Image encryption based on permutation-substitution using chaotic map and Latin Square Image Cipher

In this paper we presented a image encryption based on permutation-substitution using chaotic map and Latin square image cipher. The proposed method consists of permutation and substitution process. In permutation process, plain image is permuted according to chaotic sequence generated using chaotic map. In substitution process, based on secrete key of 256 bit generate a Latin Square Image Cipher (LSIC) and this LSIC is used as key image and perform XOR operation between permuted image and key image. The proposed method can applied to any plain image with unequal width and height as well and also resist statistical attack, differential attack. Experiments carried out for different images of different sizes. The proposed method possesses large key space to resist brute force attack.     

An Adaptive Packet and Block Length Forward Error Correction for Video Streaming Over Wireless Networks

Video streaming over wireless networks is a challenging task due to its high error rate. Forward error correction (FEC) is a popular mechanism to recover lost packets for video streaming. Conventional FEC mechanisms use a whole redundant packet to recover the error source packet, when the packet error occurs with only a few bit errors inside. In this paper, we propose an Adaptive packet and block length FEC (APB-FEC) control mechanism. In order to overcome the high bit error rate, a small packet length reduces the packet error rate and a large FEC block length will enhance the recovery performance. Our proposed APB-FEC can obtain better recovery performance than conventional FEC mechanisms. Hence, APB-FEC can also reduce retransmission overhead. Using extensive emulations, we validate the efficiency of APB-FEC mechanism for video streaming over wireless networks.     

Sol‐Gel Synthesis and Photocatalytic Study of Visible Light Active N‐Doped KSbWO6

KSbWO₆ was prepared by sol‐gel method. N‐doped KSbWO₆ (KSbWO_6–xN_x) was obtained by heating KSbWO₆ and urea at 400 °C. Both the compounds are characterized by powder X‐ray diffraction (XRD), TEM, SEM‐EDS, X‐ray photo electronic spectroscopy (XPS), and UV/Vis diffuse reflectance spectroscopy (UV‐DRS). A shift in the peak positions of powder XRD and XPS spectra was observed. The band gap energy (E_g) of KSbWO₆ and N‐doped KSbWO₆ was obtained from their diffused reflectance spectra.E_g was reduced from 3.17 eV to 2.56 eV upon nitrogen doping in KSbWO₆. The reduction of the E_g is attributed to the lifting of valence band of N‐doped KSbWO₆, due to the mixing of O 2p states with N 2p states. The photocatalytic activity of both the samples was studied by degradation of methylene blue (MB). The nitrogen doped KSbWO₆ shows higher photocatalytic activity compared to that of KSbWO₆.     

Synthesis and Pharmacological Use of 10H-Phenothiazines,Their Sulfones,and Ribofuranosides

This article describes the synthesis of 10H-phenothiazines from 2-aminobenzenethiol and o-halonitrobenzenes via Smiles rearrangement. Upon refluxing with hydrogen peroxide in glacial acetic acid, these phenothiazines yield the corresponding 10H-phenothiazine-5,5-dioxides. The phenothiazines have also been used as base to prepare ribofuranosides by the reaction with β-D-ribofuranose-1-acetate-2,3,5-tribenzoate. All the synthesized compounds have been characterized by spectral and elemental analysis and have been examined for antioxidant and antimicrobial activity.

Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file.     

The Chaperone‐like Activity and Structure of Mutant H119G of Rat Lens αB‐crystallin: A Study of Divalent Metal Ion Binding Site

