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21.
A series of Zn(II)-Schiff bases I, II and III complexes were synthesized by reaction of o-phenylenediamine with 3-methylsalicylaldehyde, 4-methylsalicylaldehyde and 5-methylsalicylaldehyde. These complexes were characterized using FT-IR, UV-Vis, Diffuse reflectance UV-Vis, elemental analysis and conductivity. Complex III was characterized by XRD single crystal, which crystallizes in the triclinic system, space group P-1, with lattice parameters a?=?9.5444(2) Å, b?=?11.9407(2) Å, c?=?21.1732(3) Å, V?=?2390.24(7) Å3, D c ?=?1.408 Mg m?3, Z?=?4, F(000)?=?1050, GOF?=?0.981, R1?=?0.0502, wR2?=?0.1205. Luminescence property of these complexes was investigated in DMF solution and in the solid state. Computational study of the electronic properties of complex III showed good agreement with the experimental data. 相似文献
22.
Parvin Farshchi Seyed Khatiboleslam Sadrnezhaad Naser Moharram Nejad Mahmood Mahmoodi Leila Ibrahimi Ghavam Abadi 《Journal of nanoparticle research》2011,13(8):3511-3519
Using survey data, public awareness of and attitudes toward nanotechnology are examined in Iran (N = 759). Iran is a developing country with a national nanotechnology action plan for a ten year period starting from 2003
and has been active in the field of research and development of nanotechnology meanwhile. First, the results show that majority
of people are still not familiar with nanotechnology and perceived risks posed by this technology are not considered to be
a lot and most people feel its benefits outweigh the risks. The emotions toward this technology are of a hopeful and positive
nature and this technology is looked upon favorably in Iran. In particular, our results reveals that although the level of
trust is high specially in scientists to communicate the risks with the public, there are a great number who just have some
trust not quite a lot of it. Knowing that it is a hard and time-consuming effort to manage a nation’s view on nanotechnology,
extensive research as well as collaboration with other countries is needed to effectively communicate the risks in time. 相似文献
23.
Sofian M. Kanan Fatin Samara Imad A. Abu-Yousef Naser Abdo Danial Tobias 《Research on Chemical Intermediates》2010,36(5):473-482
Ag (I) nanoclusters doped in mordenite zeolite were prepared and spectroscopically analyzed. Strong luminescence emission
that is dependent on the excitation wavelength was observed. These variations in the emission modes are due to the site selective
luminescence where various luminophores might be excited upon selecting the proper excitation wavelength. The selected material
was found to have strong affinity to remove the quinalphos pesticide, which is widely used for the protection of several vegetable
and fruit crops, from water bodies. HPLC and GC–MS techniques were used to follow the kinetic data and to identify the photodecomposition
products, respectively. The photodecomposition of quinalphos in the presence of the silver doped mordenite catalyst gives
different products compared to the irradiation of quinalphos without catalyst. The presence of the Ag-mordenite catalyst not
only adsorbs the quinalphos from the solution but it also reduces its toxic effect as tested on the fruit fly (Drosophila melanogaster). 相似文献
24.
Mathematical Notes - This article has been retracted at the request of the Editorial Board of the journal in accordance with the COPE guidelines. This article contains a significant amount of... 相似文献
25.
Let (R,m) be a commutative Noetherian regular local ring of dimension d and I be a proper ideal of R such that mAss R (R/I) = Assh R (I). It is shown that the R- module Hht(I) I (R) is I-cofinite if and only if cd(I,R) = ht(I). Also we present a sufficient condition under which this condition the R-module H i I (R) is finitely generated if and only if it vanishes. 相似文献
26.
Recently user quality of experience (QoE) is employed in evaluating end user satisfaction in communications systems. Generally, current approaches for QoE assessment are obtrusive, laboratory based and offline. Estimation of user satisfaction in static manner based on mean opinion score is not directly related to instantaneous individual end user contentment. In this paper, based on correlations between user’s physiological signals and her/his feelings about the service quality, a non-intrusive and user centric QoE assessment system for voice communications is developed. The findings of this study indicate that the emotional patterns in response to the changes in channel quality can be adapted to estimate the level of satisfaction in a QoE assessment system in a live manner. Based on experimental results, two categories of users are identified: sensitive and insensitive towards quality degradations. The results indicate that for the sensitive users, our non-intrusive subjective quality assessment method outperforms ITU-T P.563 standard with respect to root mean square error; while, the results are much better among the insensitive users. 相似文献
27.
