the use of a rhodamine-B chromate ion-associate complex as an electroactive material in a poly(vinyl chloride) membrane plasticized with o-nitrophenyloctyl ether as a solvent mediator. In a phosphate buffer solution of pH 6 - 7, the sensor displays a stable, reproducible and linear potential response over the concentration range of 1 x 10(-1) - 5 x 10(-6) mol l(-1) with an anionic Nernstian slope of 30.8 +/- 0.5 mV decade(-1) and a detection limit of 1 x 10(-6) mol l(-1) Cr(VI). High selectivity for Cr(VI) is offered over many common anions (e.g., I-, Br-, Cl-, IO4-, CN-, acetate, oxalate, citrate, sulfate, phosphate, thiosulfate, selenite, nitrate) and cations (e.g., Ag+, Ca2+, Sr2+, Co2+, Ni2+, Cu2+, Mn2+, Fe2+, Zn2+, Cd2+, Al3+, Cr3+). The sensor is used for determining Cr(VI) and/or Cr(III) ions in separate or mixed solutions after the oxidation of Cr(III) into Cr(VI) with H2O2. As low as 0.2 microg ml(-1) of chromium is determined with a precision of +/-1.2%. The chromium contents of some wastewater samples were accurately assessed, and the results agreed fairly well with data obtained by atomic absorption spectrometry. 相似文献
60.
Wafa Arif Nosheen Fatima Rana Iqra Saleem Tahreem Tanweer Muhammad Jawad Khan Sohad Abdulkaleg Alshareef Huda M. Sheikh Fatima S. Alaryani Manal Othman AL-Kattan Hanan Ali Alatawi Farid Menaa Aroosa Younis Nadeem 《Molecules (Basel, Switzerland)》2022,27(21)
Resin composites have been widely used in dental restoration. However, polymerization shrinkage and resultant bacterial microleakage are major limitations that may lead to secondary caries. To overcome this, a new type of antibacterial resin composite containing ciprofloxacin-loaded silver nanoparticles (CIP-AgNPs) were synthesized. The chemical reduction approach successfully produced CIP-AgNPs, as demonstrated by FTIR, zeta potential, scanning electron microscopy, and ultraviolet-visible (UV-vis) spectroscopy. CIP-AgNPs were added to resin composites and the antibacterial activity of the dental composite discs were realized against Enterococcus faecalis, Streptococcus mutans, and the Saliva microcosm. The biocompatibility of modified resin composites was assessed and mechanical testing of modified dental composites was also performed. The results indicated that the antibacterial activity and compressive strength of resin composites containing CIP-AgNPs were enhanced compared to the control group. They were also biocompatible when compared to resin composites containing AgNPs. In short, these results established strong ground application for CIP-AgNP-modified dental composite resins. 相似文献