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Raman spectroscopy, in principle, is an excellent technique for the study of molecular species developed on metal surfaces during electrochemical investigations. However, the use of the more common laser wavelengths such as the 514.5‐nm line results in spectra of less than optimal intensity, particularly for iron oxide compounds. In the present work, near‐resonance enhancement of the Raman spectra was investigated for the iron oxide and iron oxyhydroxide compounds previously reported to be present in the passive film on iron, using a tuneable dye laser producing excitation wavelengths between 560 and 637 nm. These compounds were hematite (α‐Fe2O3), maghemite (γ‐Fe2O3), magnetite (Fe3O4), goethite (α‐FeOOH), akaganeite (β‐FeOOH), lepidocrocite (γ‐FeOOH) and feroxyhyte (δ‐FeOOH). Optimum enhancement, when compared to that with the 514.5‐nm line, was obtained for all the iron oxide and oxyhydroxide standard samples in the low wavenumber region (<1000 cm−1) using an excitation wavelength of 636.4 nm. Particularly significant enhancement was obtained for lepidocrocite, hematite and goethite. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
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Single-walled carbon nanotube (SWCNT) bundles have the potential to provide an attractive solution for the resistivity and electromigration problems faced by traditional copper interconnects. This paper discusses the modeling of nanotube bundle resistance for on-chip interconnect applications. Based on recent experimental results, the authors model the impact of nanotube diameter on contact and ohmic resistance, which has been largely ignored in previous bundle models. The results indicate that neglecting the diameter-dependent nature of ohmic and contact resistances can produce significant errors. Using the resistance model, it is shown that SWCNT bundles can provide up to one order of magnitude reduction in resistance when compared with traditional copper interconnects depending on bundle geometry and individual nanotube diameter. Furthermore, for local interconnect applications, an optimum nanotube diameter exists to minimize the resistance of the carbon nanotube bundle.  相似文献   
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Described herein is a new printing method—direct writing of conducting polymers (CPs)—based on pipette‐tip localized continuous electrochemical growth. A single barrel micropipette containing a metal wire (Pt) is filled with a mixture of monomer, supporting electrolyte, and an appropriate solvent. A droplet at the tip of the pipette contacts the substrate, which becomes the working electrode of a micro‐electrochemical cell confined to the tip droplet and the pipette. The metallic wire in the pipette acts as both counter and reference electrode. Electropolymerization forms the CP on the working electrode in a pattern controlled by the movement of the pipette. In this study, various width poly(pyrrole) 2D and 3D structures are extruded and characterized in terms of microcyclic voltammetry, Raman spectroscopy, and scanning electron microscopy.

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In this letter, we develop an efficient method for optimizing the geometry of a dielectric strip over a metallic substrate for subwavelength waveguide applications. We investigate the effect of the design parameters on the light propagation and find the optimum design for both loss and light confinement. The proposed design technique generates optimal waveguide geometries that can support single-mode propagation while simultaneously achieving low loss and small modal sizes  相似文献   
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In this paper, we present a modeling methodology for fully integrated inductively degenerated cascode ultrawideband low noise amplifiers (LNA) with generalized filter-based impedance matching networks. Our accurate analytical models capture the impact of device and passive component parasitics and transistor short channel effects to generate accurate designs. Utilizing our methodology, we are able to accurately generate an ultrawideband LNA in the 3.1–10.6 GHz frequency band using third and fifth order Chebyshev filters as input impedance matching networks. The speed and accuracy of the proposed analytical model will facilitate rapid design space exploration for ultrawideband LNAs.  相似文献   
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We discuss long-range boundary effects in simple two- or three-dimensional fluids. These boundary effects are due to the existence of long-range correlations in nonequilibrium fluids and can be computed either by means of kinetic theory or phenomenological mode-coupling theories. In particular, we use kinetic theory to compute the stress tensor and heat flux vector for a fluid in a nonequilibrium steady state in a finite geometry and show that both the effective shear viscosity and effective heat conductivity have contributions due to the walls of the container that influence the behavior of the system far into the fluid. We also show that the mechanocaloric effect is present in the bulk of a three-dimensional fluid and that there are normal stresses in a fluid whenever the temperature gradient is nonzero.Work performed under National Science Foundation grant No. CHE 77-16308.  相似文献   
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Thermal stress calculations for an isotropic medium are presented. The calculations simulate a continuous wave laser beam pumping a laser crystal. Two different crystal shapes, a rod and a rectangular slab, are shown to give significantly different stress distributions. The calculation is based on an experiment where an argon laser was used to pump a neodymium: phosphate glass sample and photographs of stress fractures are shown.  相似文献   
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