Bahram Mokhtari Kobra Pourabdollah Naser Dallali 《Journal of Radioanalytical and Nuclear Chemistry》2011,287(3):921-934
Calixarenes has been subject to extensive research in development of many extractants, transporters, stationary phases, electrode ionophores and optical and electrochemical sensors over the past four decades. In this paper, the nuclear applications of calixarenes are summarized in six fields including complexation studies, solvent extraction, membrane transport, chromatography, luminescent and colorimetric applications, and electroanalytical applications. In the first to fourth sections, the extractability, extraction equilibria and extraction constants of lanthanide, actinide and other nuclear waste cations ions, which were subjected to solvent extraction by the macrocyclic ligands, are reviewed. In two last sections, the analytical applications of calixarene complexes towards nuclear waste cations, including spectroscopic and electroanalytic sensors, are discussed. The examples described in this review illustrate the potential of calixarene derivatives in the rapidly growing field of cations recognition in nuclear wastes. 相似文献
28.
In this report, TiO(2) -SiO(2) composite nanoparticles were prepared by the thermal hydrolysis method using titanium tetrachloride and tetraethylorthosilicate as TiO(2) and SiO(2) precursors, respectively. The prepared nanoparticles were characterized by X-ray powder diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), nitrogen adsorption/desorption and UV-Vis diffuse reflectance spectroscopy (DRS). The results indicated that, in comparison with pure TiO(2), TiO(2)-SiO(2) composite nanoparticles had a higher thermal stability, which prevents phase transformation from anatase to rutile. In addition, the TiO(2)-SiO(2) nanoparticles had a higher specific surface area, larger pore volume, greater band gap energy and smaller crystallite size. Thus, the surface area of TiO(2)-40% SiO(2) composite nanoparticles was about 17 times higher than that of pure TiO(2) nanoparticles. The photocatalytic activity of TiO(2)-SiO(2) composite nanoparticles in the photodegradation of C.I. Basic Violet 2 was investigated. The photodegradation rate of Basic Violet 2 using TiO(2)-40% SiO(2) nanoparticles calcined at 600°C was much faster than that using pure TiO(2) and Degussa P25 TiO(2) by 10.9 and 4.3 times, respectively. The higher photoactivity of the TiO(2)-SiO(2) composite nanoparticles was attributed to their higher surface area, larger pore volume, greater band-gap energy and smaller crystallite size compared with pure TiO(2). 相似文献
29.
The rapid development of wireless in-building communication systems, has widened the scope of supported applications. Remote terminals may be capable of producing broadband real-time traffic such as variable bit-rate (VBR) video or bursty data transfers. Consequently one of the important issues in indoor broadband wireless networks (IBWN) is employment of an efficient bandwidth management protocol. In such a protocol, both the effects of radio channel behavior and the traffic heterogeneity have to be considered. In this paper we present a bandwidth allocation scheme based on the interplay of the radio channel characteristics and the traffic parameters and requirements. In the proposed scheme the base station visits the terminals in a non-uniform cyclic fashion. The inter-visit interval and the amount of service which is provided to each user during a visit, is determined using the channel and traffic parameters based on an analytical approach. This system is evaluated by simulations and is found to provide improved performance in fulfilling the requirements of multimedia services in IBWN. 相似文献
30.
Urea (U) and salicylic acid (SA) crystallize from aqueous solution as a 11 adduct whose structure shows them to be linked via several weak and one strong hydrogen bonds. The ir spectra of the adduct and its deuterated counterpart have been analyzed and the stretching modes of the various hydrogen bonds identified. The1H and13C nmr. spectra are also interpreted to show that discrete adducts of U·SA persist in solution. On heating, U·SA decarboxylates at a much lower temperature than SA itself. 相似文献