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71.
Tienan Zang Yachen Xie Sa Su Feiran Liu Qianqian Chen Dr. Jing Jing Prof. Rubo Zhang Prof. Guangle Niu Prof. Xiaoling Zhang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(25):10089-10093
Enzymes contain several subunits to maintain different biological functions. However, it remains a great challenge for specific discrimination of one subunit over another. Toward this end, the fluorescent probe TPEMA is now presented for highly specific detection of the B subunit of cytosolic creatine (CK) kinase isoenzyme (CK-B). Owing to its aggregation-induced emission property, TPEMA shows highly boosted emission toward CK-B with a fast response time and very low interference from other analytes, including the M subunit of CK (CK-M). With the aid of a Job plot assay, ITC assay and molecular dynamics simulation, it was directly confirmed that the remarkably enhanced fluorescence of TPEMA in the presence of CK-B results from the restriction of single molecular motion in the cavity. Selective wash-free fluorescence imaging of CK-B in macrophages under different treatments was successfully demonstrated. 相似文献
72.
An adaptive dynamic surface control (DSC) scheme is proposed for the multi-input multi-output attitude control of near-space hypersonic vehicles (NHV). The proposed control strategy can improve the control performance of NHV despite uncertainties and external disturbances. The proposed controller combines dynamic surface control and radial basis function neural network (RBFNN) and is designed to control the longitudinal dynamics of NHV. The DSC technique is used to handle the problem of “explosion of complexity” inherent to the conventional backstepping method. RBFNN is used to approximate the unknown nonlinear function, and a robustness component is introduced in the controller to cancel the influence of compound disturbance and improve robustness and adaptation of the system. Simulation results show that the proposed strategy possesses good robustness and fast response. 相似文献
73.
在本文中,我们设计并研制了用于毫米级精度人卫激光测距的圆扫描时间分析系统。研制的圆扫描变像管理论时间分辨率可优于3ps,可用于双色测距;偏转灵敏度高达10cm/kV,偏转空间分辨率优于24lp/mm;利用双MCP内增强,增益~1×106,并有门控功能以进一步提高信噪比和动态范围。扫描控制电路能提供300MHz、10W的正弦信号,其频率、幅度、相位稳定度均可满足要求。调试过程中较好地解决了阻抗变换、空间干扰和相位正交等关键问题。在仅2W的RF功率驱动下,即可实现稳定的φ24mm的圆扫描,系统实测时间分辨率达4.8ps。在实验室实测测距精度达亚毫米级。动态实验及模拟测距表明,该时间分析系统可满足第四代人卫激光测距系统的需要。 相似文献
74.
当高电荷态类钴氙离子(cobalt like -Xe, Xe27+)入射金属Ni表面过程中,共振电子俘获释放势能完成中性化,形成多激发态的Xe原子,其外壳层电子退激辐射红外光谱线.入射离子特殊的势能释放方式、离子动能和金属表面引起离子增益的能量在极短的时间(飞秒量级)沉积靶平方纳米尺度的空间范围,引起靶表面原子激发和电离,形成复杂组态之间的跃迁,特别是偶极禁戒跃迁(电四极跃迁、磁偶极跃)和X射线发射.单离子X射线产额随入射离子的动能增加而增加.
关键词:
高电荷态离子
红外光谱线
X射线
禁戒跃迁 相似文献
75.
采用射频磁控溅射的方法,在Si(100)基片上制备了纳米β-FeSi2/Si多层结构,利用X射线衍射、透射电子显微镜、光致发光光谱等表征技术,研究了β-FeSi2/Si多层结构的结构、成分和光致发光特性.研究结果表明:利用磁控溅射法得到的Fe/Si多层膜,室温下能够检测到β-FeSi2的1.53 μm处光致发光信号;未退火时多层膜是(非晶的FeSi2+β-FeSi2颗粒)/非晶Si结构,退火后则是
关键词:
2')" href="#">β-FeSi2
磁控溅射
XRD
光致发光光谱 相似文献
76.
We have analysed theoretically the polarization and dielectric constant of uniaxial ionic crystals,including the effect of the nonlinear interactions between ions.The spectrum of polaritons(coupling modes of photons and optical phonons) under nonlinear interactions was developed.A new branch of dispersion relations emerges in the original frequency gap. 相似文献
77.
Adsorption isotherms and kinetics of methylene blue on a low-cost adsorbent recovered from a spent catalyst of vinyl acetate synthesis 总被引:1,自引:0,他引:1
Zhengyong Zhang Zebiao Zhang Y. Fernández Hao Niu Jinhui Peng Libo Zhang Shenghui Guo 《Applied Surface Science》2010,256(8):2569-2801
A regenerated activated carbon used as catalyst support in the synthesis of vinyl acetate has been tested as a low-cost adsorbent for the removal of dyes. After a thorough textural characterization of the regenerated activated carbon, its adsorption isotherms and kinetics were determined using methylene blue as model compound at different initial concentrations. Both Langmuir and Freundlich isotherm models were developed and then compared. It was found that the equilibrium data were best represented by the Langmuir isotherm model. The kinetic data were fitted to pseudo-first-order, pseudo-second-order and intraparticle diffusion models, and it was found that the best fitting corresponded to the pseudo-second-order kinetic model. The results showed that this novel adsorbent had a high adsorption capacity, making it suitable for use in the treatment of methylene blue enriched wastewater. 相似文献
78.
Weisheng Niu 《Journal of Mathematical Analysis and Applications》2011,374(1):166-177
We first establish the local well-posedness for the nonuniform weakly dissipative b-equation which includes both the weakly dissipative Camassa-Holm equation and the weakly dissipative Degasperis-Procesi equation as its special cases. We then study the blow-up phenomena and the long time behavior of the solutions. Two blow-up results are established for certain initial profiles. Moreover, two sufficient conditions for the decay of the solutions are presented. 相似文献
79.
Bo Li Haichao Zhang Yuxiao Niu Dechao Ran Bing Xiao 《Mathematical Methods in the Applied Sciences》2023,46(1):1096-1110
This paper investigates the problem of trajectory tracking control for quadrotor unmanned aerial vehicle (UAV) in the presence of dynamic obstacles and external disturbance forces/torques. More specifically, two new sliding mode disturbance observers are firstly designed to estimate the external disturbances, in which the observation errors can converge to zero in finite time. Furthermore, utilizing the observation information, a new sliding mode surface-like variable-based position tracking control scheme and a novel nonsingular terminal sliding mode-based attitude synchronization control scheme are developed to drive the UAV tracking the reference trajectory with obstacle avoiding. Moreover, the tracking errors of the close-loop control system can converge to zero within finite time by the analyses of Lyapunov methodology. Finally, the numerical simulation results are presented to illustrate the effectiveness of the proposed control schemes. 相似文献
80.
This article is concerned with solving the high order Stein tensor equation arising in control theory. The conjugate gradient squared (CGS) method and the biconjugate gradient stabilized (BiCGSTAB) method are attractive methods for solving linear systems. Compared with the large-scale matrix equation, the equivalent tensor equation needs less storage space and computational costs. Therefore, we present the tensor formats of CGS and BiCGSTAB methods for solving high order Stein tensor equations. Moreover, a nearest Kronecker product preconditioner is given and the preconditioned tensor format methods are studied. Finally, the feasibility and effectiveness of the new methods are verified by some numerical examples. 相似文献