Duty cycle and directional jet effects of a plasma actuator on the flow control around a NACA0015 airfoil

This paper reports on the effects of a series of fluid-dynamic dielectric barrier discharge plasma actuators on a NACA0015 airfoil at high angle of attack. A set of jet actuators able to produce plasma jets with different directions (vectoring effect) and operated at different on/off duty cycle frequencies are used. The experiments are performed in a wind tunnel facility. The vectorized jet and the transient of the flow induced by unsteady duty cycle operation of each actuator are examined and the effectiveness of the actuator to recover stall condition in the range of Reynolds numbers between 1.0 × 10⁵ and 5.0 × 10⁵ (based on airfoil chord), is investigated. The actuator placed on the leading edge of the airfoil presents the most effective stall recovery. No significant effects can be observed for different orientations of the jet. An increase of the stall recovery is detected when the actuator is operated in unsteady operation mode. Moreover, the frequency of the on/off duty cycle that maximizes the stall recovery is found to be a function of the free stream velocity. This frequency seems to scale with the boundary layer thickness at the position of the actuator. A lift coefficient increase at low free stream velocities appears to linearly depend on the supply voltage.     

Nonradical mechanisms for the uncatalyzed thermal functionalization of silicon surfaces by alkenes and alkynes: a density functional study

We propose a new concerted mechanism for the uncatalyzed hydrosilylation of terminal alkenes and alkynes, alternative to the conventional radical-based mechanism. Density functional calculations have been carried out on these and on previously proposed alternative mechanisms for the hydrosilylation of ethylene and acetylene by suitable finite size clusters as models of the thermal functionalization of -SiH3, =SiH2, and [triple bound] SiH groups in flat Si(100) and Si(111) and porous silicon surfaces by alkenes and alkynes. For each step involved in the considered hydrosilylation pathways, we optimized the geometries of reactants and products and located the corresponding transition states. The calculated activation energies for the concerted pathways of ethylene and acetylene are, respectively, 57.6 and 60.9 kcal mol(-1) on -SiH3 and in the ranges 62-63 and 58-61 kcal mol-1 on =SiH2 and 64-66 and 56-61 kcal mol(-1) on SiH. These values are much lower than the activation energies calculated for the corresponding homolytic dissociation of the Si-H bond, which is the preliminary step in the radical path, 85.6, 82-83, and 79-81 kcal mol(-1), respectively, for -SiH3, =SiH2, and [triple bound] SiH groups. Our results thus suggest that the thermal hydrosilylation of alkenes and alkynes on silicon surfaces, for which a radical-based mechanism is currently accepted, may occur through a concerted mechanism.     

Polarization dependence of electroluminescence from closely-stacked and columnar quantum dots

Quantum dots (QDs) have a potential for application in semiconductor optical amplifiers (SOAs), due to their high saturation power related to the low differential gain, fast gain recovery and wide gain spectrum compared to quantum wells. Besides all advantages, QDs realized by Stranski-Krastanov growth mode have a flat shape which leads to a gain anisotropy and a related transverse magnetic (TM) and -electric (TE) polarization dependence as compared to bulk material. This has so far prevented their applications in SOAs. It has been suggested that control of optical polarization anisotropy of the QD can be obtained through QD shape engineering, in closely stacked or columnar QDs (CQDs). To this aim, we have fabricated and tested SOA structures based on closely-stacked and columnar QDs. Closely-stacked InAs QDs with 4, 6 and 10 nm GaAs spacer showed a minor improvement in the ratio of TM and TE integrated electroluminescence (EL) over standard QDs along with a strong reduction in efficiency. In contrast, a large improvement was obtained in CQDs, depending on the number of stacked submonolayers which can be attributed to the more symmetric shape of columnar QDs. A relatively small spectral separation (ΔE ~ 21 meV) between TE- and TM-EL peaks has been observed showing that heavy- and light hole-like states, respectively are energetically close in these QDs. These results indicate that columnar QDs have a significant potential for polarization-independent QD SOA.     

High-power and long-lifetime inGaN blue- violet laser diodes grown by molecular beam epitaxy

InGaN 405 nm multiple quantum well laser diodes grown by molecular beam epitaxy (MBE) with a continuous-wave (CW) lifetime of up to 42 h are reported. The CW threshold current density of the ridge waveguide laser diodes is 3.6 kA/cm² and the slope efficiency for uncoated facets is 0.42 W/A per facet with a maximum CW output power of 45 mW per facet. Statistical variation of CW lifetime with dissipated power is presented for MBE-grown laser diodes from five different wafers.     

