Nickel(II) complexes of 2-aminoacetophenone N(4)-substituted thiosemicarbazones

Mononuclear nickel(II) complexes with 2-aminoacetophenone thiosemicarbazones and three N(4)-substituted thiosemicarbazones have been prepared in EtOH solution and characterized by physical and spectral methods. I.r. and electronic spectra of the thiosemicarbazones and their complexes, along with physical properties of the complexes, have been obtained. The 2-aminoacetophenone thiosemicarbazones coordinate both as neutral and anionic ligands via the thiosemicarbazone moiety's azomethine nitrogen and thione/thiolato sulfur [on loss of the N(2) hydrogen].     

The Design and Optimization of an Ion-Exchanged Polarization Converter Using a Genetic Algorithm

In this work, a genetic algorithm is used for the optimization of the design parameters of an integrated optical polarization converter on a glass substrate. The algorithm is applied to find the minimum possible length for the converter. The required asymmetry for the structure is realized with the aid of a cleaving process following the ion-exchange process. Simulation results show the possibility of realizing such a low-cost integrated converter. The obtained results demonstrate the importance of using such an algorithm in integrated optics problems where several design parameters such as the geometrical dimensions, the temperature, and the time duration are to be optimized.     

High-throughput high-performance TDMA through pseudo-orthogonal carrier interferometry pulse shaping

This letter provides a novel method for doubling throughput in time division multiple access (TDMA) systems. Specifically, with pseudo-orthogonal positioning of carrier interferometry pulse shapes, a TDMA system is designed to support twice as many real symbols in a slot, without increasing bandwidth or slot duration. With regard to performance, the doubling of throughput comes at the cost of only 1-2 dB performance degradations at probability of error of 10/sup -2/.     

Smart antenna arrays with oscillating beam patterns: characterization of transmit diversity in semi-elliptic coverage

By applying carefully selected time-varying delays to the array elements of a smart antenna located at the base station (BS), small oscillations are generated in the beam pattern. These oscillations create a time-varying channel demonstrating intra-symbol time variation and characterized by coherence time T/sub C/. At a single-antenna mobile station (MS), the time-varying channel (with coherence time T/sub C/) creates a time diversity which is exploited to enhance the mobile's performance (by introducing oversampling to the mobile receiver). We present a channel model which characterizes the time-varying channel that results from beam pattern oscillation. We then use our channel model to evaluate the coherence time, T/sub C/, at the mobile station (MS). The channel model presented corresponds to the so-called geometric-based stochastic channel model (GSCM), with a semi-elliptic coverage area. This geometric approach allows us to stochastically model the parameters of the time-varying channel impulse response. Simulations based on the GSCM show that 7-fold time diversity can be exploited at the MS (when beam pattern movement is small), which significantly improves the MS receiver probability-of-error performance.     

Acoustic technique to monitor the kinetics of porous development phenomena in viscoelastic media

In this paper, the potential of a low frequency acoustic technique for the study and characterisation of viscoelastic porous media is investigated. This work was based on the limits of ultrasonic applications in highly absorbent porous media. In this context, fermenting dough was used as a model propagation medium. This type of product has a very complex matrix in terms of texture, openings and moisture. The basic theory of sound in such matter is recalled, especially the effects of the scattering of sound energy in matrices like that of the product under investigation. Depending on the properties of the openings, acoustic velocity and intensity of sound were chosen to represent the state of evolution of the matter. A tap-test acoustic technique was employed and allowed a quality indicator to be obtained. The results of the validation step using various technological parameters indicate that a high degree of sensitivity can be reached with non-destructive acoustic techniques.     

Comparative study on thermal cracking of Athabasca bitumen

In this study, three commonly used isoconversional methods, namely: Ozawa–Flynn–Wall (OFW), Kissinger–Akahira–Sunose (KAS), and the advanced non-linear integral method of Vyazovkin (NLN) were employed for the first time for calculating the activation energy for thermal cracking of Athabasca bitumen under inert conditions. Thermal cracking of Athabasca bitumen was carried out at nonisothermal conditions at different heating rates under nitrogen atmosphere using thermogravimetic analyzer (TG). One isothermal TG experiment was conducted for model prediction. Differences in the values of activation energy determined from the three methods selected have been demonstrated. These differences were mainly attributed to the approximations used for the temperature integral employed in the integral methods. Nonetheless, all the methods tested in this study provided satisfactory isothermal predictions. The study showed that, among the three methods tested, the NLN method provided more accurate results. This is because NLN is approximation free and uses small time segments for the temperature integral.     

