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991.
Sílvia PetronilhoAuthor Vitae Manuel A. CoimbraAuthor VitaeSílvia M. Rocha 《Analytica chimica acta》2014
Vitis vinifera L. (common grapevine) is considered one of the major world fruit crops based on the extent of cultivated land and on its economic value. Grapevine is composed by several different chemical compounds, including sesquiterpenic ones. Sesquiterpenic compounds play a significant role in varietal aromas, contributing to fruity and flowery odours, and are also well known for their potential health benefits. The advantages and drawbacks of different extraction and gas chromatographic techniques used for the determination of sesquiterpenic compounds are critically presented. Also, the future trends of sample preparation and gas chromatographic tools are discussed. This review provides the state-of-the-art and the technical know-how for the researchers who want to start studying sesquiterpenic compounds on complex matrices such as grapevine products. 相似文献
992.
Combining bar adsorptive microextraction with capillary electrophoresis—Application for the determination of phenolic acids in food matrices
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Nuno da Rosa Neng Rute C. P. Sequeiros José Manuel Florêncio Nogueira 《Electrophoresis》2014,35(17):2488-2494
In this contribution, bar adsorptive microextraction coated with a mixed‐mode anion exchange/RP followed by liquid desorption was combined for the first time with a capillary electrophoresis‐diode array detection system (BAμE(MAX)‐LD/CE‐DAD), for the determination of phenolic acids in food matrices, using chlorogenic, ferulic, cumaric, and caffeic acids as model compounds. Assays performed in aqueous media spiked at the 0.8 mg/L level yielded average recoveries up to 40% for all four phenolic acids, under optimized experimental conditions. The analytical performance showed also good precision (RSD < 15%), convenient LODs (18.0–85.0 μg/L) and linear dynamic ranges (0.8–8.0 mg/L) with convenient determination coefficients (r2 > 0.9900). By using the standard addition method, the application to food matrices such as green tea, red fruit juice, and honey allowed very good performances for the determination of minor amounts of phenolic acids. The proposed methodology proved to be a suitable alternative for the analysis of polar to ionic compounds, showing to be easy to implement, reliable, sensitive, and requiring a low sample volume to determine phenolic acids in food samples. 相似文献
993.
An overview of the most significative results so far attained in the application of carbon nanotubes, fullerenes and nanodiamonds as chromatographic separation media is presented. In particular, the authors focus on their use in capillary and packed-column gas chromatography, in high performance liquid chromatography and capillary electrochromatography, paying also attention to recently developed stationary phases for fast chromatography and nanochromatography. The performance of the nanomaterials is compared to that of planar and amorphous carbon sorbents and critically discussed in regard to retentive capability and selectivity. A wide part of this review is devoted to the most recent improvements achieved in terms of selectivity by use of functionalized nanotubes and by combination of carbon nanotubes with ionic liquids. Practical aspects of synthetic procedures in preparing novel stationary phases in relationship with their chromatographic behaviour are also commented. 相似文献
994.
995.
Fang Zhu Jianqiao XuAuthor Vitae Yuanyuan KeAuthor VitaeSiming HuangAuthor Vitae Feng ZengAuthor VitaeTiangang LuanAuthor Vitae Gangfeng Ouyang 《Analytica chimica acta》2013
As a very popular sample preparation technique, solid-phase microextraction (SPME) coupled with various analytical instrumentation, has been widely used for the determination of trace levels of different plant compounds, such as volatile organic compounds (VOCs) emitted from the different plant organs, and environmental contaminants in plants. In this review, recent applications of in vitro and in vivo SPME in plant analysis are discussed and summarized according to the different organs of plants, including fruits, flowers, leaves, stems, roots and seeds, and the whole plant as well. Future developments and applications of SPME in plant analysis, especially in vivo sampling approaches, are also prospected. 相似文献
996.
Xiaomei PeiAuthor Vitae Bing ZhangAuthor VitaeJuan TangAuthor Vitae Bingqian LiuAuthor VitaeWenqiang LaiAuthor Vitae Dianping Tang 《Analytica chimica acta》2013
Methods based on sandwich-type immunosensors and immunoassays have been developed for detection of multivalent antigens/analytes with more than one eptiope due to the use of two matched antibodies. High-affinity antibodies and appropriate labels are usually employed for the amplification of detectable signal. Recent research has looked to develop innovative and powerful novel nanoparticle labels, controlling and tailoring their properties in a very predictable manner to meet the requirements of specific applications. This articles reviews recent advances, exploiting nanoparticle labels, in the sandwich-type immunosensors and immunoassays. Routine approaches involve noble metal nanoparticles, carbon nanomaterials, semiconductor nanoparticles, metal oxide nanostructures, and hybrid nanostructures. The enormous signal enhancement associated with the use of nanoparticle labels and with the formation of nanoparticle-antibody-antigen assemblies provides the basis for sensitive detection of disease-related proteins or biomolecules. Techniques commonly rely on the use of biofunctionalized nanoparticles, inorganic-biological hybrid nanoparticles, and signal tag-doped nanoparticles. Rather than being exhaustive, this review focuses on selected examples to illustrate novel concepts and promising applications. Approaches described include the biofunctionalized nanoparticles, inorganic-biological hybrid nanoparticles, and signal tage-doped nanoparticles. Further, promising application in electrochemical, mass-sensitive, optical and multianalyte detection are discussed in detail. 相似文献
997.
Dr. Bo Peng Dr. Xueliang Huang Dr. Lan‐Gui Xie Prof. Dr. Nuno Maulide 《Angewandte Chemie (International ed. in English)》2014,53(33):8718-8721
A Brønsted acid catalyzed redox arylation of ynamides that employs aryl sulfoxides as the arylating agents is reported. This metal‐free transformation proceeds at room temperature and efficiently affords α‐arylated oxazolidinones in a redox‐neutral, atom‐economic fashion. 相似文献
998.
Flavylium Network of Chemical Reactions in Confined Media: Modulation of 3′,4′,7‐Trihydroxyflavilium Reactions by Host–Guest Interactions with Cucurbit[7]uril
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In moderately acidic aqueous solutions, flavylium compounds undergo a pH‐, and in some cases, light‐dependent array of reversible chemical reactions. This network can be described as a single acid–base reaction involving a flavylium cation (acidic form) and a mixture of basic forms (quinoidal base, hemiketal and cis and trans chalcones). The apparent pK′a of the system and the relative mole fractions of the basic forms can be modulated by the interaction with cucurbit[7]uril. The system is studied by using 1H NMR spectroscopy, UV/Vis spectroscopy, flash photolysis, and steady‐state irradiation. Of all the network species, the flavylium cation possesses the highest affinity for cucurbit[7]uril. The rate of interconversion between flavylium cation and the basic species (where trans‐chalcone is dominant) is approximately nine times lower inside the cucurbit[7]uril. 相似文献
999.
Serkan ?im?ekAuthor Vitae Ercan TopuzAuthor Vitae 《AEUE-International Journal of Electronics and Communications》2012,66(3):228-234
An extremely rapid, versatile prototyping methodology is developed for waveguide filters with periodic dielectric loading which enables direct dimensional synthesis of the unit cell starting from given design objectives. A prototype filter has been designed using a low dielectric constant material and built for the purposes of testing the feasibility of the proposed approach. Our numerical results are compared with an independent commercial software package and also with experimental measurements. Simulation results are also presented for a filter loaded high dielectric constant material. In both cases the results are in excellent agreement with the theory and demonstrate the validity and the applicability of the proposed method. 相似文献
1000.