135La高自旋态的实验研究

利用在束γ谱实验技术,通过¹²⁸Te(¹⁰B,3n)¹³⁵La反应研究了¹³⁵La的高自旋态.基于γγ符合关系、γ射线的相对强度和各向异性度的测量结果,建立了¹³⁵La的能级纲图.在hω≈0.40MeV附近,观测到基于πh_11/2质子轨道上的负宇称带的带交叉.比较N=78同中子素链能级结构的系统性,认为该带交叉是由一对h_11/2准质子发生转动顺排造成的.在高自旋态处,观测到具有很强M1跃迁、Signature劈裂很小的ΔI=1负宇称带,根据系统性认为该带是建立在πh_11/2(νh_11/2)²组态上的γ≈–60°的扁椭球形变带.     

A high‐precision unstructured adaptive mesh technique for gas–liquid two‐phase flows

Adaptive mesh techniques are used widely in the numerical simulations of fluid flows, and the simulation results with high accuracies are obtained by appropriate mesh adaptations. However, gas–liquid two‐phase flows are still difficult to be simulated on adaptive meshes, especially on unstructured adaptive meshes, because the physical phenomena near gas–liquid interfaces are highly complicated and in general, not modeled appropriately on adaptive meshes. In this paper, a high‐precision unstructured adaptive mesh technique for gas–liquid two‐phase flows is developed and verified/validated. In the unstructured adaptive mesh technique, the PLIC algorithm is employed to simulate interfacial dynamic behaviors and, therefore, the reconstruction method for the interfaces in refined cells is developed, which satisfies the gas and liquid volume conservations and geometrical conservations of interfaces. In addition, the physics‐based consideration is performed on the momentum calculations near interfaces, and the calculation method with gas and liquid momentum conservations is developed. For verification, the slotted‐disk revolution problem is solved. As a result, the unstructured adaptive mesh technique succeeds in reproducing the slotted‐disk shape accurately and well maintaining the shape after one full‐revolution. The dam‐break problem is also simulated and the momentum conservative calculation method succeeds in providing physically appropriate results, which show good agreements with experimental data. Therefore, it is confirmed that the developed unstructured adaptive mesh technique is very efficient to simulate gas–liquid two‐phase flows accurately. Copyright © 2010 John Wiley & Sons, Ltd.     

Energetically deep defect centers in vapor-phase grown zinc oxide

Vapor-phase grown ZnO crystals were investigated by means of DLTS measurements. The generation of defect center E4 subsequent to annealing in different ambients was monitored. By conducting electron irradiations with energies, where either both the Zn- and O-sublattice are damaged or according to [1] only the Zn-lattice, a chemical assignment to the defect centers E4 and E3 could be accomplished. DLTS investigations of ZnO samples under illumination give evidence that E4 is a negative-U center. PACS 71.55.-i; 71.55.Gs     

Hybrid quantum circuit with a superconducting qubit coupled to a spin ensemble

We report the experimental realization of a hybrid quantum circuit combining a superconducting qubit and an ensemble of electronic spins. The qubit, of the transmon type, is coherently coupled to the spin ensemble consisting of nitrogen-vacancy centers in a diamond crystal via a frequency-tunable superconducting resonator acting as a quantum bus. Using this circuit, we prepare a superposition of the qubit states that we store into collective excitations of the spin ensemble and retrieve back into the qubit later on. These results constitute a proof of concept of spin-ensemble based quantum memory for superconducting qubits.     

Functional modification of cytochrome c by peroxynitrite in an electron transfer reaction.