The molecular chaperone αB‐crystallin, the major player in maintaining the transparency of the eye lens, preventing the aggregation of stress‐damaged and aging lens proteins from aggregation. In nonlenticular cells, it is involved in various neurological diseases, diabetes, and cancer. The role of some metal ions in the αB‐crystallin biology has been reported. Theoretical calculations have proposed that the coordination sites involving His101, His119, Lys121, His18 and Glu99 of human αB‐crystallin were the binding sites for divalent metal ions. Our previous mutagenesis study suggested that His18 rat lens αB‐crystallin is a crucial binding site for Cu(II) and Zn(II) in terms of chaperone‐like activity and structure. In this study mutant H119G of rat lens αB‐crystalin was cloned and expressed to investigate whether His119 is the coordination binding site. Copper and zinc at 1 mM concentration significantly increase the chaperone‐like activity in wild type αB‐crystalin, whereas zinc, copper and magnesium at 1 mM reduced the activity of H119G significantly. The results from chaperone‐like activity, ANS fluorescence measurement and Far‐and Near‐UV CD studies suggest that the replacement of His119 with Glycine resulted in a conformational and minor environmental changes that decrease chaperone‐like activity in the presence of divalent ions suggested that His119 was a crucial binding site for Cu(II) and Zn(II), which was similar to our previous study results of His18. Both results together suggest that His18 and His119 coordinates each other for the binding site of Cu(II) and Zn(II) in terms of improving the chaperone‐like activity and stability of crystallin/metal ion complex.     

Flexible optical encryption with multiple users and multiple security levels

We present a basic optical encryption architecture that admits several cryptography applications based on multiplexing. Users can decrypt different private images from the same encrypted image, a superuser can have a key that decrypts all encrypted images, and multiplexed images can be encrypted with different levels of security. This system is presented in the context of a general framework of optical encryption application development. We illustrate with a real-world three-dimensional scene, captured with digital holography, and encrypted using the fractional Fourier transform, where different users have access to different three-dimensional objects in the scene.     

Antimony potassium tartrate

Single source precursor, antimony potassium tartrate, was used for the preparation of Sb₂O₃, KSb₃O₅, K_0.51Sb _0.67 ^III Sb ₂ ^V O_6.26, and KSbO₃. Antimony trioxide (Sb₂O₃) was prepared by hydrothermal method, while potassium antimony oxides (KSbO₃, K_0.51Sb _0.67 ^III Sb ₂ ^V O_6.26, and KSbO₃) were obtained from the thermal decomposition of antimony potassium tartrate. All the compounds were characterized by powder X-ray diffraction (PXRD), thermogravimetric analysis (TG), Fourier transform infrared spectroscopy (FT-IR), UV–Vis diffuse reflectance spectra, and scanning electron microscopy (SEM). The decomposition process of antimony potassium tartrate with temperature was given. The product formation at different temperatures of thermal decomposition was monitored by PXRD and FT-IR. The TG profile of antimony potassium tartrate shows mass loss at three regions. The infrared spectra of parent and decomposed products gave characteristic Sb-O bands. The band gap energy of decomposed products was obtained. The SEM diagrams of Sb₂O₃ show different morphologies. Direct solid state preparation of KSb₃O₅ and K_0.51Sb _0.67 ^III Sb ₂ ^V O_6.26 under identical experimental conditions was unsuccessful.     

First Stereoselective Total Synthesis of Oplopandiol

The first stereoselective synthesis of the naturally occurring conjugated diyne oplopandiol is reported. The pivotal functionalities are derived from Cadiots? Chodkiewicz cross‐coupling reaction, Ohira? Bestmann alkynation, asymmetric Noyori reduction, and cis‐olefination reaction     

Efficient Protocol for Reductive Amination of Aldehydes and Ketones with Sodium Borohydride in an Ionic Liquid/H2O System

The imines were generated in situ from carbonyl compounds and amines, which undergo smooth reduction with sodium borohydride in an ionic liquid/H₂O solvent system. The reaction conditions were very mild and neutral to afford the corresponding highly functionalized amines in excellent yields.     

Fully phase-encrypted memory using cascaded extended fractional Fourier transform

In this paper, we implement a fully phase-encrypted memory system using cascaded extended fractional Fourier transform (FRT). We encrypt and decrypt a two-dimensional image obtained from an amplitude image. The full phase image to be encrypted is fractional Fourier transformed three times and random phase masks are placed in the two intermediate planes. Performing the FRT three times increases the key size, at an added complexity of one more lens. The encrypted image is holographically recorded in a photorefractive crystal and is then decrypted by generating through phase conjugation, the conjugate of the encrypted image. A lithium niobate crystal has been used as a phase contrast filter to reconstruct the decrypted phase image, alleviating the need of alignment in the Fourier plane making the system rugged.