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91.
E. J. K. Nilsson M. S. Johnson O. J. Nielsen E. W. Kaiser T. J. Wallington 《国际化学动力学杂志》2009,41(6):401-406
Relative rate techniques were used to study the title reactions in 930–1200 mbar of N2 diluent. The reaction rate coefficients measured in the present work are summarized by the expressions k(Cl + CH2F2) = 1.19 × 10?17 T2 exp(?1023/T) cm3 molecule?1 s?1 (253–553 K), k(Cl + CH3CCl3) = 2.41 × 10?12 exp(?1630/T) cm3 molecule?1 s?1 (253–313 K), and k(Cl + CF3CFH2) = 1.27 × 10?12 exp(?2019/T) cm3 molecule?1 s?1 (253–313 K). Results are discussed with respect to the literature data. © 2009 Wiley Periodicals, Inc. Int J Chem Kinet 41: 401–406, 2009 相似文献
92.
93.
DFB lasers with CW threshold currents as low as 8 mA at room temperature have been fabricated using the VPE transport process. The low threshold currents are attributed to narrow active stripes and to the high coupling strength of the grating. Single-mode lasing at 1.53?m up to I = 8Ith and during high-speed direct modulation has been confirmed. 相似文献
94.
Camilla Nilsson Eva Malmström Mats Johansson Stacy M. Trey 《Journal of polymer science. Part A, Polymer chemistry》2009,47(2):589-601
A series of well‐defined allyl‐ether functionalized polyester dendrimers has been synthesized via the divergent approach using traditional esterification reactions. Two commercially available trifunctional thiols, trimethylolpropane tri(3‐mercaptopropanoate) (TRIS) and ethoxylated trimethylolpropane tri(3‐mercaptopropanoate) (ETTMP), were incorporated with the dendrimers into the thiol‐ene polymer networks. The thiol‐ene reactions were conducted at room temperature and cured by UV light without the addition of photoinitiatior. Highly crosslinked films were obtained and characterized with respect to mechanical (DMA) and thermal (DSC and TGA) properties. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 589–601, 2009 相似文献
95.
Camilla Nilsson Neil Simpson Michael Malkoch Mats Johansson Eva Malmström 《Journal of polymer science. Part A, Polymer chemistry》2008,46(4):1339-1348
Well‐defined, allyl‐ether functional, first‐generation dendrimers have been synthesized. The convergent growth approach was utilized, using the anhydride of the allyl‐ether terminated building block. Three different core moieties were used: trimethylolpropane, trisphenol, and ditrimethylolpropane. The coupling reactions proceeded in good yields and all compounds were characterized by NMR, MALDI‐TOF, and SEC. The allyl‐terminated dendrimers were crosslinked by thiol–ene chemistry, using a multifunctional thiol, TriThiol, to give clear and smooth films. The photopolymerization was conducted in the presence of a photoinitiator, Irgacure 651, and no traces of either allyl‐ether groups or thiols were observed by FT‐Raman after cure. All crosslinked films were characterized with respect to mechanical (DMA) and thermal (DSC) properties. It was found that homogeneous networks were formed and that the core functionality and structure had little effect on the network properties. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1339–1348, 2008 相似文献
96.
D. Nilsson J. -O. Adler B. -E. Andersson K. I. Blomqvist L. Isaksson A. Sandell B. Schröder K. Ziakas L. Van Hoorebeke D. Ryckbosch R. Van de Vyver 《Zeitschrift für Physik A Hadrons and Nuclei》1990,336(2):239-240
The high spin structure of the nucleus129Ba has been investigated using a18O induced reaction. The known bands could be followed up to a maximum spin (55/2) ?. Some 56 states and 78 transitions could be placed in the level scheme. Band crossings were established in both positive and negative parity structures. They display features of strong polarization effects due to the alignment of h11/2 protons. 相似文献
97.
Huang C Weiss TM Nordlund D Wikfeldt KT Pettersson LG Nilsson A 《The Journal of chemical physics》2010,133(13):134504
Using small angle x-ray scattering, we find that the correlation length of bulk liquid water shows a steep increase as temperature decreases at subzero temperatures (supercooling) and that it can, similar to the thermodynamic response functions, be fitted to a power law. This indicates that the anomalous properties of water are attributable to fluctuations between low- and high-density regions with rapidly growing average size upon supercooling. The substitution of H(2)O with D(2)O, as well as the addition of NaCl salt, leads to substantial changes of the power law behavior of the correlation length. Our results are consistent with the proposed existence of a liquid-liquid critical point in the deeply supercooled region but do not exclude a singularity-free model. 相似文献
98.
Michel Chedid Hans Nilsson Alf Johansson Jan Welinder 《AEUE-International Journal of Electronics and Communications》2010,64(10):947-952
An active inductor based on an improved gyrator circuit is proposed. The active inductor is developed to be implemented in a high impedance transceiver for a wearable DC power line communication network where requirements such as low power consumption, high bandwidth and numerous nodes support are prioritized. A load isolation step is introduced to ensure the stability of the active inductance's size on different load currents. The proposed gyrator circuit is analyzed and optimized by means of theoretical calculations. The theoretical results are then verified by simulations and experiments in the frequency range up to 10 MHz. 相似文献
99.
Miller DJ Öberg H Kaya S Sanchez Casalongue H Friebel D Anniyev T Ogasawara H Bluhm H Pettersson LG Nilsson A 《Physical review letters》2011,107(19):195502
The oxidation of Pt(111) at near-ambient O2 pressures has been followed in situ using x-ray photoelectron spectroscopy (XPS) and ex situ using x-ray absorption spectroscopy (XAS). Polarization-dependent XAS signatures at the O K edge reveal significant temperature- and pressure-dependent changes of the Pt-O interaction. Oxide growth commences via a PtO-like surface oxide that coexists with chemisorbed oxygen, while an ultrathin α-PtO2 trilayer is identified as the precursor to bulk oxidation. These results have important implications for understanding the chemical state of Pt in catalysis. 相似文献
100.
This paper numerically investigates a cascade of erbium-doped fiber amplifiers (EDFAs) with different spectral characteristics in an alternating scheme. Thereby, in a transmission band with appropriate spectral properties (1544-1550 nm), the sensitivity of optically amplified long-haul WDM transmission links on the span loss between amplifiers can be reduced to that of single-channel systems. This may be as much as an order of magnitude better than in a traditional, nonalternating, WDM cascade. While passive bandpass filters are necessary to control the wavelength range, there is no need for any active gain equalization or feed-back control. The gain in the cascade can also to some extent automatically adjust to compensate for a spectral tilt of the loss. We show that the range of this automatic loss tilt compensation can be increased, up to three times its original value, by enhancing the difference of the net gain that signals at different wavelengths experience in EDFAs of different types 相似文献