Metal complexes of gliclazide: Preparation,spectroscopic and thermal characterization. Biological potential study of sulphonylurea gliclazide on the house fly,Musca domestica (Diptera – Muscidae)

Metal complexes of gliclazide (GLZ; HL) drug are prepared and characterized based on elemental analyses, IR, diffused reflectance, magnetic moment, molar conductance and thermal analyses (TG and DTG) technique. From the elemental analyses data, the complexes are proposed to have the general formulae [M(HL)Cl₃(H₂O)]·3H₂O (M = Cr(III) and Fe(III)), [M(HL)Cl₂(H₂O)₂]·yH₂O (M = Co(III), Ni(II) and Cu(II), y = 0–2) and [M(HL)Cl₂]·yH₂O (M = Mn(II) and Zn(II), y = 0–1). The molar conductance data reveal that all the metal chelates are non-electrolytes. IR spectra show that GLZ is coordinated to the metal ions in a neutral bidentate manner with ON donor sites of the amide-O and sulphonamide-OH. From the magnetic and solid reflectance spectra, it is found that the geometrical structures of these complexes are octahedral (Cr(III), Fe(III), Co(II), Ni(II) and Cu(II)) and tetrahedral (Mn(II) and Zn(II)). The thermal behaviour of these chelates is studied using thermogravimetric analysis (TG and DTG) techniques. The results obtained show that the hydrated complexes lose water molecules of hydration followed immediately by decomposition of the anions and ligand molecules in the successive unseparate steps. The activation thermodynamic parameters are calculated using Coats–Redfern method. The GLZ drug, in comparison to its metal complexes also is screened for their biological activity against house fly, Musca domestica (Diptera – Muscidae). Dose of 5 μg/insect of gliclazide is typically applied against 3 days-old larval instar of M. domestica. Survival of pupal and adult stages has been affected by the complexes of gliclazide more than larval instars. Morphogenic abnormalities of larvae, pupae and adults are studied. On the other hand, pupation and adult emergence program is deteriorated by the effect of different chemicals.     

Spherical hybrid silica particles modified by methacrylate groups

Organic–inorganic hybrid materials have been used as fillers to reinforce dental resin composites, which require strengthening to improve their performance in large stress-bearing applications such as crowns and multiple-unit restorations. Homogeneous organic–inorganic hybrid materials with high performance were prepared by mixing 3-methacryloxypropyltrimethoxysilane (MPTS) and tetraethylorthosilicate (TEOS) synthesized by the sol–gel route. The matrix was prepared by hydrolyzing and condensing the TEOS and MPTS, using basic catalysis and excess water. The resulting xerogel was treated at 50, 100, 150, and 200 °C for 4 h, and the structure was analyzed by thermogravimetry (TG/DTA), photoluminescence (PL), nuclear magnetic resonance (NMR ²⁹Si and ¹³C), transmission electron microscopy (TEM), infrared spectroscopy (IR), and Raman spectroscopy. The PL spectra displayed the Eu³⁺ lines characteristic of ⁵D₀ → ⁷F_{J (J = 0, 1, 2, 3, 4)} ions, and the blue emission was ascribed to the silica matrix. TG, MNR and infrared spectroscopy analyses indicated the hybrid silica was stable, with the organic part present up to 150 °C. Increasing the temperature of the heat treatment was found to increase the degree of hydrolysis. The size and morphology of the silica particles were identified by TEM.     

Copper(II) complexes of 2-aminoacetophenone N(4)-substituted thiosemicarbazones

Mononuclear copper(II) complexes with 2-aminoacetophenone thiosemicarbazone and three N(4)-substituted thiosemicarbazones have been prepared in ethanolic solution and characterized by physical and spectral methods. I.r., electronic and e.s.r. spectra of the complexes, as well as i.r., electronic, and ¹H- and ¹³C-n.m.r. spectra of the thiosemicarbazones, have been obtained. The 2-aminoacetophenone thiosemicarbazones coordinate as neutral ligands via the thiosemicarbazone moiety's azomethine nitrogen and thione sulfur, except for the piperidylthiosemicarbazone, which undergoes deprotonation and coordinates via the thiolato sulfur, as well as through the azomethine nitrogen. Complexes formed in the presence of triethylamine also form complexes with the anionic form of these thiosemicarbazones.