Photocatalytic Valorization of Plastic Waste over Zinc Oxide Encapsulated in a Metal–Organic Framework

The conversion of waste plastic into high-value-added chemicals is regarded as a promising approach for relieving global plastic pollution and contributing to the circular economy. Herein, a partial calcination strategy is developed to fabricate a zinc oxide/UiO66-NH₂ (ZnO/UiO66-NH₂) heterojunction, in which ZnO is encapsulated in porous UiO66-NH₂ for the photocatalytic valorization of plastic. This strategy preserves the framework structure of UiO66-NH₂, thus enabling the formation of ZnO with ultra-small size distributed inside the skeleton. The synergistic effect of the obtained ZnO/UiO66-NH₂ heterojunction facilitates providing an efficient channel for carrier/mass transfer and guarantees structural stability. As a result, ZnO/UiO66-NH₂ exhibits high activity for converting polylactic acid (PLA) and polyvinyl chloride (PVC) into acetic acid, coupled with H₂ production. This work provides a feasible strategy for rationally designing heterojunction photocatalysts, as well as an insight into understanding the process of photocatalytic valorization of plastic.     

Pre-Protonated Vanadium Hexacyanoferrate for High Energy-Power and Anti-Freezing Proton Batteries

Proton batteries have been considered as an innovative energy storage technology owing to their high safety and cost-effectiveness. However, the development of fast-charging proton batteries with high energy/power density is greatly limited by feasible material selection. Here, the pre-protonated vanadium hexacyanoferrate (H-VHCF) is developed as a proton cathode material to alleviate the capacity loss of proton-free electrode materials during electrochemical tests. The pre-protonation process realizes fast and long-distance transport of protons by shortening diffusion path and reducing migration barriers. Benefitting from the enhanced hydrogen bonding network combined with dual redox reactions of V and Fe in protonated H-VHCF cathode, a high energy density of 74 Wh kg⁻¹ at 1.1 kW kg⁻¹, and a maximum power density of 54 kW kg⁻¹ at 65 Wh kg⁻¹ is achieved for the asymmetric proton batteries coupling with MoO₃/MXene anode. Proton transport and double oxidation-reduction center are verified by theoretical calculations and ex situ experimental measurements. Considering the anti-freezing availability of proton batteries, 82.5% of its initial capacity is maintained after 10000 cycles under −40 °C at 0.5 A g⁻¹. As a proof-of-concept, flexible device fabricated by optimized electrodes and hydrogel electrolytes can power up a light-emitting diode even under a bent state.     

Research on the Mechanical Properties of Magnetorheological Damping and the Performance of Microprobe Test Process

Journal of Electronic Testing - In order to control the stable and controllable loading of the wafer level microprobe test bench, the magnetorheological (MR) damper used in the existing research...     

A rare-earth spectral traceability anti-counterfeiting detection technology

In this paper, a rare-earth spectral traceability anti-counterfeiting detection technology is proposed. Configure rare-earth samples No.1, No.2 and No.3 with different doping ratios. The spectral signals of these three samples are collected and integrated into a sample library. The traceability anti-counterfeiting detection is to compare the spectral information of the samples to be tested with the established sample library by selecting specific wavelength points for light intensity values. If the sample to be measured meets the light intensity range of the established sample library at a specific wavelength point, the sample model will be output. If it does not meet the light intensity range, the sample to be tested is fake. After testing, the anti-counterfeit rate of samples No.1, No.2 and No.3 can reach 100%. This testing process does not destroy the sample, and the anti-counterfeit effect is unique and reliable.     

硅基微波光子波束形成器研究进展

微波波束形成器是相控阵雷达、5G通信基站等射频发射系统中的核心器件。近年来硅基微波光子波束形成器以其带宽大、尺寸紧凑、重量轻、损耗低、抗电磁干扰等优势成为微波光子学中的研究热点之一。文章从微波光子波束形成的基本原理和性能指标出发,总结了近年来应用于微波光子波束形成器的多种集成可调光学真延迟线结构和波束形成网络架构,并介绍了微波光子波束形成系统集成芯片和自动化控制的最新进展,最后对硅基微波光子波束形成器的未来发展进行了展望。     

SYNTHESIS OF SODALITE BY DRY POWDER METHOD

用新颖的干粉方法合成系列沸石的研究已从五元环沸石延伸到具有四元环和六元环的方钠石。本研究运用干粉方法在Ｎａ２Ｏ－ＳｉＯ２－Ａｌ２Ｏ３混合物中分别以乙醇胺和乙二胺－氟化物为模板，合成出了方钠石。有机模板剂以吸附态模板方式进入体系。用ＸＲＤ数据、扫描电镜图及红外光谱测试结果对实验产品做了表征。结果表明，干粉体系制备的方钠石的晶胞参数小于水热体系和非水体系合成的方钠石的相应值。而以乙醇胺为模板制备的方钠石与以乙二胺－氟化物为模板的样品比较，后者具有较快的晶化速度、较小的晶胞体积和晶粒     

KZnF3：Eu^3＋单晶生长及光谱特性

利用Ｂｒｉｄｇｍａｎ－Ｓｔｏｃｋｂａｒｇｅｒ方法在氩气气氛下生长出ＫＺｎＦ３：Ｅｕ＾３＋单晶，测定了晶体的激发光谱、荧光发射光谱和ＥＳＲ谱，讨论了Ｅｕ离子的取代格位。     

Preparation of Europium Induced Conformation—specific anti—calmodulin Monoclonal Antibody

Monoclonal antibody technique was employed to detect the conformational difference of CaM induced by metal ions. A trivalent europium ion induced conformation-specific anti-calmodulin monoclonal antibody was successfully prepared with europium-saturated calmodulin as antigen.     

Pulse radiolysis of one-electron oxidation of rare tricyclic nucleoside derivative

~~Pulse radiolysis of one-electron oxidation of rare tricyclic nucleoside derivative@赵红卫$Shanghai Institute of Nuclear Research, Chinese Academy of Sciences! Shanghai 201800,China @江致勤$Department of Chemistry, Tongji Unviersity!Shanghai 200092,China @窦大营$Shanghai Institute of Nuclear Research, Chinese Academy of Sciences! Shanghai 201800,China @吴铁一$Shanghai Institute of Nuclear Research, Chinese Academy of Sciences! Shanghai 201800,China @王文锋$Shanghai…