H_2BPMPBD和DAM协同萃取部分Ln(Ⅲ)

4 酰代双吡唑啉酮是以吡唑酮为端基、脂肪族碳氢取代基联结而成的一类新型非环四齿酸性螯合剂[1 ,2 ] ,螯合功能团比普通的 4 酰代吡唑酮多一倍 ,对金属离子具有很强的萃取能力 ,其中对Ｆｅ(Ⅲ )、Ｃｏ(Ⅱ )、Ｎｉ(Ⅱ )、稀土离子的萃取分离以及稀土荧光配合物方面的研究已有报道[3～ 5] 。为了进一步探讨该类萃取剂的萃取性能 ,在合成萃取剂 1 ,4 双 ( 1′ 苯基 3′ 甲基 5′ 氧代吡唑 4′ 基 )丁二酮 [1 ,4]的基础上 ,研究了Ｈ2 Ａ与ＤＡＭ的氯仿溶液从硝酸介质中协同萃取Ｌｎ(Ⅲ )的性能。通过考察萃取剂浓度和溶液酸度等因素对Ｌｎ(Ⅲ …     

Photon cascade emission of Pr~(3+) in LnBaB_9O_(16) (Ln = La, Y)

Under 216 nm UV-excitation, cascade emission of Pr3+ occurs from 1S0 state in LaBaB9O16:Pr3+ that converts a single UV photon of high energy into two visible photons. The observation of the cascade emission in this oxide matrix is largely due to the weak crystal field on the lanthanum sites. The analysis of the vibrational coupling indicates that the radiative transition from the 3P0 state is related to the low phonon frequency of the BO4 borate groups bonded to the lanthanum atoms (hwmax-850cm-1). On the other hand, the cascade emission does not take place in a closely related material, YBaB9O16:Pr3+, which can be interpreted by the fact that the 4f5d levels are located below the 1S0 level in this material.     

Molecular Dynamic Study for Chiral Discrimination of α-Phenylethylamine by Modified Cyclodextrin in Gas Chromatography

IntroductionAfter the introduction of modified cyclodextrins (CDs) as a new type ofchiral stationaryphases, great progress has been made in enantioselective gas chromatography, which hasraised many questions about the mechanism of chiral recognition and intermolecularinteractionsl. Theoretical computational methods in conjunction with modellingprocedures have been extensively used to investigate the nature of binding processesresponsible for inclusion complex formation2'3. It is of interest t…     

大泽山葡萄籽油中脂肪酸成分的GC／MS分析

介绍了用正己烷抽提葡萄籽,然后将油进行皂化,用气相色谱－质谱法测定油中脂肪酸,共检测出１４种脂肪酸,其中亚油酸含量最高,占８６．４８％。     

Growth twins in self-frequency doubling laser crystal YbxY1−xAl3(BO3)4

Using chemical etching.method, the growth twins in self-frequency doubling laser crystal Yb_xY_1−xAl₃(BO₃₄ have been observed. The etching pits on both sides of growth twin boundaries in the (10 1) slice are of the triangles with different orientations. The structure of growth twins is investigated by transmission synchrotron topography. In the transmission synchrotron topograph, the growth twins are visible not by ‘domain contrast’ but by ‘boundary contrast’, i.e. the twins appear in the topograph in form of X-ray kinematical diffraction contrast due to the lattice strain stemming from the impurity incorporation in the boundaries. The growth twins in Yb_xY_1−xAl₃(BO₃)₄ crystal are of inversion types, since no domain contrast was observed.     

具有单侧刚性约束的两自由度振动系统在强共振条件下的拟周期运动与混沌

采用理论分析和数值仿真相结合的方法,研究了一类两自由度碰撞振动系统在一种强共振条件下的Hopf分叉问题.分析并证实了碰撞振动系统在此共振条件下可由稳定的周期1-1振动分叉为不稳定的周期3-3振动,讨论了亚谐振动向混沌运动的演化过程.     

用Level Set方法求解具有自由面的流动问题

为采用Ｌｅｖｅｌ Ｓｅｔ方法来计算有自由的流动问题提出了一种方案,把自由水面视为水和空气的交界面,两种介质用统一的Ｎ－Ｓ方法求解,在自由面两侧分别采用各自的密度和粘性,并在自由面上给以适当的光滑;采用边界元法求解双调和方程来确定距离函数;Ｎ－Ｓ方程用投影法求解,文中给出了二维水池水面振荡和瞬时溃坝问题的算例,可以看出用ＬｅｖｅｌＳｅｔ方法求解有自由面流动问题是有效的。     

穿过反平面圆形夹杂界面的曲线型刚性线

利用复变函数方法和叠加原理建立了求解刚性线夹杂问题的弱奇积分方程,利用Ｃａｕｃｈｙ型奇异积分方程主部分方法,研究了穿过反平面圆夹杂界面的曲线型刚性线夹杂在界面交点处点处的奇性应力指数以及交点处角形域内的奇性应力,并定义了交点处的应力奇性因子。利用所得的奇性应力指数,通过对弱奇异积分方程的数值求解,得出了刚性线端点和交点处的应力奇性因子。     

基于费马素数域高基FFT的RS码快速译码算法

基于数论变换理论,提出了一种新的Rs码频域译码算法,该算法基于以3为成元的费马素数域GF(Fn)高基变换．与常规的以√2生成元的变换相比,该变换提高了最大译码长度;而与以2为基的变换相比,GF(Fn)高基变换．与常规的以√2生成元的变换相比,该变换提高了最大译码长度;而与以2为基的变换相比,c信和卫星通信系统中获得广泛应用的RS(255,223)标准码．