全文获取类型
收费全文 | 779篇 |
免费 | 29篇 |
国内免费 | 1篇 |
专业分类
化学 | 323篇 |
晶体学 | 4篇 |
力学 | 19篇 |
数学 | 55篇 |
物理学 | 307篇 |
无线电 | 101篇 |
出版年
2021年 | 10篇 |
2020年 | 5篇 |
2019年 | 8篇 |
2018年 | 4篇 |
2017年 | 10篇 |
2016年 | 23篇 |
2015年 | 17篇 |
2014年 | 10篇 |
2013年 | 28篇 |
2012年 | 36篇 |
2011年 | 49篇 |
2010年 | 27篇 |
2009年 | 27篇 |
2008年 | 34篇 |
2007年 | 47篇 |
2006年 | 25篇 |
2005年 | 28篇 |
2004年 | 38篇 |
2003年 | 27篇 |
2002年 | 41篇 |
2001年 | 12篇 |
2000年 | 19篇 |
1999年 | 12篇 |
1998年 | 10篇 |
1997年 | 8篇 |
1996年 | 8篇 |
1995年 | 15篇 |
1994年 | 14篇 |
1993年 | 7篇 |
1992年 | 19篇 |
1991年 | 11篇 |
1990年 | 14篇 |
1989年 | 16篇 |
1988年 | 9篇 |
1987年 | 13篇 |
1986年 | 5篇 |
1985年 | 12篇 |
1984年 | 6篇 |
1983年 | 8篇 |
1982年 | 7篇 |
1981年 | 10篇 |
1980年 | 11篇 |
1979年 | 4篇 |
1978年 | 6篇 |
1977年 | 4篇 |
1976年 | 8篇 |
1975年 | 11篇 |
1974年 | 4篇 |
1973年 | 5篇 |
1969年 | 3篇 |
排序方式: 共有809条查询结果,搜索用时 31 毫秒
31.
Capillary electrochromatography (CEC) was employed as a rapid and high-efficiency method for the isocratic separation of all 20 important phenylthiohydantoin (PTH) amino acids, the end products of Edman degradation during N-terminal protein sequencing. For this purpose, 75 microm ID fused-silica capillaries were packed with standard 3 microm Hypersil octadecyl silica (ODS) particles using a two-step column fabrication process, which represents a fast, reliable and efficient means of producing long-term stable columns. The influence of solvent composition, pH, type of buffer cation, buffer concentration, and temperature on retention behavior of PTH amino acids was investigated. Same-day and day-to-day reproducibility of the retention times (over a period of two months) were found to be better than 3%. When comparing this new technique with traditional reversed phase-high performance liquid chromatography (RP-HPLC) methods applied in automated protein sequenators, CEC shows essentially shorter separation times and superior resolution. 相似文献
32.
Radiation induced radical reactions in poly(chloroalkyl methacrylate)s/triallylisocyanurate mixtures
P. Wuensche S. Mueller K.-H. Lorkowski 《Journal of polymer science. Part A, Polymer chemistry》1989,27(5):1589-1598
Radical generation after γ-irradiation at 77 K and radical reactions during temperature increase are discussed for the polymers poly(2-chloroethyl methacrylate) and poly(1,2,2,2-tetrachloroethyl methacrylate), mixed with triallylisocyanurate (TAIC). After the radiation interaction radicals are generated in the ester alkyl side groups of the polymer by chlorine abstraction in both polymer/TAIC mixtures. Radical transfer to TAIC occurs during temperature increase to produce allyl radicals. Hence, the high radiation sensitivity of chlorine-containing polymers is combined with the reactivity of allyl radicals of TAIC in such polymer–TAIC mixtures. 相似文献
33.
S. H. Sheen J. G. Skofronick C. R. Mueller 《International journal of quantum chemistry》1975,9(5):817-824
The effects of orbiting resonances on elastic differential cross sections are investigated for the Lennard-Jones (12, 6) model potential. The elastic differential cross section consists of three terms: a resonance term, a potential scattering term and an interference term. The interference term has a significant effect only at small angles of the differential cross section. The importance of the potential scattering term depends proportionally upon the orbiting resonance energy. For the low-lying orbiting resonance states, the resonance term is the dominant term, but at higher energy it appears only in the backward differential cross sections. Generally, by fitting the large angle differential cross sections, the resonance orbital angular momentum can be estimated. 相似文献
34.
35.
36.
37.
Mueller CA Weinmann W Dresen S Schreiber A Gergov M 《Rapid communications in mass spectrometry : RCM》2005,19(10):1332-1338
A new multi-target screening (MTS) procedure for drugs in blood and urine for toxicological analysis has been developed using a hybrid triple-quadrupole linear ion trap mass spectrometer (QTrap) for the fast detection and identification of 301 forensically important drugs, e.g. tranquilizers (benzodiazepines), hypnotics, drugs of abuse (opiates, cocaine, amphetamines, cannabinoids), antidepressants, neuroleptics, and some cardiac drugs, in one single liquid chromatography/tandem mass spectrometry (LC/MS/MS) analysis. Samples were extracted either with liquid-liquid extraction or solid-phase extraction. A multiple reaction monitoring (MRM) as survey scan and an enhanced product ion (EPI) scan as dependent scan were performed in an information-dependent acquisition (IDA) experiment. Finally, drug identification was carried out by library search with a newly developed MS/MS library based on EPI spectra at three different collision energies in positive mode. The advantage of this newly developed method is the possibility to detect and identify 301 drugs in one single LC/MS/MS run. 相似文献
38.
39.
40.
Lana G. Kaiser Ma?gorzata Marjańska Gerald B. Matson Isabelle Iltis Seth D. Bush Brian J. Soher Susanne Mueller Karl Young 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2010,202(2):259-266
Glutathione (GSH) is a powerful antioxidant found inside different kinds of cells, including those of the central nervous system. Detection of GSH in the human brain using 1H MR spectroscopy is hindered by low concentration and spectral overlap with other metabolites. Previous MRS methods focused mainly on the detection of the cysteine residue (GSH-Cys) via editing schemes. This study focuses on the detection of the glycine residue (GSH-Gly), which is overlapped by glutamate and glutamine (Glx) under physiological pH and temperature. The first goal of the study was to obtain the spectral parameters for characterization of the GSH-Gly signal under physiological conditions. The second goal was to investigate a new method of separating GSH-Gly from Glx in vivo. The characterization of the signal was carried out by utilization of numerical simulations as well as experiments over a wide range of magnetic fields (4.0–14 T). The proposed separation scheme utilizes J-difference editing to quantify the Glx contribution to separate it from the GSH-Gly signal. The presented method retains 100% of the GSH-Gly signal. The overall increase in signal to noise ratio of the targeted resonance is calculated to yield a significant SNR improvement compared to previously used methods that target GSH-Cys residue. This allows shorter acquisition times for in vivo human clinical studies. 相似文献