Determination of doping effects on Si and GaAs bulk samples properties by photothermal investigations

The knowledge of doping effects on optical and thermal properties of semiconductors is crucial for the development of opto-electronic compounds. The purpose of this work is to investigate these effects by mirage effect technique and spectroscopic ellipsometry SE.

The near gap optical spectra are obtained from photothermal signal for differently doped Si and GaAs bulk samples. However, the above bandgap absorption is determined from SE. These spectra show that absorption in the near IR increases with dopant density and also the bandgap shifts toward low energies. This behavior is due to free carrier absorption which could be obtained by subtracting phonon-assisted absorption from the measured spectrum. This carrier absorption is related to the dopant density through a semi-empirical model.

We have also used the photothermal signal phase to measure the influence of doping on thermal diffusivity.     

U2RV: UAV‐assisted reactive routing protocol for VANETs

When it comes to keeping the data routing robust and effective in vehicular ad hoc networks (VANETs), stable and durable connectivity constitutes the keystone to ensure successful point‐to‐point communication. Since VANETs can comprise all kinds of mobile vehicles moving and changing direction frequently, this may result in frequent link failures and network partitions. Moreover, when VANETs are deployed in a city environment, another problem arises, that is, the existing obstructions (eg, buildings, trees, and hoppers) preventing the line‐of‐sight between vehicles, thus degrading wireless transmissions. Therefore, it is more complicated to design a routing technique that adapts to frequent changes in the topology. In order to settle all these problems, in this work, we design a flooding scheme that automatically reacts at each topology variation while overcoming the present obstacles while exchanging data in ad hoc mode with drones that are commonly called unmanned aerial vehicles (UAVs). Also, the aim of this work is to explore well‐regulated routing paths providing a long lifetime connectivity based on the amount of traffic and the expiration time of each discovered path. A set of experiments is carried out using a simulation, and the outcomes are confronted with similar protocols based on a couple of metrics. The results clearly show that the assistance of UAVs to vehicles is capable of providing high delivery ratios and low delivery delays while efficiently extending the network connectivity.     

EARP: An Enhanced ACO-Based Routing Protocol for Wireless Sensor Networks with Multiple Mobile Sinks

A plenty of Ant Colony Optimization (ACO)-based routing algorithms have been proposed to find optimal path of mobile sinks in Wireless Sensor Networks (WSNs). However, they concentrate on energy efficiency and ignore fault tolerance for critical data collection points like Cluster Heads (CHs). They supposed an ideal scenario where there are no failures which is not the case in reality due to failures resulting from unattended and hostile deployment environments and so on. Moreover, the existing routing protocols are not application-specific enabled (i.e., the parameters cannot be adapted to the application’s requirements). In this paper, we propose an energetically-optimized multi-sink-based clustered WSN model along with a fault-tolerant and energy-efficient Enhanced ACO based Routing Protocol (EARP) to provide reliable data transmission in case of encountering a faulty path. Unlike existing studies, EARP addresses jointly the different constraints of forest fires detection application like fault tolerance, network lifetime and response time. The proposed EARP is simulated along with its counterparts in a general scenario based on various main metrics and also in an application-specific scenario (forest fires detection) based on network lifetime and response time. The simulations results prove its superiority, compared to its peers, in both scenarios.

     

Multiple resonances in the semi-classical limit

We construct for the Schrödinger operator in the semi-classical limit compact perturbations of a radial symmetric potential which give rise to resonances associated to arbitrarily high order poles for the meromorphic extension of the resolvent. Our results concern the hamiltonianP ₀=–h ²–x ² in the 2-dimensional case, as well as a fairly large class of radial-symmetric potentials in the 3-dimensional case. We show that the poles of the resolvent for such a potential are necessarily simple, and subsequently the degeneracy is due to a lack of symmetry.     

Intramolecular interactions in the triplet excited states of benzophenone-thymine dyads

Time-resolved and product studies on the synthesized dyads 1 and 2 have provided evidence that the benzophenone-to-thymine orientation strongly influences intramolecular photophysical and photochemical processes. The prevailing reaction mechanism has been established as a Paterno-Büchi cycloaddition to give oxetanes 3-6; however, the ability of benzophenone to achieve a formal hydrogen abstraction from the methyl group of thymidine has also been evidenced by the formation of photoproducts 7 and 8. These processes have been observed only in the case of the cisoid dyad 1. Adiabatic photochemical cycloreversion of the oxetane ring is achieved upon direct photolysis to give the starting dyad 1 in its excited triplet state. The photobiological implications of the above results are discussed with respect to benzophenone-photosensitized damage of thymidine.     

Enantioselective organocatalytic oxidation of functionalized sterically hindered disulfides

[structure: see text]. The first study on enantioselective oxidation of functionalized sterically hindered disulfides is reported. This study shows that the Shi organocatalytic system using carbohydrate-derived ketone with oxone is superior to the Ellman-Bolm vanadium catalyst in terms of chemical yield and enantioselectivity. Whereas the latter system afforded mostly racemic thiosulfinates in low to moderate yields, the former one afforded thiosulfinates with up to 96% ee.     

Gradient Estimates for Solutions of Ultraparabolic Equations

We establish a priori estimates for solutions to ultraparabolic equations which play a crucial role in the solvability of the initial value problem. A class of these equations came from population dynamics, namely from a fish larvae model.      

Synthesis,characterization and optical properties of ZnO nanoparticles with controlled size and morphology

Zinc oxide monodispersed nanoparticles were synthesized using a modified polyol process without any requirement to use a catalyst or calcination step at high temperature. The morphology and the size of the resulting oxide particles were adjusted by using several synthesis parameters (temperature, alkaline ratio, hydrolysis ratio, etc.). The increasing of the alkaline ratio results in a great change of the elaborated particles morphology that evolved from irregular and anisotropic forms (conical, nanorod-like and elliptical) to spherical one. A growth mechanism of these particles was proposed on the basis of zincite crystal structure and the morphology evolution as a function of the synthesis parameters. The photoluminescence spectra show UV-excitonic and visible emission bands. The strongest intensity of the visible emission was observed in nanorod-like particles, which implies an increased fraction of oxygen vacancies in this sample. The rod-like particles with 1 μm length show the dominant UV-emission, which evidences their improved stoichiometry.     

The influence of antiferroelectric compounds on helical pitch of orthoconic W-1000 mixture

The influence of six antiferroelectric compounds on the helical pitch of mixture W-1000, which was reported as long pitch orthoconic antiferroelectric liquid crystalline mixture, was checked by spectrophotometry and polarimetry methods. The electro-optical properties for the mixture with the longest pitch were measured. An improvement in electro-optical response due to the long pitch is reported. The novelty in electro-optical properties is the good symmetry response.