The redox reaction of cytochrome c after modification with peroxynitrite under physiological conditions was investigated. Cytochrome c was treated with a bolus of synthetic peroxynitrite at a sub-millimolar concentration, and then subjected to reduction by superoxide and oxidation by hydrogen peroxide. The ability for the membrane potential formation in the mitochondrial respiratory chain was also evaluated. After the treatment with peroxynitrite, the cytochrome c molecule was mono-nitrated mainly at a tyrosine residue, using liquid chromatography-electrospray ionizing mass spectrometry (LC-ESI-MS) and HPLC. Although the redox capacity of cytochrome c was not affected by the peroxynitrite treatment, the oxidation of ferrocytochrome c to ferricytochrome c by hydrogen peroxide was accelerated. When cytochrome c was treated with peroxynitrite in the presence of 5-methoxytryptamine, an inhibitor for the tyrosine nitration by peroxynitrite, the acceleration of hydrogen peroxide-mediated oxidation was suppressed. It was also found that the formation of membrane potential in the rat liver mitochondria was suppressed when peroxynitrite-treated cytochrome c was used instead of the intact cytochrome c in vitro. From these results, we concluded that the peroxynitrite-treated cytochrome c was nitrated at a tyrosine residue and became more susceptible to oxidation by hydrogen peroxide, concomitantly losing the ability to transfer electrons in the mitochondrial respiratory chain. It is suggested that the peroxynitrite-induced modification of cytochrome c increases the susceptibility to non-physiological oxidants, and may cause dysfunction of mitochondria by suppressing of membrane potential.     

Interaction between charged soft microcapsules and red blood cells: effects of PEGylation of microcapsule membranes upon their surface properties

Four types of hydrophilic gel microcapsules containing water have been prepared by an interfacial polymerization method. Each type of microcapsules has a membrane of different composition. Using three kinds of monomers, N,N-dimethylacrylamide (DMAAm), 4-(aminomethyl)styrene (AmSt), and N,N-dimethylaminopropylacrylamide (DMAPAA), one type of aqueous copolymer having primary and tertiary amino groups was obtained. By the polymerization of three kinds of monomers, DMAAm, AmSt, and 2-[(methacryloyloxy)ethyl] trimethylammoniumchloride (METAC), another type of aqueous copolymer having primary and quaternary ammonium groups was also obtained. Two more types of copolymers were synthesized by copolymerization of -acryloxy-ω-methoxy-poly(ethylene glycol) (a-PEG) with the above two kinds of monomer mixture. These copolymers were polymerized with terephthaloyldichloride at the water/oil interface to prepare four types of microcapsules containing water, i.e., poly(DMAAm-co-DMAPAA-co-AmSt-alt-terephthalic acid) microcapsules, poly(DMAAm-co-DMAPAA-co-AmSt-co-PEG-alt-terephthalic acid) microcapsules, poly (DMAAm-co-METAC-co-AmSt-alt-terephthalic acid) microcapsules, and poly (DMAAm-co-METAC-co-AmSt-co-PEG-alt-terephthalic acid) microcapsules, which will be abbreviated to MC 1, MC 2, MC 3, and MC 4, respectively. It has been predicted that the microcapsule membranes are hydrophilic and soft and have two-sublayer structures from electrophoretic mobility measurements and from the analysis of the data with Ohshima’s electrokinetic theory for soft particles. The outer sublayers of MC 1 and MC 2 are negatively charged and those of MC 3 and 4 are slightly positively charged. Also, the surfaces of MC 1 and MC 2 are harder than those of MC 3 and 4. By PEGylation, the surface charge density in the membranes decreases and the surface becomes softer. It has been found that the membrane of red blood cells (RBC) is also soft and is composed of two-sublayers, the outer sublayer of which is negatively charged and the inner one is positively charged. The interaction of four types of microcapsules with RBC has been studied. It was found that microcapsules with soft surfaces (MC 3 and MC 4) do not interact with RBC, even though the microcapsule surfaces are positively charged and the surface of RBC is negatively charged. On the other hand, microcapsules with negatively charged but harder surfaces (MC 1) interact with RBC to introduce hemolysis. The membrane surface of MC 2, which is obtained by PEGylation of MC 1, becomes softer than that of MC 1 so that the interaction with RBC was weakly suppressed. From these, it was concluded that the dominant factor to control the interaction between synthetic polymer surfaces and biological cell surfaces is not the surface charges carried by the polymer surfaces but the softness of the polymer surfaces.     

Polarized target asymmetry in π+ photoproduction between 0.3 and 1.0 GeV at 130°

The polarized target asymmetry for γ + p → π⁺ + n was measured at c.m. angles around 130° for the energy range between 0.3 and 1.0 GeV. A magnetic spectrometer system was used to detect π⁺ mesons from the polarized butanol target. The data show two prominent positive peaks at 0.4 and 0.8 GeV and a deep minimum at 0.6 GeV. These features are well reproduced by the phenomenological analysis made by us.