A CASSCF-CI study of the coordination of ethylene with iron

Summary Complete active space SCF, CASSCF, and contracted CI calculations have been performed on the -bonded complex between ethylene and an iron atom. An extended basis set of the ANO type was used, which included polarization functions on all centers. The results indicate an attractive interaction between Fe ⁵ F(d⁷s) and ethylene, with an estimated binding energy of 14 kcal/mol. The low spin complex arising from Fe ³ F(d⁷s) was found to be bound with 18 kcal/mol. Both these potential minima are, however, above the ground state of the iron atom. It is concluded that the interaction between atomic ground state iron and ethylene is not of the normal -bonded type, but is dominated by dispersion forces. A preliminary study showed this interaction to be almost isotropic, with no preferred site for the iron atom.     

Ein neuer,ergiebiger Zugang zu Dihydroactinodiolid und α-substituierten Furanderivaten

Dihydroactinodiolid 1 is formed in high yields by oxidation of the alcohols 2 and 3 and the ether 4 . Furthermore, the oxidation of the epoxy-alcohols 13 and 14 gives rise to the formation of furancompounds ( 15 and 16 , respectively).     

Optically induced transverse voltages in thin metal films

Results of experiments on laser induced voltages in metal films are summarized. The voltages are found to occur along certain directions in the plane of slant-angle vapour deposited films. A thermo-electric model based on periodic variations in the microscopic film structure, is described. The magnitude of the effect is proportional to the absorbed power/length between the contact points. Application of the films in the wavelength range 0.33–10.6μm is described and compared to more conventional detectors. A recent application, using the effect as a tool to profile non-uniformities in thin films, is also discussed.