Hybrid integration of semiconductor lasers with Si-basedsingle-mode ridge waveguides

Hybridization is a convenient way for providing silicon-based integrated optical circuits with a laser source. An entirely passive alignment technique exclusively based on the high precision obtainable by lithography and by semiconductor processes was examined. A novel way of cleaving the laser chips by self-aligned cleaving grooves was employed. It resulted in 15.5-dB coupling losses between the laser diode and the single-mode buried ridge waveguide     

Molecularly imprinted polymers in capillary electrochromatography: recent developments and future trends

The developments in molecularly imprinted polymer (MIP)-based capillary electrochromatography (CEC) achieved during the past years are reviewed in this article. The MIP is prepared using a templated polymerization reaction and results in a material with a high selectivity towards a predetermined target. The selectivity of the MIP is comparable to that of the biological antibodies, however, the MIP is much more stable and is thus able to withstand extremely harsh conditions in terms of pH, temperature, and organic solvents. The high selectivity and stability of the MIP made it an interesting candidate for application as stationary phase sorbent in chromatography. However, due to slow kinetics the efficiency of the early MIP columns, which were predominantly applied in high-performance liquid chromatography (HPLC), were limited. The use of CEC was thought to improve the efficiency of the MIP-based separation system. The small dimensions of the capillary format employed in CEC have put demands on the polymer systems which have resulted in the development of many different polymer formats. Thus, this need for novel MIP formats for applications in CEC has contributed a lot to the general development of MIP formats as well as to the knowledge in MIP synthesis and characteristics.     

Ultrasonic-trap-enhanced selectivity in capillary electrophoresis

We combine ultrasonic trapping and capillary electrophoresis (CE) with the goal to detect ultra-low concentrations of proteins via size-selective separation and enrichment of antibody-coated latex spheres. An 8.5 MHz standing ultrasonic wave is longitudinally coupled into the sub-100- micro m diam capillary of the CE system. Competition between acoustic and viscous forces result in in-flow separation of micro m-diam spheres according to their size. Experiments separating 2.8- and 2.1- micro m-diam fluorescent latex particles, which model a protein-specific immunocomplex/free particle mixture, indicate a potential improvement of the concentration limit of detection of 10(4) compared to current CE systems. Theoretical calculations show room for further improvement.     

Local probing of the surface chemical bond using X-ray emission spectroscopy

2 and CO on Ni(100), benzene on Ni(100) and Cu(110), and glycine adsorbed on Cu(110). New types of molecular states are observed which are directly related to the surface chemical bond. The long-accepted Blyholder model which is based on a frontier orbital concept cannot explain our results for N₂ and CO chemisorption. We find it necessary to offer a new picture where changes in the whole molecular orbital framework have to be considered. We show that both π and σ type interactions are important in describing the bonding in benzene to metal surfaces. The future prospect is illustrated by the adsorption of the simplest amino acid, glycine, on Cu(110). The adsorbate has four different atomic centers where X-ray emission spectra are obtained, providing a unique view of the local electronic structure. Accepted: 6 March 1997     

Numerical modeling of ozone production in a pulsed homogeneousdischarge: a parameter study

The pulsed volume discharge is an alternative for the efficient generation of ozone in compact systems. This paper presents a parameter study of the reactions in this kind of homogeneous discharge by using a numerical model which solves plasma chemical kinetic rate and energy equations. Simulations are performed for 10^-9-10^-5 s single pulses and oxygen gas density in the range 10<300 K and normalized electric field of 1000 decreased. The maximum concentration is 3% at 10 amagat and 100 K. The results on ozone accumulation in multiple pulse discharges are presented. In contrast to the single pulse case, higher efficiency is achieved at lower gas density. This scaling can be explained by losses due to ion currents     

Search for forbiddenβ-decays of the drip line nucleus12Be

Beta-coincidentγ-rays have been measured from implanted pure samples of¹²Be separated at the LISE3 spectrometer at GANIL. An intensity of 0.040(26) % can be estimated for the branching ratio of the isospin forbidden pure-Fermi transition to the 0⁺ excited state of¹²B and of 0.008(6)% of the transition to the 1^?1 excited state. Both are taken to represent upper limits. The half-life has been re-measured to be 26.1(2.4) ms.     

Electronic structure of disordered alloys: Optical and photoemission measurements on Ag-Au and Cu-Au alloys

Optical and photoemission measurements on Ag-Au and Cu-Au alloys over the whole composition range are reported. It is found that for these alloys, which represent the situation in many binary alloy systems, neither the commonly used virtual crystal model (and thus not that of the rigid band), nor the independent band model describes the observed results. Calculations in the recently developed coherent potential approximation however reproduce the main features of the observed density of states for the alloys.     

A tool to calculate the linewidth of complicated semiconductor lasers

A theory of the low-frequency phase fluctuations in the output of a semiconductor laser due to spontaneous emission is developed. The theory can be used as a tool to numerically calculate the linewidth of complicated laser structures, e.g., by use of the transfer matrix formulation. The results for the single Fabry-Perot laser are shown to be in exact agreement with the most accurate treatments published so far. Results are then presented for both DFB and F-P lasers with external optical feedback showing how the linewidth varies with the threshold gain, with the coupling coefficient, and with the external feedback conditions.     

Fission barriers and the inclusion of axial asymmetry

The nuclear potential-energy surface has been calculated on the basis of the modified-oscillator model with the inclusion of the degrees of freedom of axial asymmetry. For the heavier actinides the inner barrier is found to be reduced by up to one MeV. This is in agreement with the results obtained by Pashkevich. For superheavy elements a similar reduction is obtained.     

Algebraic decoding of the Zetterberg codes

The Zetterberg codes are one of the best known families of double-error correcting binary linear codes. Unfortunately, no satisfactory decoding algorithm has been known for them until recently when an algebraic decoding algorithm was described by P. Kallquist (1989). It requires, however, to solve a quadratic equation in order to decide whether 2 or 3 errors have occurred. A simple criterion is derived to determine whether 1, 2, or 3 errors have occurred when a Zetterberg code is used for data transmission. Based on criterion a new decoding algorithm is proposed which is faster than the known one