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71.
Olivier Gicque Dominique Thévenin Nasser Darabiha 《Flow, Turbulence and Combustion》2005,73(3-4):307-321
In this paper we wish to investigate the occurrence of super-equilibrium temperature values, observed in many experimental
configurations. We would like to understand the origin of this phenomenon. Previous authors have already shown that differential
diffusion can lead to considerable changes in the temperature field and we would like to build on top of this observation.
We investigate numerically super-equilibrium combustion by considering both laminar counter-flow and turbulent diluted hydrogen/air
diffusion flames. These turbulent flames are computed using direct numerical simulations (DNS). A detailed reaction mechanism
is employed and the transport properties are modeled using multicomponent diffusion velocities, including the Soret effect.
Analyzing these results we introduce three complementary parameters (dilution-free mixture fraction, dilution excess and local
enthalpy) to describe the local combustion conditions. Introducing a measure of dilution separately from the mixture fraction
is necessary for a proper analysis. Using this set of parameters it becomes possible to explain super-equilibrium temperature
levels as a consequence of differential diffusion. 相似文献
72.
Soghra Farzipour Mina Saeedi Mohammad Mahdavi Hossein Yavari Mohammadreza Mirzahekmati Nasser Ghaemi 《合成通讯》2014,44(4):481-487
Clean and easy preparation of quinazolin-4(3H)-one derivatives using 2-aminobenzamides and Vilsmeier reagent is described. 2-Aminobenzamides were converted into the corresponding quinazolinones under mild and efficient conditions, in good yields without undesirable by-products.
[Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications® for the following free supplemental resource(s): Full experimental and spectral details.] 相似文献
73.
Considering the thermodynamic aspects and reaction pathways of chemical adsorption of NH3 molecule at the open ends of boron nitride nanotubes (BNNTs), theoretically, it was found that the open-ended BNNTs are able
to cleave the N–H bond of NH3 via a one- or two-stepwise mechanism. The N-enriched and B-enriched open-ended BNNTs show a nucleophilic and electrophilic
behavior toward the NH3, respectively. Besides, some effects of this chemical adsorption on the electronic properties of BNNTs were explored. 相似文献
74.
Abedi A Safari N Amani V Khavasi HR 《Dalton transactions (Cambridge, England : 2003)》2011,40(26):6877-6885
The complexes [Fe(dm4bt)(3)][FeCl(4)](2) (1) and [Fe(dm4bt)(3)][FeBr(4)](2) (2) were prepared from the reaction of 2,2'-dimethyl-4,4'-bithiazole (dm4bt) with FeCl(3)·6H(2)O and FeBr(3), respectively, in methanol. Both complexes were characterized by IR, UV-Vis and (1)H NMR spectroscopy and their structures were studied by single-crystal diffraction. The methylated bithiazole led to high spin Fe(II) centers in the octahedral cation part of complexes 1 and 2 with Fe-N distance of 2.220 ?, in spite of the low spin octahedral Fe(II) complexes with unsubstituted bithiazole ligands. Crystal structure determination of 2 was performed at 90, 120 and 298 K. Temperature reduction to 90 K resulted in a decrease in the Fe-N bond length to 2.206 ? which is still in the range of high spin Fe(II). Complex 1 shows a reversible mechanochromic effect from the crystalline phase to powder form from red to yellow; it also displays reversible photochromism from yellow to green in solution under sunlight. The magnetic behaviour of the complexes was also studied at 2-300 K. The temperature dependence of χ(m)T curves for the two forms of 1, crystal and powder, demands some changes in their magnetic behavior, causing different colors i.e. red and yellow. At low temperatures, χ(m)T decreases where the decrease starts at around 65 K for compound 1, and at around 100 K for compound 2, due to different counterions. The two complexes exhibit antiferromagnetism at around 4 K. 相似文献
75.
Mohamed M.S. Nasser 《Journal of Mathematical Analysis and Applications》2011,382(1):47-56
This paper presents a boundary integral method for approximating the conformal mappings from any bounded or unbounded multiply connected region G onto the second, third and fourth categories of Koebe?s canonical slit domains. The method can be also used for calculating the conformal mappings of simply and doubly connected regions. The method is an extension of the author?s method for the first category of Koebe?s canonical slit domains (see [M.M.S. Nasser, Numerical conformal mapping via a boundary integral equation with the generalized Neumann kernel, SIAM J. Sci. Comput. 31 (2009) 1695-1715]). Three numerical examples are presented to illustrate the performance of the proposed method. 相似文献
76.
77.
This paper is concerned with new algorithms which provide the sharp bounds that are guaranteed to contain the exact solutions of nonlinear Volterra integral equations. We develop new enclosure algorithms based on the interval methods which was first introduced by Moore in [24] together with the Taylor polynomials to improve the accuracy of the scheme by reducing the width of interval solutions. The modified methods calculate a priori bound automatically in parallel with the computation of solutions of integral equations. We will show that the accuracy of the proposed algorithms is dependent on the number of interval subdivisions. Some numerical experiments are also included to demonstrate the validity and applicability of the scheme and showing a marked improvement in comparison with the recent existing numerical results. 相似文献
78.
Nasser Eddine Mouhoub Abdelhamid Benhocine Hocine Belouadah 《Applied Mathematical Modelling》2011,35(9):4575-4588
A project is an enterprise consisting of several activities which are to be carried out in some specific order. The activities and the order in which they need to be carried out can be represented by a PERT network. The PERT technique is a traditional, well-known approach to the expert of project management. When networks are used, it often becomes necessary to draw dummy activities. Since the computation of project completion time is proportional to the number of arcs, including dummy arcs, it is desirable to draw a network with as few dummy activities as possible.In this paper, we propose a new method for constructing, for a given project scheduling problem, a PERT network having as small as possible the number of dummy arcs by using some results on line graphs. This algorithm deals with the existence of transitive arcs. The paper contains illustrative examples, proofs of some theoretical results as well as a comparative study with a similar algorithm known in the literature. Computational results showed the superiority of our algorithm. 相似文献
79.
Nano-baskets of calixarenes have been subject to extensive research in the construction of liquid chromatographic phases, extractants, transporters, electrode ionophores, and optical and electrochemical sensors over the past 4 decades. There has long been interest in calixarene-based liquid chromatographic phases. Owing to the recent rapid growth in the number of publications on calixarene-based liquid chromatographic phases, this review paper focuses on their different applications in the main fields of molecular and ionic species as well as liquid chromatographic mobile and stationary phases. Although the recent reports have focused on the optimization and application of one kind or a unique group of calixarenic mobile or stationary phases, this review is a collection and comparison of a variety of research data dealing with the synthesis, preparation and behavior of calixarene-based liquid chromatographic phases. 相似文献
80.