回旋速调管变周期TE01-TE11模式变换器

针对蛇形圆波导变换器尺寸大和带宽窄的不足,提出了变周期蛇形圆波导模式变换器,以实现TE01到TE11模式的高效率转换。根据耦合波方程,编制了优化计算程序,对工作于30.5 GHz、半径为16 mm的变周期以及传统蛇形变换器几何结构分别进行了优化计算,得到了可实现最高模式变换效率的几何参量。计算结果表明：传统结构变换器最优长度长达1 056.97 mm,转换效率98.1%,90%以上转换带宽也仅为3.3%;变周期变换器最优长度为769.53 mm,转换效率为99.3%,90%以上转换带宽为5.9%。变周期结构相对于传统结构的模式变换器具有尺寸小和带宽宽的明显优势。测试表明所提出的模式变换器具有良好的模式变换性能。     

采用接收与协作双重分集的系统性能分析

研究了一种同时采用两种分集技术的通信方式。在给定的工作环境中,分析了双重分集系统的工作原理,以及信号的传输与接收的过程。并把本文研究的双重分集技术与单纯的空间分集、单纯的协作分集两种技术作了比较。最后通过理论分析与数值计算的结果表明,与单纯的协作分集和单纯的空间分集相比,本文研究的双重分集系统性能更为优越。     

A Phosphorescent Platinum(II) Bipyridyl Supramolecular Polymer Based on Quadruple Hydrogen Bonds

A platinum(II) bipyridyl complex bearing bis‐ureidopyrimidinone (Pt‐bisUPy) has been designed and its self‐assembling behavior has been thoroughly investigated by ¹H NMR, DOSY NMR, Ubbelohde viscometry analysis, UV/Vis, and emission spectroscopies. Pt‐bisUPy underwent concentration‐dependent ring‐chain polymerization in apolar solvents. Hydrogen‐bonding interactions play an important role during the formation of the supramolecular polymers. Hydrogen‐bonded supramolecular polymers were transformed to nanoparticles in water through the miniemulsion method. These nanoparticles showed strong π–π excimeric emission. Metal‐metal‐to‐ligand charge transfer (MMLCT) from Pt–Pt interactions was not significant in the emission spectrum. The phosphorescence of the nanoparticle persisted even under aerobic conditions. The triplet state of these phosphorescent nanomaterials were long‐lived and possessed moderate emission quantum yields. Furthermore, the low toxicity of these materials promises a place for them in in vitro and in vivo bioimaging.     

Thermogravimetric analysis of carbide slag

Potential of carbide slag as transesterification catalyst is validated. Combined with X-ray fluorescence for ingredient determination, X-ray diffraction for textural phase analysis, scanning electron microscope for surface morphology observation and Hammett indicator for basic strength mensuration, thermal event of carbide slag is investigated through thermogravimetric analysis to estimate the potential of this calcium-based industrial waste as transesterification catalyst. Further, kinetic parameters are calculated through model-free method, where the experiments are conducted at temperature heating rates of 5, 10, 15, and 20 K min^?1. As for activation energy and reaction order, Vyazovkin method and Avrami theory are respectively mentioned. Meanwhile, catalytic performance of carbide slag is labeled by transesterification efficiency and calcium hydroxide is conditionally mentioned for comparison. In conclusion, potential of carbide slag as transesterification catalyst is adequately validated.     

Size-dependent visible photoluminescence from ZnO nanoparticles prepared via SiO2 network

This study reports a simple method for the synthesis of different size of wurtzite ZnO nanoparticles in assistance of tetraethyl orthosilicate (TEOS). With the increase of the amount of TEOS added, the average size of ZnO nanoparticles was found decreased from ∼14.6 to ∼1.9 nm by characterization of X-ray diffraction (XRD) and high-resolution electron microscopy (HRTEM). The growth of ZnO nanoparticles is proposed to be controlled by the density of the SiO₂ chain mesh which is determined by TEOS amount in precursor. Ultraviolet–visible (UV–VIS) absorption and photoluminescence (PL) spectra show both shift to higher energy in cut-off edge and in visible emission bands respectively. The electron transition process in the mechanism of the visible emission shift was described and related to quantum size effect in ZnO nanoparticles.