Photoreaktionen kleiner organischer Moleküle. 4. Mitt. Absorptions-spektren,Photoionen- und Resonanzphotoelektronenspektren von Vinylbromid.

Ohne Zusammenfassung     

Determination of lithium and halogens and the significance of lithium to the understanding of cosmochemical processes

With a newly developed method fluorine and the other halogens have been measured in terrestrial, meteoritic and lunar samples. As a valuable byproduct lithium was determined also via teh reactions⁶Li (n,α)t→¹⁶O (t, n)¹⁸F. From our measurements the following new values for the “cosmic” abundance are derived (in atoms per 10⁶ Si atoms) F 750, Cl 4350, Br 8.83, and I 1.14. We could show that the Li/Be or Li/Zr ratios can be used to estimate the ratio of the Mg-silicates to the group of refractory elements and in course to calculate the bulk composition of the Moon and other planetary objects.     

Peak recognition technique by a computer program copying the human judgement

Summary It is still difficult to determine peaks and peak boundaries properly, though peak recognition is very important for the precision of quantitative data. A new computer program overcomes these problems using a method which is adapted from human judgements. The algorithm was developed for HPLC but can also be used in other fields of analytical chemistry.     

Automatische Analyse und Simulation von NMR-Spektren

Analytical and Bioanalytical Chemistry -     

An extremal problem related to probability

Summary We consider a walk from a stateA ₁ to a stateA _n+1 in which the probability of remaining atA _i isp _i , and the probability of progressing fromA _i toA _i+1 is 1 –p _i . The probabilityW _nk of reachingA _n+1 fromA ₁ in exactlyn + k steps can then be expressed as a polynomial of degreen + k in then variablesp ₁,,p _n . We determine the maximum value ofW _nk and the (unique) choice (p ₁,,p _n ) for which this extremum occurs.Dedicated to Professor Otto Haupt with best wishes on his 100th birthday     

On orthogonal linear ℓ1 approximation

Summary The problem is considered of orthogonal ₁ fitting of discrete data. Local best approximations are characterized and the question of the robustness of these solutions is considered. An algorithm for the problem is presented, along with numerical results of its application to some data sets.     

A fluctuation theorem for moderately interacting diffusion processes

Summary We study the asymptotic behaviour of the fluctuations of the empirical processes of the second example of moderately interacting diffusion processes of [3] and show that in the limit, as the number of different processes tends to infinity, these fluctuations behave gaussian.This work has been supported by the Deutsche Forschungsgemeinschaft     

Stationary policies and Markov policies in Borel dynamic programming

Summary The question of the existence of good Markov [good stationary] policies is studied for a general class of Borel [stationary] dynamic programming models. It is shown, for example, that Markov [stationary] policies are uniformly adequate if every transition law is absolutely continuous with respect to a fixed measure [and the reward function is positive or the model satisfies certain compactness and continuity conditions].Research supported by Deutsche Forschungsgemeinschaft, Sonderforschungsbereich 72Research supported by National Science Foundation Grant MCS 8100789