全文获取类型
收费全文 | 144篇 |
免费 | 1篇 |
国内免费 | 1篇 |
专业分类
化学 | 92篇 |
晶体学 | 1篇 |
力学 | 3篇 |
数学 | 10篇 |
物理学 | 17篇 |
无线电 | 23篇 |
出版年
2022年 | 1篇 |
2021年 | 9篇 |
2020年 | 4篇 |
2019年 | 3篇 |
2018年 | 1篇 |
2017年 | 3篇 |
2016年 | 1篇 |
2015年 | 2篇 |
2014年 | 1篇 |
2013年 | 2篇 |
2012年 | 3篇 |
2011年 | 6篇 |
2010年 | 1篇 |
2009年 | 2篇 |
2008年 | 14篇 |
2007年 | 5篇 |
2006年 | 11篇 |
2005年 | 10篇 |
2004年 | 12篇 |
2003年 | 9篇 |
2002年 | 4篇 |
2001年 | 5篇 |
2000年 | 5篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1996年 | 5篇 |
1993年 | 3篇 |
1991年 | 2篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1984年 | 5篇 |
1983年 | 2篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1975年 | 2篇 |
1966年 | 1篇 |
1932年 | 1篇 |
排序方式: 共有146条查询结果,搜索用时 15 毫秒
41.
Kettle SF Diana E Rossetti R Boccaleri E Jayasooryia UA Stanghellini PL 《Inorganic chemistry》2000,39(25):5690-5696
The infrared and Raman spectra of the title compounds in the ca. 400-150 cm-1 region are reported. For the first time, detailed assignments are given for all of the features in this region for the first series of compounds. An attempt is made to extend to all of the modes the plastic cluster model of vibrational analysis, which is normally applied only to nu(M-M) vibrations. While mixing occurs between nu(Fe-Fe) and nu(Fe-E), species containing Te posed particular problems; the reasons for this are discussed and give new insights into the plastic cluster model itself. 相似文献
42.
Journal of Thermal Analysis and Calorimetry - The thermogravimetric analysis when applied to liquid binary mixtures of acetonitrile–water and methanol–water reproduces the whole course... 相似文献
43.
Parolari P. Marazzi L. Rossetti D. Maier G. Martinelli M. 《Lightwave Technology, Journal of》2000,18(9):1284-1288
The authors present a novel coherent-to amplified spontaneous emission (ASE) converter based on SOA's cross-gain modulation (XGM) in a counterpropagating configuration. Experimental characterizations of the ASE converter with bit-error rate (BER) measurements at 2.5 and 5 Gb/s are shown. The device capabilities are exploited in a delay lines optical recognizer at 2.5 Gb/s. Recognition is based on a coherent-to-incoherent light conversion followed by a fiber array correlation filter. Experimental evidence here reported shows performance improvement in comparison with a scheme which adopts a standard telecom source 相似文献
44.
Kobayashi T Yamaguchi T Ohta H Sunatsuki Y Kojima M Re N Nonoyama M Matsumoto N 《Chemical communications (Cambridge, England)》2006,(18):1950-1952
Two heterotrinuclear complexes, [Mn(II)(Ni(II)L)2].2CH3OH (where H3L = 1,1,1-tris(N-salicylideneaminomethyl)ethane) and [Fe(III)(Ni(II)L)2]NO3.C2H5OH, consisting of three face-sharing octahedra have been prepared; although these complexes have closely related structures and have the same 1-5/2-1 spin system, they show completely different magnetic interactions between the adjacent metal ions: ferromagnetic (Ni(II)-Mn(II)) and antiferromagnetic (Ni(II)-Fe(III)). 相似文献
45.
Sharma RP Singh A Venugopalan P Dansby-Sparks R Xue ZL Rossetti S Ferretti V 《Journal of Coordination Chemistry》2010,63(17):3016-3027
A new complex salt of composition [Co(phen)(3)](3)(V(4)O(12))(2)Cl·27H(2)O (phen = 1,10-phenanthroline and [V(4)O(12)](4-) = tetrameric dodecaoxotetravanadate ion) was synthesized by reacting appropriate salts in aqueous medium. The complex salt has been characterized by elemental analyses, thermogravimetric analysis (TGA), cyclic voltammetry (CV), FT-IR and UV/Vis spectroscopies, solubility product and conductance measurements. Single crystal X-ray structure determination revealed ionic structure consisting of three complex cations, [Co(phen)(3)](3+), two [V(4)O(12)](4-) anions, one chloride and twenty seven lattice waters. Detailed structural and spectroscopic analyses of [Co(phen)(3)](3)(V(4)O(12))(2)Cl·27H(2)O show that the large anion is stabilized by the large cationic metal complex as there is preferred shape compatibility that leads to a large number of lattice stabilizing non-covalent interactions. 相似文献
46.