Comparison of Twisted P-Form Spectra for Flat Manifolds with Diagonal Holonomy

We give an explicit formula for the multiplicities of the eigenvalues ofthe Laplacian acting on sections of natural vector bundles over acompact flat Riemannian manifold M = \ ⁿ , a Bieberbach group. In the case of the Laplacian acting onp-forms, twisted by a unitary character of , when hasdiagonal holonomy group F ₂ ^k , these multiplicities have acombinatorial expression in terms of integral values of Krawtchoukpolynomials and the so called Sunada numbers. If the Krawtchoukpolynomial K _p ⁿ (x)does not have an integral root, this expressioncan be inverted and conversely, the presence of such roots allows toproduce many examples of p-isospectral manifolds that are notisospectral on functions. We compare the notions of twistedp-isospectrality, twisted Sunada isospectrality and twisted finitep-isospectrality, a condition having to do with a finite part of thespectrum, proving several implications among them and getting a converseto Sunada's theorem in our context, for n 8. Furthermore, a finitepart of the spectrum determines the full spectrum. We give new pairs ofnonhomeomorphic flat manifolds satisfying some kind of isospectralityand not another. For instance: (a) manifolds which are isospectral onp-forms for only a few values of p 0, (b) manifolds which aretwisted isospectral for every , a nontrivial character of F, and(c) large twisted isospectral sets.     

能提供高功率密度的FAN4800 PFC／PWM组合IC

业界面临的挑战1,电器本身的节能问题在未来几年,全球CRT彩电的数量预计将会持平,而数字电视(DTV)市场区间则预计将以30%的年复合增长率增长,于2009年达到9,400万台。平板电视以两种技术为主:液晶电视(到2009年约5,800万台)和等离子电视(到2009年约1,200万台)。本文将着重讨论占据最大部分平板电视市场份额的液晶电视。     

A tetranuclear 3d-4f single molecule magnet: [CuIILTbIII(hfac)2]2

We report now the first single molecule magnet (SMM) consisting of d-f elements. The present study demonstrates that the synthesis of the d-f polynuclear molecule is a very promising approach to SMMs. (1) The d-f polynuclear molecule can be easily synthesized by the assembly reaction of the d-component and the f-component, (2) the high-spin ground state can be generated by a smaller number of metal ions than the d complex, and (3) the molecular magnetic anisotropy is easily derived from the f-component.     

Rapid determination of short chain carnitines in human plasma by electrospray ionisation-ion trap mass spectrometry using capillary electrophoresis instrument as sampler

A capillary electrophoresis apparatus was used as sampler for flow injection analysis (FIA) in tandem mass spectrometry of L-carnitine and its acetyl- and propionyl-metabolites in human plasma. The capillary electrophoresis instrument was coupled to the ion trap mass spectrometer by an electrospray ionization coaxial sheath liquid interface. The electrophoresis capillary introduced the sample directly into the source by applying a prolonged sample injection. The use of the capillary electrophoresis apparatus miniaturised the FIA procedure, substantially reducing the quantities of solvents and samples used, and allowed rapid automated sequential analyses. The method was optimised and validated using a dialyzed human plasma matrix. The plasma samples were analysed after a simple, rapid deproteinisation procedure with acetonitrile and diluted 70 times before direct injection into the mass spectrometer for product ion scan MS/MS analysis in positive ionisation. The total analysis time was 5 min, including capillary preconditioning and acquisition time (3 min). The method was sensitive, allowing the determination of L-, L-acetyl- and L-propionyl-carnitines at 140, 14 and 3.6 nM concentrations (injected values) corresponding to lower limit of quantitation values in plasma of 10, 1 and 0.25 microM, respectively. The method was processed for full validation and applied to the analysis of L-carnitine and its short chain derivatives in human plasma samples.     

Asymmetric distribution of phosphatidyl serine in supported phospholipid bilayers on titanium dioxide

Supported phospholipid bilayers (SPBs) are useful for studying cell adhesion, cell-cell interactions, protein-lipid interactions, protein crystallization, and applications in biosensor and biomaterial areas. We have recently reported that SPBs could be formed on titanium dioxide, an important biomaterial, from vesicles containing anionic phospholipid phosphatidyl serine (PS) in the presence of calcium. Here, we show that the mobility of the fluorescently labeled PS present in these bilayers is severely restricted, whereas that of the zwitterionic phosphatidyl choline is not affected. Removal of calcium alleviated the restriction on the mobility of PS. Both components were found to be mobile in SPBs of identical compositions prepared in the presence of calcium on silica. To explain these results, we propose that, on TiO2, PS is trapped in the proximal leaflet of the bilayers. This proposal is supported by the results of protein adsorption experiments carried out on bilayers containing various amounts of PS prepared on silica and titania.     

Theoretical study of alkali cation-benzene complexes: potential energy surfaces and binding energies with improved results for rubidium and cesium

High level ab initio quantum chemical calculations have been carried out on the binding of alkali metal to benzene with special attention to heavier metals for which the agreement between the most recent theoretical investigations and the experimental bond dissociation energies (BDEs) is not very good. We performed BSSE-corrected geometry optimizations employing the MP2 level of theory with large basis sets and a modified Stuttgart RSC 1997 basis set for rubidium and cesium and carried out single point energy calculations at the MP4 level, obtaining, also for the latter metals, BDE values in good agreement with the experimental results. Furthermore, in view of the development of empirical correction terms to force fields to describe cation-pi interactions, we evaluated the potential energy surface along the benzene symmetry axis and discussed the role of the BSSE correction on the accuracy of our results.