The reaction of the bifunctional organic molecule 1-(dimethylamino)-2-propyne (DMAP) on the Si(100) surface has been investigated by density functional calculations employing a two-dimer cluster model. We found that, once in the physisorbed dative bonded well (-20.0 kcal mol(-1)), DMAP can proceed via a number of pathways, involving the formation of Si-C sigma bonds, which lead to thermodynamically more stable configurations. We first considered the cycloaddition of the CC triple bond, leading to a Si-C di-sigma bonded product (-58.7 kcal mol(-1)), for which we computed an energy barrier of only 12.5 kcal mol(-1), consistently with the observed switching of DMAP adsorption linkage at 300 K. We also explored the dissociative pathway involving the methylene C-H bond cleavage on the dative bonded DMAP, leading to three adsorption products with one (-57.3 kcal mol(-1)) and three Si-C sigma bonds (-58.7 and -60.6 kcal mol(-1)). The energy barrier for this pathway is computed 24.7 kcal mol(-1) and may therefore compete at temperature above 300 K with the reaction pathway involving the addition of the alkyne unit. 相似文献
47.
The adducts of cyclohexane-1,4-dione with HgCl2, ZnCl2, and TiCl4 have been prepared, and the IR. absorption spectra of the solid products studied. The lowering of the carbonyl frequency shows that the acceptor is linked by dative bonds to the carbonyl oxygen donors. This result confirms the cyclohexane-1,4-dione · HgCl2 structure which has been determined by X rays diffraction. 相似文献
48.
49.
Iogann Tolbatov Alessandro Marrone Cecilia Coletti Nazzareno Re 《Molecules (Basel, Switzerland)》2021,26(24)
Owing to the growing hardware capabilities and the enhancing efficacy of computational methodologies, computational chemistry approaches have constantly become more important in the development of novel anticancer metallodrugs. Besides traditional Pt-based drugs, inorganic and organometallic complexes of other transition metals are showing increasing potential in the treatment of cancer. Among them, Au(I)- and Au(III)-based compounds are promising candidates due to the strong affinity of Au(I) cations to cysteine and selenocysteine side chains of the protein residues and to Au(III) complexes being more labile and prone to the reduction to either Au(I) or Au(0) in the physiological milieu. A correct prediction of metal complexes’ properties and of their bonding interactions with potential ligands requires QM computations, usually at the ab initio or DFT level. However, MM, MD, and docking approaches can also give useful information on their binding site on large biomolecular targets, such as proteins or DNA, provided a careful parametrization of the metal force field is employed. In this review, we provide an overview of the recent computational studies of Au(I) and Au(III) antitumor compounds and of their interactions with biomolecular targets, such as sulfur- and selenium-containing enzymes, like glutathione reductases, glutathione peroxidase, glutathione-S-transferase, cysteine protease, thioredoxin reductase and poly (ADP-ribose) polymerase 1. 相似文献
50.
Simone Fantauzzi Dr. Emma Gallo Prof. Alessandro Caselli Dr. Cristiana Piangiolino Dr. Fabio Ragaini Prof. Nazzareno Re Prof. Sergio Cenini Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(5):1241-1251
Herein we report the one-pot synthesis of several N-heterocyclic compounds by rearrangement reactions of N-aryl-2-vinylaziridines. The optimization of the synthetic methodology employed allowed us to obtain differently substituted 2,5-dihydro-1H-benzo[b]azepines in good yields and purities. The relationship between the nature of the starting N-aryl-2-vinylaziridine and the obtained N-heterocycle was also investigated. Finally, to rationalize all the experimental results reported in this paper a theoretical study was performed that casts light on the reaction mechanism. 相似文献